Search

Thermal interface materials (TIMs) used to fill the gaps between chip and heat sink are one of the most important materials for electronic packaging. Low thermal resistance is the key to achieving high heat dissipation efficiency. However, most studies only focused on how to enhance the thermal conductivity of the gel TIMs and ignored the thermal resistance, which is significantly influenced by the rheological properties. In this work, we aimed to investigate the effects of in situ modification of aluminum fillers on the rheological properties and thermal resistance of the gel TIMs. Six modifiers were compared for their ability to improve the compatibility between aluminum fillers and silicone oil. The rheological results showed that the gel TIM modified with 0.170 wt% dodecyl trimethoxysilane had the best rheological properties, including the lowest viscosity and yield stress, the weakest Payne effect, and the shortest relaxation time. The thermal resistance measurements further verified that the bond line thickness and thermal resistance of gel TIMs were determined by the rheological properties. This work provides a reference for the formulation design and process optimization of gel TIMs. [ABSTRACT FROM AUTHOR]

Increased demand on the mechanical and thermal properties on the thermal interface and die attach material creates a demand for materials with tailored material properties. Solder matrix fiber composites (SMFCs) have been shown to address these challenges, but have, so far, required complicated procedures and components. In this paper, we present the fabrication of a new type of SMFC based on commercially available fiber networks infiltrated with Sn–Ag–Cu alloy (SAC305) or indium using equipment for large-volume production. The composite material exhibits similar thermal properties compared to pure solder, and mechanical properties that can be tailored toward specific applications. We also show that the handling properties of the SMFC allows it to be used in process flows where multiple reflow cycles are required and can achieve a well-defined bond line thickness (BLT) and good bonding using fluxless reflow under pressure. [ABSTRACT FROM AUTHOR]

Thermal interface materials (TIMs) play a major role in the performance of semiconductor devices by optimizing the thermal contact between device and heatsink. Their influence is further increasing with the usage of novel chip materials such as SiC and GaN. In this methodology study, we compared five of the most established evaluation methods for solid TIMs with each other: transient plane source, LaserFlash, DynTIM, TIMA, and an application-oriented $R_{\mathrm{ th}}$ measurement system. We investigated a wide range of typical TIMs in order to explore the limits of the different measurement systems. The results show that, despite existing norms, the used characterization method has a significant influence on the measured thermal conductivity. We also show that the temperature and pressure dependence has a significant influence on the thermal performance of TIMs and that these data need to be included in device specifications. Additionally, detailed error analysis and discussion about sample selection, error influence, and measurement effort for the presented methods are given. [ABSTRACT FROM AUTHOR]

A reliable thermal interface material (TIM) typically has a low storage modulus ( \textG^\prime ) and a tan( $\delta$ ) less than one; these mechanical properties are crucial for minimizing contact resistance ( \mathbf {R}_{\mathbf {c}} ). This paper demonstrates the correlation between storage modulus ( \textG^\prime ) and the crosslink density of silicone gels. Formulations span between 0.30 and 1.00 hydride to vinyl (H:Vi) ratios for the vinyl terminated and hydride pendent polymers used in the gel. These gels are tailored for TIM applications by adding highly conductive particles to improve thermal conductivity. During this study, when 80 wt% conductive filler was added to gels with a 0.6 H:Vi ratio, the \textG^\prime increased by 6025%. In order to minimize \textG^\prime , the crosslinker in the formulation was replaced with a chain extender. With this formula substitution, the modulus of the filled gel can be successfully lowered to the original value of the unfilled gel while maintaining the crucial properties of a reliable TIM. In effect, it is possible to independently optimize the thermal conductivity of a TIM while creating a compliant gel that maintains surface contact and minimizes contact resistance. [ABSTRACT FROM AUTHOR]