1. Quantum dynamics of polyatomic dissociative chemisorption on transition metal surfaces: mode specificity and bond selectivity.
- Author
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Jiang, Bin, Yang, Minghui, Xie, Daiqian, and Guo, Hua
- Subjects
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METALLIC surfaces , *QUANTUM theory , *POLYATOMIC molecules , *CHEMISORPTION , *TRANSITION metals - Abstract
Dissociative chemisorption is the initial and often rate-limiting step in many heterogeneous processes. As a result, an in-depth understanding of the reaction dynamics of such processes is of great importance for the establishment of a predictive model of heterogeneous catalysis. Overwhelming experimental evidence has suggested that these processes have a non-statistical nature and excitations in various reactant modes have a significant impact on reactivity. A comprehensive characterization of the reaction dynamics requires a quantum mechanical treatment on a global potential energy surface. In this review, we summarize recent progress in constructing high-dimensional potential energy surfaces for polyatomic molecules interacting with transition metal surfaces based on the plane-wave density functional theory and in quantum dynamical studies of dissociative chemisorption on these potential energy surfaces. A special focus is placed on the mode specificity and bond selectivity in these gas–surface collisional processes, and their rationalization in terms of the recently proposed Sudden Vector Projection model. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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