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Xylan is primarily found in the secondary cell wall of plants providing strength and integrity. To take advantage of the reinforcing effect of xylan in papermaking, it is crucial to understand its role in pulp fibers, as it undergoes substantial changes during pulping. However, the contributions of xylan that is added afterwards (extrinsic) and xylan present after pulping (intrinsic) remain largely unexplored. Here, we partially degraded xylan from refined bleached softwood kraft pulp (BSKP) and adsorbed xylan onto BSKP. Enzymatic degradation of 1 % xylan resulted in an open hand sheet structure, while adsorption of 3 % xylan created a denser fiber network. The mechanical properties improved with adsorbed xylan, but decreased more significantly after enzymatic treatment. We propose that the enhancement in mechanical properties by adsorbed extrinsic xylan is due to increased fiber-fiber bonds and sheet density, while the deterioration in mechanical properties of the enzyme treated pulp is caused by the opposite effect. These findings suggest that xylan is decisive for fiber network strength. However, intrinsic xylan is more critical, and the same properties cannot be achieved by readsorbing xylan onto the fibers. Therefore, pulping parameters should be selected to preserve intrinsic xylan within the fibers to maintain paper strength. [Display omitted] [ABSTRACT FROM AUTHOR]

Many materials of everyday use are fibrous and their strength is important in most applications. In this work we study the dependence of the strength of random fiber networks on structural parameters such as the network density, cross-link density, fiber tortuosity, and the strength of the inter-fiber cross-links. Athermal networks of cellular and fibrous type are considered. We conclude that the network strength scales linearly with the cross-link number density and with the cross-link strength for a broad range of network parameters, and for both types of networks considered. Network strength is independent of fiber material properties and of fiber tortuosity. This information can be used to design fiber networks for specified strength and, generally, to understand the mechanical behavior of fibrous materials. [ABSTRACT FROM AUTHOR]

Inspired by the excellent mechanical reinforcement effect of carbon nanotubes (CNTs) and the strong interactions between metal ions and graphene oxide (GO), ultra-robust, and high-toughness GO papers were fabricated via the synergistic reinforcement of CNTs and copper ions (Cu2+). The freestanding and flexible CNT/GO nanocomposite papers with a layered structure were readily fabricated by the vacuum-assisted filtration. After being cross-linked by a trace amount of copper ions (Cu2+), the tensile strength, elastic modulus and toughness of the modified GO papers increase 409.7%, 81.5% and 188.2%, respectively, when compared with the pure GO papers. It is revealed by scanning electron microscope and in situ Raman spectroscopy analysis that the CNTs and Cu2+ hindered the interlayer slippage between the GO sheets and promoted the stress transfer during the tensile loading. Considering the tunable and versatile properties of this hybrid carbon nanomaterial, this study will open an avenue for integrating rGO or GO papers to various applications. Image 1 [ABSTRACT FROM AUTHOR]

Highlights • Cellulose nanofibrils(CNF)/graphene nanoplatelets(GnP) hybrid papers were prepared with a simple water-based method. • CNF and hot-pressing efficiently enhance the mechanical properties of the GnP paper. • The CNF reinforced GnP paper demonstrates high electrical conductivity. • Mechanical flexibility and electrical conductivity of the papers are controllable. Abstract Mechanically flexible and high electrically conductive multilayered graphene nanoplatelets (GnP)/cellulose nanofibrils (CNF) composite papers were successfully fabricated through a vacuum-assisted self-assembly technique. The morphology observation showed that highly disassembled CNF were achieved by high-pressure homogenization of water-based cellulose slurry, and the homogenized CNF uniformly interpenetrated within the microporous GnP paper network. The analyses of mechanical properties and morphology suggest that the CNF effectively bridged the adjacent GnP sheets and efficiently strengthened the GnP papers by producing strong GnP/CNF interfacial interactions resulting from mechanical interlocking, van der Waals forces and hydrogen bonds between the GnP and the CNF. Moreover, it was noticed that hot-pressing pressure is necessary to be applied on samples to produce stronger papers with higher electrical conductivity. As the CNF loading reached 60 wt%, the Young's modulus and tensile strength of the hot-pressed GnP/CNF hybrid paper were significantly increased to 9.1 GPa and 57.7 MPa, respectively. In addition, a high electrical conductivity of 26.8 S/cm was retained for the paper with 30 wt% CNF. Our approach provides a facial and eco-friendly fabrication route to produce strong and highly conductive GnP/CNF papers which are of great practical appeal as a new type of nanomaterials in various fields. [ABSTRACT FROM AUTHOR]

The integrity of materials containing packaging (natural or synthetic polymers) is essential to keep the aseptic condition of commercialized products (health care products, food and pharmaceuticals). The objective of this paper was to study gamma radiation effects (25 kGy, 40 kGy and 50 kGy) on the main properties of paper and multilayer films (polyester and polyethylene). Paper and multilayer films are components of packaging (pouches) for radiation sterilization containing medical equipment or products. Paper was the more radiation sensitive among the studied materials and radiation effects were more pronounced at brightness, pH, tearing resistance, bursting strength and tensile strength. Concerning plastic film, no pinholes were induced by radiation and the effects on the tensile strength were not significant. Although the seal strength packaging (pouches) decreased according to increasing dose, the sealing integrity was preserved. [ABSTRACT FROM AUTHOR]

During the last two decades, cellulose nanofibres (CNF) have emerged as a promising, sustainable reinforcement with outstanding potential in material sciences. Though application of CNF in papermaking is recent, it is expected to find implementation in the near future to give a broader commercial market to this type of cellulose. The present review highlights recent progress in the field of the application of cellulose nanofibres as additives in papermaking. The effect of CNF addition on the wet end process is analysed according to the type of pulp used for papermaking. According to the literature consulted, improvement in paper’s overall properties after CNF addition depended not only on the type and amount of CNF applied, but also in the pulp’s origin and treatment. Bulk and surface application of CNF also presented significant differences regarding paper’s final properties. This review also revises the mechanisms behind CNF reinforcing effect on paper and the effect of chemically modified CNF as additives. [ABSTRACT FROM AUTHOR]

Rice straw pulps produced under different conditions were subject to near infrared (NIR) spectroscopy. At the same time, samples from those pulps were used to make handsheets, whose mechanical properties were measured. These values and those of brightness were successfully fitted to the pulping variables. Relating them to the NIR spectra, we found valid correlations for all parameters except the burst index, concluding that NIR spectroscopy could be used as an economical, timesaving and non-intrusive way to predict the mechanical strength of pulps before the paper sheet is made. [ABSTRACT FROM AUTHOR]

Highlights: [•] In this study we prepare Ag-NPs and Ag @ TiO2 composites as antibacterial nanomaterials. [•] Paper coated by PS nanocomposites containing Ag-NPs and Ag @ TiO2 composites. [•] We conclude that the prepared paper sheet characterize by SEM, EDAX and mechanical properties was evaluated. [•] Paper sheet coated by PS nanocomposites exhibited antimicrobial effect. [•] These Paper sheet can be used as food packaging materials. [ABSTRACT FROM AUTHOR]

Highlights: [•] Modified nanofibrillated cellulose (NFC) added in wet-end paper process for the first time. [•] Mechanical reinforcement and decreased air permeability with both modified and unmodified NFC. [•] Strong diminution of water absorption (divided by more than 6) with modified NFC. [•] Multi-level properties: hydrophobicity, mechanical reinforcement and air permeability. [Copyright &y& Elsevier]

Abstract: The effects of glycerol concentration and coating weight on biopolymer-coated paper properties were investigated using response surface methodology. Tests were run on the coated papers to determine water vapor barrier and mechanical properties. Coating weight was the most important parameter affecting water vapor permeability (WVP). Conversely, increasing coating weight led to a decrease in WVP and to an increase in tensile strength (TS) of the resulting coated papers. The papers coated with sodium caseinate (NaCAS) exhibited lower WVP values than those coated with other biopolymers. The TS of the papers coated with hydroxypropylmethylcellulose (HPMC) and chitosan was not affected by the glycerol concentration. HPMC-coated papers were higher in TS and %E than the other coated papers. For all types of coated paper, a maximum level of coating weight and level of glycerol concentration within range of 18.72–26.11% were found to be optimum for minimum WVP and maximum TS and %E. [Copyright &y& Elsevier]

Abstract: The damage to historical documents and books caused by the acidic character of paper is often manifested as a complete loss of their mechanical properties. Deacidification and restoration of archived paper objects require knowledge of the long-term behaviour of paper before and after repair actions. Our study was focused on the investigation of mechanical properties (tensile strength, stretch, tensile index, zero-span tensile strength, folding endurance) of original papers (one alkaline and three different acidic samples) exposed to five methods of dry-heat and moist-heat accelerated ageing. The degree of paper deterioration upon ageing was significantly influenced by the temperature and relative humidity, along with the intrinsic chemistry of the individual paper samples. The correlation matrix evaluated at a 95% confidence level for tensile strength, stretch, tensile index and zero-span showed linear correlations between these mechanical properties for all the paper samples. However, a linear dependence of folding endurance on zero-span tensile strength was found only for alkaline paper, which revealed the highest resistance to the accelerated ageing tests. In addition, the concentration of paramagnetic semiquinone species in the acidic lignin-containing paper samples was monitored by Electron paramagnetic resonance spectroscopy. [Copyright &y& Elsevier]

Tensile testing was used to measure the mechanical properties of paper at various orientations relative to the fiber alignment of paper. New, artificially aged, and naturally aged paper were shown to behave as orthotropic materials, as shown by the orientation dependence of the Young's modulus, E. The Young's modulus data could be fit to a simplified equation, indicating the shear modulus is relatively insensitive to the specific orientation. The shear modulus as measured by ultrasonic measurements was similar to that measured by fitting the modulus vs orientation data obtained by tensile testing to the orthotropic equation. The inelastic tensile strength could also be described by a simple non-linear equation, and there was more deviation of the data from this prediction for brittle papers than for non-brittle papers. The extent of fiber orientation (E x /E y) could be inferred by either the Young's modulus or the tensile strength, TS, i.e. E x /E y ≈ TS x /TS y. The measured strains were lowest for brittle paper. All brittle papers gave a strain to failure <1% whereas the non-brittle papers gave a strain to failure >1%. • Paper was shown to behave as an orthotropic material for new, artificially aged, and naturally aged papers. • The Young's modulus versus fiber orientation data could be fit to a simplified equation. • The shear modulus is relatively insensitive to the fiber orientation. • The Ramberg-Osgood equation can be used to describe the stress-strain measurements. • All brittle papers gave a strain to failure <1% whereas the non-brittle papers gave a strain to failure >1%. [ABSTRACT FROM AUTHOR]

Aramid fibers exhibit impressive mechanical properties, electrical insulation properties, and chemical stability. However, physical properties of the aramid paper are poor because of the chemical inertness and smooth surface of aramid fibers. This study reports a simple and efficient method for substantially improving the performance of the para-aramid/meta-aramid composite paper by introducing the N , N -dimethylacetamide (DMAc)/LiCl solution to induce partial dissolution or by adding the DMAc/LiCl/para-aramid solution to induce regeneration. Experimental results state that the tensile strength, specific strength, folding resistance, and interlayer bonding strength of the aramid paper are increased by 2.17, 2.13, 34.7, and 9.39 times, respectively, because of the dense and compact structure of the paper. Furthermore, the water resistance of the paper was also considerably improved. After immersing the paper samples in water for 24 h, their moisture absorption rate decreased to approximately 54% from approximately 143% for the original paper. Results indicate that partial dissolution/regeneration welding is a viable method for the efficient reinforcement of the aramid composite paper, providing additional possibilities for manufacturing the high-performance aramid paper-based materials. Unlabelled Image • The para-aramid/meta-aramid composite papers, exhibiting amazing mechanical strengths, were obtained. • The performance of the para-aramid/meta-aramid composite paper was improved by adding N , N -dimethylacetamide/LiCl solution. • The moisture absorption of aramid composite paper decreased from approximately 143% for the original paper to approximately 54%. [ABSTRACT FROM AUTHOR]