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C6H12CrKN4O12, triclinic, P1̅ (No. 2), a = 5.101(1) Å, b = 7.029(1) Å, c = 10.554(2) Å, α = 76.73(3)°, β = 77.46(3)°, γ = 81.32(3)°, V = 357.5 Å3, Z = 1, Rgt(F) = 0.0321, wRref(F2) = 0.1327, T = 293 K.

The structural parameters, chemical bonding and magnetic properties of the ternary boride series M1.5Rh5.5B3 (M = Cr, Mn, Fe, Co, Ni) were investigated by first principles DFT calculations. The calculated crystallographic lattice parameters corroborate well with the experimental results of the reported Fe1.3Rh5.7B3 single crystal. In the most stable structural model used, Fe-dumbbells as well as isolated Fe-atoms exist. From spin polarised calculations, ferromagnetism is found for the members with M = Fe, Co, while ferrimagnetism is more stable for Mn1.5Rh5.5B3 and Pauli paramagnetism is more stable for M = Cr, Ni. The total magnetic moment per formula unit for the M = Mn, Fe and Co phases is calculated to be 3.32, 5.00 and 3.26 μB, respectively. According to COHP chemical bonding analysis, Rh-B contacts are mainly responsible for the structural stability, while Rh-M interactions influence the magnetic behavior of these complex borides. [ABSTRACT FROM AUTHOR]

The article analyzes the green crystal structures of the inorganic compound trans-tetraamminedibromidochromium(III) trans-diamminetetrabromidochromate(III). It describes the coordination between the octahedral cations and anions of the compound through the interactions of nitrogen, hydrogen and bromide hydrogen bonds as well as its crystal packing showing a distorted CsCl-type lattice. It also considers the compound as the first real mixed ammine-acido chromiumIII cation-anion complex compound.

It has been shown using X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy, and elemental analysis that phase-pure VB2 with an average particle size in the range 20–35 nm can be prepared in the temperature range 595–930°C by reacting vanadium(III) chloride and sodium borohydride in the molar ratio 1 : 10 in an argon atmosphere for 14–28 h. [ABSTRACT FROM AUTHOR]