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On site characterization of wood members is a very challenging task, after consideration of all the variables affecting the material used for the construction and the complexity of the structure itself. Current procedures are limited to few characterizations; in general based on visual inspection supported by the localized drilling resistance analysis and moisture content estimation. The goal of this work was to highlight the potential of the infrared spectroscopy as a tool capable of providing complementary information for the expert inspector assessing the timber structures. The paper presents several examples of successful application of mid and near infrared spectroscopy as used for prediction of physical and mechanical properties of wood. Requirements for implementation of mid and/or near infrared spectroscopy in routine assessment protocols are also provided. [ABSTRACT FROM AUTHOR]

Abstract: Archaeological wood, as most of natural materials, is slowly decomposing on the archaeological site due to various biological factors. Rapid and accurate estimation of the degradation level is extremely important for optimal restoration and conservation. The goal of this research was to verify the effectiveness of Fourier transform near infrared (FT-NIR) spectroscopy for archaeometry. The important advantage of the NIR spectroscopy is its accuracy, simplicity and ability to perform very high number of tests without needs of any destruction to the workpiece. Five oak pieces of the archaeological wood collected from waterlogged sites in Poland have been used. Cellulose and lignin contents, as well as crystallinity and the degree of polymerization were measured with standard reference methods and compared to the contemporary wood. The near infrared spectra represent all the physical/chemical changes of the wood due to waterlogging. This technique was successfully validated in rapid estimation of the cellulose and lignin contents. The method explored in this research might be a novel tool assisting experts in evaluation of the degradation state of archaeological and historical wooden materials. [Copyright &y& Elsevier]

The goal of this work was to develop Fourier-transform-near-infrared-spectroscopy-based methodology for monitoring kinetics and estimating the biodegradation rate of coniferous pulp paper. Two experiments with paper-degrading fungi were tested: one with Chaetomium globosum alone and the other with a mixture of Aspergillus niger , Trichoderma viride , and Penicillium funiculosum . Paper sheets made of fibers with the addition of 0, 2, 3, or 5% of cationic starch and resinous adhesive were used as test samples. In order to quantify the resistance of the paper to biodegradation, tests of breaking length and evaluation of the degree of fungal infestation were performed during infestation. It was found that addition of cationic starch and resin adhesives improved mechanical properties of paper; however, it also increased susceptibility to fungal colonization. Degradation of paper colonized by C. globosum was more advanced and exhibited more rapid kinetics. Spectral analysis revealed that spectra were most varying in bands 4283, 4400, 4742, and 4808 cm −1 , which correspond to –CH, and –OH functional groups of cellulose and hemicelluloses. Differences in spectra were in good agreement with the reference methods; therefore this technique has potential for monitoring the paper biodegradation process and predicting changes in the paper's mechanical properties. [ABSTRACT FROM AUTHOR]