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A decrease in atmospheric CO2 partial pressure (pCO2) is considered an important prerequisite for the onset and intensification of Northern Hemisphere Glaciation (NHG). However, how the ocean sequestered missing CO2 during the NHG is still uncertain. Changes in surface productivity and deep ventilation in the Southern Ocean (SO) have been proposed to explain the variations in atmospheric pCO2 over the last eight glacial cycles, but it is unclear whether these mechanisms contributed to the decrease in atmospheric pCO2 during the NHG. Using titanium-normalized contents and mass accumulation rates of biogenic opal and total organic carbon from the International Ocean Discovery Program (IODP) Expedition 374 Site U1524A, we reconstruct the productivity in the Ross Sea, Antarctica, from 3.3 Ma to 2.4 Ma. The productivity records exhibit a long-term decreasing trend and several distinct phased evolutionary features. Specifically, the local productivity fluctuated dramatically during 3.3–3.0 Ma, decreased gradually during 3.0–2.6 Ma, and remained relatively constant during 2.6–2.4 Ma. By comparing productivity with its potential influences, we infer that the phased and long-term evolutions of productivity were mainly controlled by changes in deep ocean ventilation. Sea ice expansion might have decreased productivity during 3.3–3.0 Ma by light attenuation. Changes in eolian dust input have little effect on productivity. Further analysis revealed no coupling linkage between productivity and atmospheric pCO2, indicating that the productivity in the SO Antarctic Zone (AZ) was not the main factor controlling the atmospheric CO2 decrease during the NHG. To improve our understanding of the role of SO processes in the NHG, further studies should focus on the potential influences of deep ocean ventilation on atmospheric pCO2 in the AZ, and similar studies should also be extended to the sea area in the Subantarctic Zone. [ABSTRACT FROM AUTHOR]

A decrease in atmospheric CO2 partial pressure (pCO2) is considered an important prerequisite for the onset and intensification of Northern Hemisphere Glaciation (NHG). However, how the ocean sequestered missing CO2 during the NHG is still uncertain. Changes in surface productivity and deep ventilation in the Southern Ocean (SO) have been proposed to explain the variations in atmospheric pCO2 over the last eight glacial cycles, but it is unclear whether these mechanisms contributed to the decrease in atmospheric pCO2 during the NHG. Using titanium-normalized contents and mass accumulation rates of biogenic opal and total organic carbon from the International Ocean Discovery Program (IODP) Expedition 374 Site U1524A, we reconstruct the productivity in the Ross Sea, Antarctica, from 3.3 Ma to 2.4 Ma. The productivity records exhibit a long-term decreasing trend and several distinct phased evolutionary features. Specifically, the local productivity fluctuated dramatically during 3.3–3.0 Ma, decreased gradually during 3.0–2.6 Ma, and remained relatively constant during 2.6–2.4 Ma. By comparing productivity with its potential influences, we infer that the phased and long-term evolutions of productivity were mainly controlled by changes in deep ocean ventilation. Sea ice expansion might have decreased productivity during 3.3–3.0 Ma by light attenuation. Changes in eolian dust input have little effect on productivity. Further analysis revealed no coupling linkage between productivity and atmospheric pCO2, indicating that the productivity in the SO Antarctic Zone (AZ) was not the main factor controlling the atmospheric CO2 decrease during the NHG. To improve our understanding of the role of SO processes in the NHG, further studies should focus on the potential influences of deep ocean ventilation on atmospheric pCO2 in the AZ, and similar studies should also be extended to the sea area in the Subantarctic Zone. [ABSTRACT FROM AUTHOR]

Sharks are virtually absent from coastal Antarctica since the Late Eocene glaciations, but this group exhibited a notable austral diversity during the Cretaceous and Paleogene. Several species have already been described from the Aptian-Eocene successions of the Larsen Basin exposed in the James Ross Island area (northern Antarctic Peninsula) and the predominantly deep-water Hexanchiformes have a record that, although still rare, has been continually increased. Four species of this group are currently known from that basin: Notidanodon pectinatus, Xampylodon dentatus, Rolfodon thompsoni, and Rolfodon tatere. Such records are especially concentrated in the Gamma Member of the Snow Hill Island Formation (or Herbert Sound Member of Santa Marta Formation), on James Ross Island. Here we described four teeth assigned to X. dentatus and one identified as R. tatere from upper Campanian sections of James Ross Island, highlighting the nomenclatural changes that led to the definition of Xampylodon and Rolfodon. Some specimens of X. dentatus presented here are considerably more complete or represent teeth of different positions than most previous records. The material assigned to R. tatere represents the oldest record of this species in the world, extending its time range by more than 10 million years. [ABSTRACT FROM AUTHOR]

Understanding the microscopic variability of impurities in glacier ice on a quantitative level has importance for assessing the preservation of paleoclimatic signals and enables the study of macroscopic deformational as well as dielectric ice properties. Two‐dimensional imaging via laser‐ablation‐inductively‐coupled‐plasma‐mass‐spectrometry (LA‐ICP‐MS) can provide key insight into the localization of impurities in the ice. So far, these findings are mostly qualitative and gaining quantitative insights remains challenging. Recent advances in LA‐ICP‐MS high‐resolution imaging now allow ice grains and grain boundaries to be resolved individually. These resolutions require new adequate quantification strategies and, consequently, accurate calibration with matrix‐matched standards. Here, we present three different quantification methods, which provide a high level of homogeneity at the scale of a few tens of microns and are dedicated to imaging applications of ice cores. One of the proposed methods has a second application, offering laboratory experiments to investigate the displacement of impurities by grain growth, with important future potential to study ice‐impurity interactions. Standards were analyzed to enable absolute quantification of impurities in selected ice core samples. Calibrated LA‐ICP‐MS maps indicate similar spatial distributions of impurities in all samples, while impurity levels vary distinctly: Higher concentrations were detected in glacial periods and Greenland, and lower levels in interglacial periods and samples from central Antarctica. These results are consistent with ranges from complementary meltwater analysis. Further comparison with cm‐scale melting techniques calls for a more sophisticated understanding of the ice chemistry across spatial scales, to which calibrated LA‐ICP‐MS maps now contribute quantitatively. Plain Language Summary: Compared to the large amount of information relating to paleoclimate signals reconstructed from cm‐scale impurity measurements on ice cores, knowledge about the spatial variability of impurities at the micro‐scale is extremely sparse—and becomes even more rare once quantitative datasets are concerned. However, there is an increasing demand for quantitative data for assessing the preservation of paleoclimatic signals and for the study of macroscopic deformational as well as dielectric ice properties in ice flow modeling and remote sensing. Two‐dimensional imaging via laser‐ablation‐inductively‐coupled‐plasma‐mass‐spectrometry (LA‐ICP‐MS) has shown great potential in this context, but so far, gaining reliable quantitative results for micro‐scale imaging has not been possible. Here, we present new quantification strategies that finally allow accurate calibration using ice standards. We carefully discuss the pros and cons of each method, apply the calibration to different samples from Greenland and Antarctica, and deliver the first calibrated LA‐ICP‐MS impurity maps at 40 μm resolution. Our results are consistent with bulk measurements performed on melted samples. The calibrated LA‐ICP‐MS maps will be essential for further comparison with bulk meltwater analysis, which may ultimately deliver an improved understanding of paleoclimate signals stored in deep ice. Key Points: This study presents new quantification strategies for two‐dimensional micro‐scale impurity imaging on ice cores with laser‐ablation‐inductively‐coupled‐plasma‐mass‐spectrometry (LA‐ICP‐MS)Calibrated LA‐ICP‐MS maps reveal similar spatial distributions of impurities in all ice core samples, while concentrations vary distinctlyWe developed a method to investigate the displacement of impurities by grain growth and to study ice‐impurity interactions in the laboratory [ABSTRACT FROM AUTHOR]

Only at Cape Surprise, central Transantarctic Mountains, is there exposed stratigraphic evidence for major offset along the range front, which marks a major boundary in Antarctica. Several faults parallel to the range front have been identified in the Devonian to Triassic Gondwana strata in the hinterland. Analysis of the stratigraphy based on field observations and the United States Geological Survey (USGS) aerial photographs, in conjunction with USGS topographic sheets and satellite-derived elevation measurements, suggests an array of faults with varying orientations and displacements. Fault offsets range up to an estimated 850 metres. No additional range-parallel faults have been identified and no clear pattern of faulting is evident in the hinterland of the frontal escarpment. Faulting may date from the time of slow uplift during the Cretaceous as well as the more rapid Cenozoic uplift of the range. Only a few faults in the hinterland can be allied with the fontal fault system. Cenozoic uplift and associated denudation was accompanied by glaciation of Antarctica, which is documented by Sirius Group strata. These deposits, which pre-date today's polar landscape, are older than mid Miocene, and in part may date from the earliest stages of warm-based glaciation in the early Oligocene. [ABSTRACT FROM AUTHOR]

Recently, a record of large, mostly unknown volcanic eruptions occurring during the younger half of the last glacial period (12–60 ka) has been compiled from ice-core records. In both Greenland and Antarctica these eruptions led to significant deposition of sulfate aerosols, which were likely transported in the stratosphere, thereby inducing a climate response. Here we report the first attempt to identify the climatic impact of volcanic eruptions in the last glacial period from ice cores. Average negative anomalies in high-resolution Greenland and Antarctic oxygen isotope records suggest a multi-annual volcanic cooling. Due to internal climate variability, glaciological noise, and uncertainties in the eruption age, the high-frequency noise level often exceeds the cooling induced by individual eruptions. Thus, cooling estimates for individual eruptions cannot be determined reliably. The average isotopic anomaly at the time of deposition also remains uncertain, since the signal degrades over time as a result of layer thinning and diffusion, which act to lower the resolution of both the oxygen isotope and sulfur records. Regardless of these quantitative uncertainties, there is a clear relationship of the magnitude of isotopic anomaly and sulfur deposition. Further, the isotopic signal during the cold stadial periods is larger in Greenland and smaller in Antarctica than during the milder interstadial periods for eruptions of equal sulfur deposition magnitude. In contrast, the largest reductions in snow accumulation associated with the eruptions occur during the interstadial periods. This may be the result of a state-dependent climate sensitivity, but we cannot rule out the possibility that changes in the sensitivity of the isotope thermometer or in the radiative forcing of eruptions of a given sulfur ejection may play a role as well. [ABSTRACT FROM AUTHOR]

The stability of contemporary ice shelves is under threat due to global warming, and the geological records in the Ross Sea offer such an opportunity to test the linkage between them. However, the absence of calcareous microfossils in the sediments of the Ross Sea results in uncertainties in establishing a precise chronology for studies. Hence, three sediment cores were collected and studied in terms of radiocarbon dating, magnetic susceptibility, and sediment grain size to reconstruct the environmental processes in the Ross Sea since the last glacial period. The main results are as follows: (1) two grain-size components were identified for the studied cores, which can be correlated to ice-shelf and sea-ice transport, respectively; (2) due to old-carbon contamination and an inconsistent carbon reservoir, the radiocarbon dates were generally underestimated, and as an alternative, changes in magnetic susceptibility of the studied cores can be tuned to the ice-core records to establish a reliable age–depth model and; (3) integrating sediment grain-size changes and comparisons with other paleoenvironmental proxies in the Antarctic, a process from a sub-ice sheet in the last glacial period to a sub-ice shelf in the glacial maximum, and, finally, to a glaciomarine state since the last deglacial period was identified in the western Ross Sea. Integrating these findings, the warming processes in the Antarctic were highlighted in the retreat processes of the Ross Ice Shelf in the past. [ABSTRACT FROM AUTHOR]

The Larsemann Hills, near Prydz Bay is a key region to understand past glacial dynamics in East Antarctica. However, multi-proxy dating constraints for this area indicate an uncertain chronology for deglaciation history during the Last Glacial Period (LGP). In this paper, we report two 26Al exposure ages and eighteen 10Be exposure ages for bedrock samples to better understand past glacial histories. The minimum exposure ages range from 82.84 ± 4.67 ka to 15.1 ± 1.95 ka corresponding to Marine Isotope Stages (MIS) 5–2, and fourteen of these samples date from before the global Last Glacial Maximum (c. 19–26.5 ka). Analysis of 10Be and 26Al concentrations implies a complex deglaciation history, and surface lowering of bedrock may have caused systematic age underestimation. Further comparisons between two adjacent regions in the Mirror Peninsula reveal two major deglaciations involving the Lambert Glacier / Amery Ice Shelf System dated at 61.78 ka to 82.84 ka and 21.98 ka to 49.5 ka during the LGP. • We present new evidence for studying glacial history of Larsemann Hills, Antarctica. • Cosmogenic nuclides 10Be and 26Al dating method is applied for better analysis. • Two major deglaciation events occurred regionally within MIS 2–3 and MIS 4–5. • The exposure age and elevation show a highly significant positive correlation. • Multi-proxy and adjacent evidence are summarized and compared with this study. [ABSTRACT FROM AUTHOR]

Antarctic fjords and coastal bays are excellent traps for sediment and represent key areas for high-resolution investigation of past environmental conditions. Robertson Bay is an understudied coastal area located at the confluence of the Ross Sea and the Southern Ocean. Recently obtained seafloor morphology data indicate the presence of a cross-shelf elongated valley, composed of three minor basins separated by sills and seabed ridges with an arcuate shape. Several cores were collected within the basins, and investigated using a multiproxy approach including sedimentological, chemical, geochemical, and micropaleontological characterization to reconstruct the paleoenvironmental evolution from the last glacial period to present. The ages of two of these cores are constrained using ramped pyrolysis oxidation radiocarbon dating. Four sedimentary facies were recognised from which we developed a sedimentary model covering the last 21,000 years (21 ka BP). Our record provide evidence for a covering ice shelf cover from 21 to 16.5 ka BP, which gradually receded between 16,5 and 11 ka BP due to the progressive intrusion of modified Circumpolar Deep Water, thereby promoting the formation of Ice Shelf Water and High Salinity Shelf Water. From 11 to 5,8 ka BP, the ice shelf continued shrinking and nutrient-rich of modified Circumpolar Deep Water penetration onto the continental shelf progressively favoured diatom blooms and a general increase in primary productivity until 5.8 ka BP. The Late Holocene is characterised by an alternation of prolonged sea ice cover with stratified water column and strong bottom current with prolonged sea-ice free season with the intrusion of modified Circumpolar Deep Water and very slow energy bottom current. • First paleoenvironmental study from the LGM to the present in Robertson Bay. • Strong impact of regional ice sheet recession on environmental conditions and productivity. • Multiproxy approach constrained by Ramped Pyrolysis based age model. • The coastal bay area was studied by sediment cores and geophysical data. [ABSTRACT FROM AUTHOR]

The 17O-excess (Δ17O) of sulfate (SO 4 2−) in Antarctic ice cores is a potential tool for assessing past oxidant chemistry. However, a significant gap between atmospheric and ice core Δ17O(SO 4 2−) has been reported in Antarctica. Here, we report Δ17O(SO 4 2−) of surface snow at sites with different snow accumulation rates along a latitudinal traverse route in East Antarctica. While the Δ17O(nss-SO 4 2−) values for the coastal region showed an average of 1.0 ± 0.5‰ (n = 8) that can be explained by atmospheric Δ17O(SO 4 2−) variations, Δ17O(nss-SO 4 2−) in the katabatic (2.7 ± 0.2‰, n = 5) and inland (3.5 ± 0.3‰, n = 6) regions showed relatively high values that cannot be explained only by atmospheric deposition. Lower methanesulfonate (MSA) fluxes and lower mass ratios of MSA to SO 4 2−, along with higher Δ17O(nss-SO 4 2−) values, were observed in the katabatic and inland regions, suggesting the production of SO 4 2− with a high Δ17O value through MSA oxidation via OH radicals. The influence of this chemical post-depositional effect on MSA and Δ17O(SO 4 2−) is more pronounced in the inland compared to the katabatic region. The Δ17O(SO 4 2−) records in Antarctic ice cores with low accumulation rates may be impacted by elevated Δ17O(SO 4 2−) values originating from MSA oxidation, necessitating careful interpretation. In particular, the shift in Δ17O(SO 4 2−) from glacial to interglacial periods, previously interpreted as a change in atmospheric sulfate formation, requires reconsideration. • Antarctica has a discrepancy of atmospheric and ice core Δ17O(SO 4 2−). • Δ17O(nss-SO 4 2−) in snow differs latitudinally from coastal to inland regions. • Interpretation of ice core Δ17O(SO 4 2−) needs caution with considering the post-depositional change. [ABSTRACT FROM AUTHOR]