1. Molybdenum oxide/nickel molybdenum oxide heterostructures hybridized active platinum co-catalyst toward superb-efficiency water splitting catalysis.
- Author
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Luu Luyen Doan, Thi, Chuong Nguyen, Dinh, Komalla, Nikhil, Hieu, Nguyen V., Nguyen-Dinh, Lam, Dzade, Nelson Y., Sang Kim, Cheol, and Hee Park, Chan
- Subjects
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MOLYBDENUM oxides , *NICKEL oxide , *MOLYBDENUM , *PLATINUM , *HYDROGEN evolution reactions , *HETEROSTRUCTURES , *DENSITY functional theory , *PHOTOELECTROCHEMISTRY , *OXYGEN evolution reactions - Abstract
[Display omitted] • An electrocatalyst based on the Pt-MoO 3 /NiMoO 4 NRs has been fabricated for industrial-grade water splitting. • The electrolyzer using Pt-MoO 3 /NiMoO 4 NRs electrodes only required 1.55 V to achieve 10 mA cm−2. • Density functional theory calculations proved that the good synergy of the MoO 3 /NiMoO 4 and Pt benefited their catalytic performance. A new catalyst has been developed that utilizes molybdenum oxide (MoO 3)/nickel molybdenum oxide (NiMoO 4) heterostructured nanorods coupled with Pt ultrafine nanoparticles for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) toward industrial-grade water splitting. This catalyst has been synthesized using a versatile approach and has shown to perform better than noble-metals catalysts, such as Pt/C and RuO 2 , at industrial-grade current level (≥1000 mA·cm−2). When used simultaneously as a cathode and anode, the proposed material yields 10 mA·cm−2 at a remarkably small cell voltage of 1.55 V and has shown extraordinary durability for over 50 h. Density functional theory (DFT) calculations have proved that the combination of MoO 3 and NiMoO 4 creates a metallic heterostructure with outstanding charge transfer ability. The DFT calculations have also shown that the excellent chemical coupling effect between the MoO 3 /NiMoO 4 and Pt synergistically optimize the charge transfer capability and Gibbs free energies of intermediate species, leading to remarkably speeding up the reaction kinetics of water electrolysis. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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