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We perform an ex-ante life cycle assessment, integrating cradle-to-gate greenhouse gas emissions into an off-grid energy system model. By applying a multi-objective optimization, minimizing both costs and carbon dioxide equivalent (CO 2 e) emissions, we find the Pareto boundary between these two goals. As a case study, we chose the power supply to an astronomical observatory in Chile, using mostly solar power and energy storage in batteries and hydrogen. We compare the ex-ante study to a prior ex-post life cycle assessment, and furthermore dive into sensitivities of our model regarding component lifetimes and costs. We find (i) low-hanging fruit in lowering emissions with small cost increases, (ii) ex-ante life cycle assessments' possibility to find less CO 2 e intensive power systems compared to ex-post conducted studies, (iii) a pronounced sensitivity of the optimization model on assumed lifetimes of energy storage components. This study shows the importance of including life cycle CO 2 e emissions into the optimization objective of energy system models. This method uncovers the environmental and economic trade-offs associated with high shares of renewable energies in off-grid energy systems. • We integrate life cycle assessment (LCA) into an off-grid energy system optimization. • The applied case study powers a remote astronomical telescope in Chile. • A multi-objective optimization finds Pareto curves at varying costs and lifetimes. • Low-hanging fruit shows low additional system costs to reduce CO 2 e impacts. • In contrast, a separate LCA did not find such trade-offs in costs and CO 2 e emissions. [ABSTRACT FROM AUTHOR]

• Substitution factors for forest products for the Canadian context were developed. • Substitution factors ranging from 0.51 to 0.91 tC/tC were found. • They will lead to more accurate assessments of the forest GHG mitigation potential. • These factors will help governments to manage forest and fight climate change. Evaluating the climate change mitigation potential of the forest sector requires a holistic approach based on forest carbon (C) sequestration, C storage in harvested wood products (HWP) and substitution on markets. High uncertainty is associated with substitution factors, that express avoided fossil greenhouse gas (GHG) emissions from the use of forest-based products in replacement of GHG-intensive materials and fossil fuels. Few studies have focused on the development of substitution factors in Canada, resulting in the use of unrepresentative generic data. Here, we provide a framework to reduce uncertainties related to substitution factors for primary wood products in a Canadian context. A life cycle assessment framework is used to quantify fossil GHG emissions for a baseline and a wood-intensive scenario. For solid product substitution, we focused on the construction sector and analyzed a range of innovative wood buildings with steel and reinforced concrete as alternative materials. We found non-weighted averages of 0.80 tC/tC for sawnwood and 0.81 tC/tC for panels. For energy substitution, we analyzed cases with different specifications on biomass product, facility type and alternative fossil fuel source in non-residential heat production and biofuel transportation sectors. We found a non-weighted average of 0.80 tC/tC for non-residential heat production and 0.51 tC/tC for biofuel transportation, that can be interpreted as 0.91 tC/tC for heavy fuel oil, 0.69 tC/tC for light fuel oil and 0.68 tC/tC for natural gas substitution. These results provide a benchmark for substitution factors in Canada, to help guide forest management strategies for climate change mitigation. [ABSTRACT FROM AUTHOR]

Bioenergy with carbon capture and storage (BECCS) is regarded as a crucial negative emission technology (NET) in many prospective climate change mitigation scenarios that limit global warming below 2 °C. However, there is still insufficient understanding of the overall life cycle environmental performance of different BECCS configurations. Despite the fact that BECCS entails many technological combinations, the technology is still regarded as a single "black box" technology in most climate scenarios. This study presents a critical review of life cycle assessment (LCA) on a wide range of BECCS options: biomass direct-fired power generation, biomass gasification power generation, bio-hydrogen production, biomass application in industry sectors and other biomass conversion processes, such as pyrolysis and fermentation. It is evident from the review that the biomass direct-fired and gasification power plant with a 100% biomass firing ratio and the gasification-based bio-hydrogen processes have a strong potential to achieve negative emissions. However, the net negative life cycle emissions range widely among studies for each configuration due to variations in technology, LCA methodology and assumptions. Additionally, there is an insufficient assessment of comprehensive environmental impacts for BECCS systems other than GWP, making it still unclear about the trade-offs between the benefit from climate change mitigation and potential negative impacts. Main recommendations for improving LCA on BECCS include developing a generalized guideline and standardization for BECCS LCA, conducting LCAs with comprehensive impact categories, focusing on BECCS configurations being overlooked, considering the impact of land use change and the global warming potential of biomass, and extending LCA in both temporal and spatial dimension. [Display omitted] • Systematically review of life cycle assessment on BECCS systems. • Detailed review on various biomass conversion technologies. • Net negative life cycle emissions range widely among studies. • Insufficient studies of some biomass conversion pathways. • Insufficient studies on multi-environmental environment impact categories. [ABSTRACT FROM AUTHOR]

With emphasis on constructing low-carbon cities, the renovation of old communities highlights the importance of renewing rainwater management facilities. Rain garden is an exceptional Nature-based Solution for rainwater management. When applying them to renovate old communities, the carbon footprint should be considered. This study focused on renovating facilities in the Greater Bay Area and utilized the Energy Expert platform to calculate rain garden carbon footprint with the Life Cycle Assessment. The carbon reduction benefits during the operation were estimated. This study accounting the life cycle carbon footprint of the 5455 m2 rain garden was 1117.42 tCO 2 e. The carbon footprint contribution, from highest to lowest was the end-of-life phase, materials production phase, construction phase, use and maintenance phase. Regarding carbon emission inventory, waste soil landfill, fertilizer acquisition, and waste soil recycling ranked high. Transportation also accounted for a remarkable carbon emission. The rain garden showed great potential for climate change mitigation, with a total and net carbon reduction of 1927.41 and 809.99 tCO 2 e, respectively. To reduce the carbon footprint of the rain garden, we should focus on waste soil treatment and transportation. Recommendations included increasing waste soil recycling, in situ recycling and green transportation. [ABSTRACT FROM AUTHOR]

Plastics account for 4.5% of global greenhouse gas (GHG) emissions, which are hard-to-abate due to the use of fossil fuels as feedstock. Our study develops a cradle-to-gate life cycle assessment of bioethylene production, exploring 33 pathways across Brazil, the EU, and the US. It aims to understand whether substituting fossil-based ethylene with bioethylene contributes to lowering carbon emissions, and in which of the relevant bioenergy-producing regions/countries the valorisation of biofuels as feedstocks would provide a less carbon-intensive bioethylene production. Results indicate that bioethylene production through catalytic dehydration of sugarcane bioethanol in Brazil presents lowest GHG emission. This pathway could deliver up to −2.1 kg CO 2 e/kg ethylene when accounting for biogenic carbon storage in long-lived applications such as infrastructure. In contrast, beef tallow performs the poorest as a raw material, regardless of whether land-use change (LUC) emissions are considered. When biogenic carbon storage is factored out, none of the pathways outperforms conventional fossil-based steam cracking; however, some are within the fossil-based range indicating potential indirect benefits through reduced refinery utilisation. Our study underscores that biomaterials production as a climate mitigation strategy must be on par with circular economy measures and the conservation of native forestry ecosystems. These results are particularly relevant to policymakers and industries seeking to align polymer manufacturing with sustainability objectives. • Bio-ethylene cradle-to-gate GHG emissions were assessed for 33 pathways. • Sugary, starch, lignocellulosic and oily crops are raw materials for bio-ethylene. • Local specificities such as biogenic carbon storage and land-use are critical to LCA GHG emissions. • Sugarcane bioethanol dehydration route yielded 2.1 kgCO 2 e captured per of kg ethylene. • Climate mitigation and circular economy policies must be designed coherently. [ABSTRACT FROM AUTHOR]

Anthropogenic greenhouse gas emissions (GHGE) are behind climate change. In Chile, food system is the second source of GHGE. Changing Chileans dietary patterns is key to reducing such emissions. There is geographic variability in terms of dietary patterns within the country. Here we investigated the dietary GHGE in five different geographical zones, along with the main contributing food groups and socio-demographic variables. Data for 4676 individuals were obtained from the 2010–2011 National Survey of Food Consumption. The carbon footprint value of each food was obtained from studies using life cycle assessment methodology. Median and percentiles of dietary GHGE were calculated, expressed in kilograms of carbon dioxide equivalent per person per day (kgCO 2 eq/person/d) and compared among zones by Kruskal-Wallis and Dunn's tests. Logistic regression models were fitted to analyzed associations among the variables of interest and quartiles of GHGE. Diet-related GHGE ranged from 3.50 (2.34–5.12) in the North-Central Zone to 4.66 (2.89–6.69) kgCO 2 eq/person/d in the South zone. Meat accounted for 53–58% of the GHGE in all the zones, followed by dairy products with 12–13%. Higher GHGE were significantly associated with energy intake (kcal/d) in all of the zones, with high socioeconomic level in the North-Central, South and Metropolitan zones, and with urban residence in the South-Central zone. Tailored policies considering geographic variability are warranted to promote healthy and sustainable diets among the Chilean population. • Differences in dietary greenhouse gas emissions were determined among five Chilean geographical zones. • South and Metropolitan region showed the highest GHGE while North showed the lowest. • Meat and dairy were the most contributing foods in all zones. • GHGE were positively associated with energy intake in all zones & with high socioeconomic level in three zones. • The promotion of sustainable diets in Chile must consider the geographical specificities. [ABSTRACT FROM AUTHOR]

Lithium-ion batteries (LIBs) play a crucial role in driving energy transitions, particularly in electric vehicles (EVs) and energy storage systems. Forecasting LIB prices has received significant attention due to the tightening of raw material markets. Additionally, the implementation of carbon pricing policies has highlighted the need to incorporate the carbon footprint of LIBs in price evaluation. This study presents a comprehensive analysis of the carbon footprint, pricing trajectories, and forthcoming carbon pricing ramifications associated with LIBs. Firstly, the findings derived from the life-cycle carbon footprint assessment indicate that the global production volume-weighted average carbon footprint of EV battery packs spans 49.2–81.1 kgCO 2 eq/kWh, depending on the chosen end-of-life treatment. Strategic end-of-life selections, aligned with battery chemical composition, can diminish the carbon footprint by up to 46% relative to improper disposal methods. Notably, direct cathode recycling of NCA and NMC622 batteries exhibits superior environmental performance. Secondly, techno-economic analysis predicts that the mean price of EV battery packs with diverse chemical compositions will decline to $75.1/kWh by 2030, factoring in the compound annual growth rate of critical raw material prices over the past decade. LFP batteries emerge as the top economic performers. Lastly, the results reveal that monetizing a battery's carbon footprint may offset battery price reductions through learning effects. This underscores the imperative of effective recycling for curtailing the carbon footprint and ensuring the enduring economic and environmental competitiveness of LIBs. • Life-cycle carbon emissions are integrated into future battery price projections. • Direct cathode recycling provides the greatest potential for carbon reduction. • LFP might be the only lithium-ion battery to achieve the $80/kWh price target. • Cost reductions from learning effects can hardly offset rising carbon prices. • Recycling is needed for climate change mitigation and battery economics. [ABSTRACT FROM AUTHOR]

Wood and other bio-based building materials are often perceived as a good choice from a climate mitigation perspective. This article compares the life cycle assessment of the same multi-residential building from the perspective of 16 countries participating in the international project Annex 72 of the International Energy Agency to determine the effects of different datasets and methods of accounting for biogenic carbon in wood construction. Three assessment methods are herein considered: two recognized in the standards (the so-called 0/0 method and −1/+1 method) and a variation of the latter (−1/+1* method) used in Australia, Canada, France, and New Zealand. The 0/0 method considers neither fixation in the production stage nor releases of biogenic carbon at the end of a wood product's life. In contrast, the −1/+1 method accounts for the fixation of biogenic carbon in the production stage and its release in the end-of-life stage, irrespective of the disposal scenario (recycling, incineration or landfill). The −1/+1 method assumes that landfills offer only a temporary sequestration of carbon. In the −1/+1* variation, landfills and recycling are considered a partly permanent sequestration of biogenic carbon and thus fewer emissions are accounted for in the end-of-life stage. We examine the variability of the calculated life cycle-based greenhouse gas emissions calculated for a case study building by each participating country, within the same assessment method and across the methods. The results vary substantially. The main reasons for deviations are whether or not landfills and recycling are considered a partly permanent sequestration of biogenic carbon and a mismatch in the biogenic carbon balance. Our findings support the need for further research and to develop practical guidelines to harmonize life cycle assessment methods of buildings with bio-based materials. [Display omitted] • Life cycle assessments of the same multi-residential building were carried out by experts from 16 countries. • Effects of methods and datasets of biogenic carbon accounting in wood construction were identified. • Different end-of-life scenarios (incineration, landfill, recycling) cause variations in the results. • Different interpretations of the permanence of storing biogenic carbon in landfills also cause variations in the results. • The input and output flows of biogenic carbon must be balanced to correctly assess its climate change impacts. [ABSTRACT FROM AUTHOR]

Generation of goods and services are highly dependent on the use of natural resources. Until very recently, there was an implicit belief that the physical expansion of the economic system could be unlimited, as if the planet would have conditions and time enough to recover and continue to supply resources. This belief implies a confidence in an economic system that would provide whatever is necessary for a continuous growing production and consumption. Even believing that technology alone is not enough to solve the current environmental problems, it is certain that it can collaborate to mitigate climate change and to adaptation to changes in the environment. By bringing environmental aspects into discussions, eco-innovations can affect and transform the innovation system in order to create sustainable processes. However, the main challenge towards the transition to a more sustainable, cleaner and more equitable society is to set innovation in a new context, as until very recently it only considered the economic variables. This change means to value the social and environmental dimension of the innovation. In addition to eco-innovation, Life Cycle Assessment (LCA) is spreading in the industrial environment, offering promising perspectives. LCA is considered a valuable methodology in the environmental sustainability of industry. In this context, the present study addresses LCA and its relationship with the generation of eco-innovations. Drawing on contributions from literature on eco-innovation and LCA, the paper analyses available evidence on this relationship in a context of the transition towards sustainable development. To structure the debate, the paper offers a conceptual approach and an illustrative case on international researchers' and practitioners’ perceptions on the potentially positive relationship between eco-innovation and LCA. The study gathers data in the Web of Science (WoS) Core Collection and in Scopus, in order to provide a picture of the distribution of documents retrieved from these databases, dealing with both eco-innovation and LCA topics. The paper concludes that the convergence of the eco-innovation and LCA studies is quite plausible, but at least in its initial phase, the literature that unites both themes is scarcely found in publications in the area of innovation, being more frequent in the area of engineering and management that usually addresses LCA studies. [ABSTRACT FROM AUTHOR]

Strict energy performance requirements have reduced the building's operational energy use and related environmental impact in the past decades. Consequently, the embodied impacts of buildings gained importance, and hence focussing on the life cycle impacts has become essential to further reduce the environmental impact of buildings. Life cycle assessment (LCA) is an internationally accepted method used for this purpose. Current LCA studies of buildings typically look at their whole life cycle but ignore potential changes in operational energy use due to climate change. However, the latter is expected to influence the operational energy use of buildings to a significant extent. This paper aims to improve the assessment of the operational phase by including variations in the yearly operational energy use caused by climate change and expected changes in the electricity mix as a strategy for climate change mitigation. This adapted dynamic assessment method is used to assess a Belgian office building. The results indicate that a Representative Concentration Pathway (RCP) 8.5 climate change scenario causes a decrease of 18 % for the end use of gas for heating and an increase of 32.4 % for the electricity use for cooling and ventilation. For the case study, the reduction of the environmental impact due to the decrease in gas use compensates the impact increase due to the higher electricity use. An increase in environmental impact in future would however occur if both heating and cooling are provided by electricity. Furthermore, depending on the changes that will occur in the electricity mix, the global warming potential of the office building will change by −13 % for an electricity mix dominated by renewables and by + 10 % for one with mainly production by gas compared to the situation with the current mix. However, the inclusion of a more extended list of environmental indicators shows that the overall environmental impact will only reduce by 4 % or even increase by 7 % compared to the situation with the current mix. [ABSTRACT FROM AUTHOR]

Increasing demand for land-based climate mitigation requires more efficient management of agricultural landscapes for competing objectives. Here we develop methods for assessing trade-offs and synergies between intensification and carbon-sequestering conservation measures in annual crop production landscapes using the DayCent ecosystem model and the Greenhouse Gases, Regulated Emissions, and Energy Use in Technologies (GREET) life-cycle assessment (LCA) model. We compiled county-scaled crop yields, fertilizer application rates, and tillage intensity for a corn–soybean farming case study landscape in the US state of Iowa. Using DayCent, we estimated a baseline soil organic carbon (SOC) accrual rate of 0.29 Mg C ha−1 y−1 driven by historical increases in crop productivity and reductions in tillage intensity. We then simulated the effects of management interventions targeted toward intensification (stover removal) and SOC sequestration (tillage intensity reduction and winter cover crop addition) individually and in combination. We propose a new multi-product landscape–LCA approach that analyzes marginal changes in corn grain, corn stover, and soybean production from the landscape in terms of their value for biofuel production (corn ethanol, soy biodiesel, and cellulosic ethanol from stover) and associated net displacement of conventional fossil-derived fuel use. This enables us to evaluate both intensification and sequestration effects in common CO 2 -equivalent mitigation units. We also used DayCent-simulated yields under the different land management scenarios to estimate farm-level costs and revenues. Our results show that intensification via collecting 30% of corn stover for biofuel production would increase the total greenhouse gas (GHG) mitigation potential of this landscape by 0.93 Mg CO 2 e ha−1 y−1 and provide $49 ha−1 y−1 of additional net revenue from biomass sales, but would reduce the baseline SOC accumulation rate by approximately 40%. In contrast, integrated approaches that include co-adoption of winter cover cropping and/or tillage intensity reduction would result in increased rates of SOC accumulation above the baseline, achieving simultaneous improvements in both farm profits and the overall GHG mitigation potential of the landscape. • Our LCA method compares intensification and carbon sequestration in agro-ecosystems. • Fine-scale management data benefits soil carbon modeling in corn–soy landscapes. • Harvesting corn stover increases carbon mitigation in a US Midwest study landscape. • Coadoption of natural solutions with stover harvest optimizes carbon and revenue. • This landscape assessment can inform local landowner and government decision-making. [ABSTRACT FROM AUTHOR]

The ever-increasing anthropogenic greenhouse gas (GHG) emissions worldwide make it quite challenging to meet country-specific Nationally Determined Contributions (NDC) targets. Therefore, it is evident that the existing emissions abatement measures need to be taken a step further. Internationally Transferred Mitigation Outcomes (ITMOs) are allowed in Article 6.2 of the Paris Agreement as a cooperative approach to achieving NDC goals. There is a potential to create ITMOs between Canada and China by replacing coal use in China with British Columbia (BC)'s liquefied natural gas (LNG) supply. Replacing coal with LNG in energy generation applications is a promising approach to mitigate emissions. With global and national pressures to reduce emissions, China has created a market for LNG imports to cater to its rising natural gas (NG) consumption due to the coal-to-gas source switching strategy. However, the terms under Article 6.2 requires generated ITMOs to ensure environmental integrity, support sustainable development goals, and have a robust accounting system. Therefore, the current study aims to quantify the life cycle environmental outcomes of generating ITMOs by exporting LNG from BC to Chinese end-users while integrating uncertainties and to provide policy recommendations in adherence with the requirements of Article 6.2. Different LNG export scenarios were generated in the study and environmental impacts of each scenario were assessed and compared using a life cycle assessment (LCA) framework developed by the authors. Sensitivity and uncertainty analyses were conducted to understand the impacts created by the data uncertainties in the final result. By replacing conventional coal with NG, approximately 40–45% and 26%–32% emissions reductions can be obtainable for Chinese textile and chemical industries, respectively. The highest emissions reduction of approximately 60% was observed when coal is replaced with NG for district heating. The life cycle emissions (LCE) quantification framework provided in the study provides stakeholders with a systematic approach to determine the total GHG emissions and emissions reduction potential of different LNG export scenarios. [ABSTRACT FROM AUTHOR]