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In this paper, the microstructure and mechanical properties of Al-6.5Si-5.5Cu-0.2Zr-0.01Sr-0.06Ti-0.2Ce cast aluminum alloys were investigated in multistage solid solution systems. The microstructure of the alloy was characterized using an optical microscope (OM), scanning electron microscope (SEM), energy-dispersive spectrometer (EDS), x-ray diffraction (XRD) and transmission electron microscope (TEM), respectively. The hardness and conductivity of the alloy were measured using a Vickers hardness and eddy current conductivity testers, respectively, and the tensile properties were described by a drawing machine. The results showed that the mechanical properties of the alloy are the worst under the four-stage solid solution system (G1). With the increase in multistage solution temperature and holding time, θ phase (Al2Cu) was gradually dissolved into α-Al matrix to enhance the effect of dislocation strengthening. When the solution temperature reached 510 °C, the mechanical properties of the alloy were the best, and the tensile strength and elongation were increased to 354.90 MPa and 9.02%, respectively. With the increase in temperature, eutectic Si agglomeration and large area of insoluble phase between metals were found, resulting in the decrease in mechanical properties. [ABSTRACT FROM AUTHOR]

Novel HEAp-Ti/Al laminated composites embedded with particles of the high-entropy alloy Al0.5CoCrFeNi (HEA) were fabricated by vacuum hot-press sintering at 730 °C. The phase composition and microstructure of the composites were studied with X-ray diffractometer (XRD), scanning electron microscope SEM, energy dispersive spectrometer (EDS), transmission electron microscope (TEM), and electron backscattering diffraction (EBSD) techniques. At this temperature, it has been observed that Al3Ti intermetallic compound is the favored phase and the reaction results in the dispersion of Al3Ti in the original Al layer. A large number of interfaces are formed between Al3Ti and Al. The deformed Al3Ti grains are concentrated in the interface near the Ti side. The mechanical properties, including tensile and compressive properties at room temperature, were analyzed. The tensile test results indicate that the composite exhibited an average tensile strength of 258 MPa and an average yield strain of 9.86%. Compression test results show that when a load perpendicular to the layer is applied, the yield strain and yield stress of the material are 9.67% and 474.09 MPa, respectively. Moreover, under a load parallel to the layer, the material fails due to interfacial debonding. [ABSTRACT FROM AUTHOR]

The structure and mechanical properties of non-equiatomic Al8Co30Cr18Fe9Ni31Nb4, Al8Co30Cr18Fe9Ni31Nb2Ti2 and Al8Co30Cr18Fe9Ni31Ti4 high entropy alloys (HEAs) were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), hardness and tensile testing. TEM and XRD analyses revealed the formation of γ''-Ni3Nb/γ (FCC), double FCC and γ'-Ni3Al/γ (FCC) structure for as-cast Al8Co30Cr18Fe9Ni31Nb4, Al8Co30Cr18Fe9Ni31Nb2Ti2 and Al8Co30Cr18Fe9Ni31Ti4 HEAs, respectively. The hardness and yield strength values were found to increase with the addition of Nb while the ductility of alloys increased with the increase in Ti concentration, significantly. The as-cast Al8Co30Cr18Fe9Ni31Ti4 alloy exhibited an excellent combination of ultimate tensile strength of 844 MPa and an elongation of 29.8% due to the coherent phase relation between γ' precipitates and γ matrix. The fractured surfaces of as-cast Al8Co30Cr18Fe9Ni31Nb4, Al8Co30Cr18Fe9Ni31Nb2Ti2 and Al8Co30Cr18Fe9Ni31Ti4 HEAs showed typical dimple type ductile fracture under tension test. [ABSTRACT FROM AUTHOR]

In this paper, the hot deformation behavior of A357 alloy was investigated by hot compression tests. Isothermal hot compression simulation tests for A357 alloy were carried out at the conditions of deformation temperature of 350-470 °C, strain rate of 0.001-10 s−1 and engineering strain of 50%. Based on the Prasad instability criterion and dynamic material model, the hot processing maps of A357 alloy were constructed. The microstructure of compressed samples at different areas of the hot processing map was characterized by metallographic and scanning electron microscope and transmission electron microscope. The experimental results showed that the unstable processing zone of A357 alloy was mainly distributed in the high strain rate (10 s−1) and low-temperature (350, 380 °C) region. With an increase in the strain, the unstable zone expanded from low temperature to high temperature (470 °C). The ideal deformation conditions were deformation temperatures of 380-410 °C and strain rates of 0.001-0.01 s−1, and deformation temperatures of 440-470 °C and strain rates of 0.01-1 s−1. When the A357 alloy was extruded with the optimal hot processing parameters, the results suggested that hot extrusion could make the microstructure uniform and fine, thereby improving mechanical properties, especially when the elongation was up to 19.5% higher than the as-cast A357 alloy. [ABSTRACT FROM AUTHOR]

There has been great attention on high-entropy alloys (HEAs) over the past decade. Unlike conventional alloy systems, HEAs commonly include at least five principal elements with equiatomic or near-equiatomic ratio. HEAs with their superior mechanical, magnetic, and thermal properties are promising materials for critical engineering applications. Medium-entropy alloys (MEAs), which consist of less than five principal elements, have very similar structural features with HEAs such as robust thermodynamic stability and exceptional mechanical performance. The insights of MEAs have not been fully revealed yet. In the present study, novel MEAs (Cu20Ni20Al30Ti30, Cu25Ni25Al25Ti25, Cu34Ni22Al22Ti22, and Cu35Ni25Al20Ti20) have been designed using thermo-physical calculations and Thermo-Calc software. These MEAs were then produced using copper heart arc melting and suction cast into cylindrical rods with 3 mm diameters. X-ray diffraction (XRD), optical microscope (OM), transmission electron microscope (TEM), scanning electron microscope (SEM), and energy-dispersive spectroscopy (EDS) were used for structural characterization. The corresponding results reveal that the Cu20Ni20Al30Ti30, MEA, consists of a body-centered cubic (BCC-B2) phase with intermetallic compounds (ICs), whereas Cu25Ni25Al25Ti25 has single BCC-B2 phase. When the amounts Cu and Ni are increased, system drives itself toward a face-centered cubic (FCC) structure. A dual BCC and FCC composite Cu35Ni25Al20Ti20 has been detected as the most promising MEA among the others with 820 and 1338 MPa measured yield and compressive strength, respectively. [ABSTRACT FROM AUTHOR]

A cost-effective iron-rich non-equiatomic Fe 50 Mn 20 Al 15 Ni 10 Co 5 medium entropy alloy (MEA) was synthesized by vacuum induction melting. The as-cast alloy exhibits a multiphase microstructure with the ordered B2 (a= 2.90 ± 0.01 Å), disordered body-centred cubic (BCC) (a= 2.89 ± 0.01 Å) and face-centred cubic (FCC) (a= 3.61 ± 0.02 Å) phases. X-ray diffraction (XRD) and transmission electron microscope (TEM) were used to confirm the structure of the evolved phases. The columnar dendrites having a width in the range of 120–300 µm were observed in the as-cast structure. The formation of Ni-Al rich B2 precipitates in the BCC matrix was confirmed based on detailed microstructural characterization using scanning electron microscope (SEM) and TEM. The phase separation in the form of modulated structure of ordered B2 and disordered BCC phase was related to the spinodal decomposition. The formation of the FCC phase at and near the grain boundaries is linked to simultaneous nucleation and growth mechanisms, which occur during the solidification. The as-cast alloy has shown an average compressive yield strength of ∼1250 MPa and ultimate strength of ∼1675 MPa, along with a compressive strain of ∼42%. The optimum balance of strength and ductility is achieved due to the formation of the hard (B2, BCC) and soft (FCC) phases and their interplay during the deformation process. These encouraging results of the alloy in the as-cast state have provided the direction to design and develop such economically viable alloys, which could be produced at industrial scale. • A novel cost-effective Fe 50 Mn 20 Al 15 Ni 10 Co 5 MEA was synthesized by vacuum induction melting. • Alloys exhibits two phase structure of BCC and FCC in as-cast state. • The modulated structure of B2 and BCC was related to spinodal decomposition. • The optimum balance of strength and ductility is achieved in the alloy. [ABSTRACT FROM AUTHOR]

Oxide dispersion strengthened tungsten (ODS-W) alloys are promising plasma facing material in future fusion reactors. In this study, composite powders of W-Er 2 O 3 were prepared by co-deposition method and hydrogen reduction, and then consolidated by spark plasma sintering (SPS). Microstructure evolution during co-deposition process was investigated using X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM) and Fourier transform infrared spectrometer (FTIR). Also, simulation using DMol3 module in Materials Studio was carried out to understand the co-deposition mechanism. The results showed that H+ of W-OH bond in white tungstic acid was replaced by Er3+ due to coordination reaction during co-deposition process, leading to formation of ring-like chelate of (WO) n Er. This indicates that doping of Er3+ was achieved at a molecular level. Consequently, Er 2 O 3 particles were relatively uniformly distributed in W-Er 2 O 3 alloy, and the hardness and compressive strength reached 627 ± 19 HV and 1640 ± 40 MPa, respectively. • Thermodynamic diagram of W-H 2 O was calculated to optimize co-deposition process. • Co-deposition mechanism was analyzed by simulation and experimental methods. • W-Er 2 O 3 alloy was prepared by co-deposition method and two-step SPS. • Er 2 O 3 particles were relatively uniformly distributed in alloy. • Hardness and compressive strength reached 627 HV and 1640 MPa, respectively. [ABSTRACT FROM AUTHOR]

Powder metallurgy Cu–1Cr–0.65Zr (wt%) alloy was fabricated using Cu, Cr, and ZrH 2 powders as initial materials by hot pressing at 950 °C for 4 h under 27.7 MPa. Microstructure was observed by scanning electron microscope (SEM) and transmission electron microscope (TEM). Mechanical and electrical properties were also analyzed. It was found that an appropriate heating treatment could result in the formation of fine and homogeneously dispersed coherent nano-precipitates, relative to Cr phase with BCC structure and Cu 5 Zr.The aging treatment induced the first increase and then decrease of hardness with the prolongation of aging time. The highest hardness of 141 HV was achieved when aging at 450 °C for 4 h, following the strength of 397 MPa with an elongation of 23%. However, the electrical conductivity was only 78.3% IACS (International Annealing Copper Standard). It was determined that the effect of Cr particles on strength was more important than that of Cu 5 Zr. [ABSTRACT FROM AUTHOR]

Aggregation of Y 2 O 3 particles with relatively large size along grain boundaries is a main limiting factor for performance improvement in W–Y 2 O 3 alloys. In order to tailor the distribution and achieve size refinement of Y 2 O 3 dispersoids, W–Y 2 O 3 alloy was prepared using ball milling with extended milling time and subsequent spark plasma sintering (SPS) in this study. Microstructure evolution of Y 2 O 3 during the preparation process was characterized in detail using X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). Mechanical properties of SPSed alloy were evaluated in terms of microhardness, three-point bending and compression tests. Structure transformation of Y 2 O 3 from BCC to FCC during the process of ball milling and subsequent sintering was first identified in W–Y 2 O 3 alloy in this study. Compared with the raw micron sized Y 2 O 3 powders, the transformed Y 2 O 3 dispersoids experienced significant size refinement. Around 76% of the nanosized Y 2 O 3 dispersoids were distributed inside grain interior, and they exhibited semi-coherent relationship with tungsten matrix. These microstructural characteristics contributed to the high compressive strength of 1804.2 MPa and microhardness of 625.7 HV in the SPSed W–Y 2 O 3 alloy. • W–Y 2 O 3 alloy were prepared by extended ball milling and SPS. • Structure transformation of Y 2 O 3 from BCC to FCC was identified in W–Y 2 O 3 alloy. • Y 2 O 3 also experienced size refinement and 76% of them were inside grain interior. • The nanosized Y 2 O 3 exhibited semi-coherent relationship with tungsten matrix. • Y 2 O 3 dispersoids contributed to improved strength mainly through grain refinement. [ABSTRACT FROM AUTHOR]

• The secondary acicular β-phase appeared after a 650 °C–1000 h aged process and significantly increased in quantity for 3000 h. • The morphology and quantity of the primary β phase changed significantly with the prolonged aging time. Taking the GH783 alloy bolt of intermediate pressure main stop valve used in 1000 MW ultra-supercritical unit as the research object, the optical microscope (OM), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffractometer (XRD) and mechanical performance tests were carried out to study the microstructure transformation and mechanical properties of GH783 alloy bolts at different aging stages under 650 °C aging environment. The results showed that the secondary needle β phase began to appear in the bolts aged for 1000 h, and the density of secondary β-phases in bolts aged for 3000 h significantly increased. When the aging time reached up to 20,000 h, the secondary β phase coarsened significantly. At the same time, as the aging time prolonged, the morphology and quantity of the primary β phase changed significantly. In terms of mechanical properties, the tensile strength and impact toughness of the bolts gradually decreased. This was due to the growing γ' phase, the formation of Ni 5 Al 3 phase and the Nb-rich Laves phase in the structure during the aging process. [ABSTRACT FROM AUTHOR]

Serration behavior is a kind of plastic instability phenomenon of materials, which widely exists in the high-entropy alloys and has influence on microstructure and mechanical properties. In this work, the microstructure and mechanical properties of a NiCrFeCoMn high-entropy alloy (HEA) were studied under high-speed impact. The microstructure of a NiCrFeCoMn HEA were investigated by optical microscope (OM), scanning electron microscope (SEM), electron backscatter diffraction (EBSD), and transmission electron microscope (TEM). The dislocation density increased with the true strain at high-strain-rate deformation, and the dislocations can be hindered and released continually by the twin layers, resulting in serration on the true stress—true strain curve. When values of the strain rates are 1250, 2000 and 4800 s−1, the yield strength of the deformed NiCrFeCoMn HEA are 510, 525 and 680 MPa, respectively. Moreover, the fluctuation of the serration became more serious with the increasing of the strain rate. Compared with the as-cast NiCrFeCoMn HEA, the true stress—true strain curve of the deformed NiCrFeCoMn HEAwas smoother. [ABSTRACT FROM AUTHOR]

In this paper, the temperature sensitivity of mechanical properties and microstructure of the additive manufactured Ti-6Al-4V alloy via selective laser melting was investigated in the deformation temperature range between room temperature (RT) and 550 °C. Mechanical properties and microstructure were characterized by the means of tensile testing, optical microscope, scanning electron microscope and transmission electron microscope. The results show that the ultimate tensile strength (UTS) of the experimental Ti-6Al-4V alloy exhibits two-stage temperature sensitivity, which is reflected in the fact that the temperature sensitivity of UTS below 500 °C is conventional, whereas, the UTS decreases drastically from 834 MPa to 562 MPa as the temperature increases from 500 °C to 550 °C. Compared with the Ti-6Al-4V alloys prepared by conventional processing methods and other additive manufacturing methods, this experimental Ti-6Al-4V alloy exhibits a competitive strength below 500 °C and possesses excellent comprehensive mechanical properties at RT. The analysis shows that the microstructure is composed of α′ martensite with plenty of twinning structures when the as-built samples are deformed below 500 °C. However, above 500 °C, martensite gradually transformed into equilibrium α phase, the microstructure changed from acicular to lamellar, and β and α 2 (Ti 3 Al) appear due to the elemental distribution homogenization and martensite decomposition, which account for the dramatic decrease of the tensile strength of the experimental Ti-6Al-4V alloy above 500 °C. Unlabelled Image • SLM Ti-6Al-4V samples deformed below 500 °C had excellent tensile strength. • α′ martensite, twins and dislocations played a significant role on tensile properties. • The ultimate tensile strength of the alloy exhibited two-stage temperature sensitivity. • β phase and α 2 phase precipitated in the samples which were deformed above 500 °C. [ABSTRACT FROM AUTHOR]