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New mapping of the Barberton Greenstone Belt in South Africa shows that the central part is a pseudo-stratigraphy made of shallow-water and deep-water siliciclastic and volcanic slide blocks, with individual blocks ranging in size from tens of meters to >10 km in length. The outcrop pattern and scale are remarkably similar to those of large-scale Miocene to recent submarine landslides in New Zealand along the active Hikurangi subduction zone that are periodically triggered by earthquakes on the subduction megathrust, providing evidence for megathrust earthquakes in the Paleoarchean. [ABSTRACT FROM AUTHOR]

Due to the inherently fluid‐mobile nature of W, the 182W record of the early Earth may have been obscured by fluid‐induced mobilization of W. To investigate W mobilization in Archean greenstone sequences, we analyzed 182W isotope systematics and major and trace element concentrations in samples from the 3.53 Ga old Onverwacht Group of the Kaapvaal Craton (South Africa) and the >3.51 Ga old Badampahar Group of the Singhbhum Craton (India). Our results for mafic and ultramafic metavolcanic rocks show W/Th ratios significantly higher than primary magmatic values, which suggests fluid‐induced W enrichment. Samples least affected by secondary W enrichment (W/Th < 0.26) show no resolvable W isotope anomalies from modern mantle values in both cratons. Samples from the Kaapvaal Craton with elevated W/Th exhibit deficits in 182W as low as −8.1 ± 4.3 ppm compared to the modern mantle. Covariations of μ182W with W/Th, and Ce/Pb suggest that negative isotope signatures were introduced during secondary fluid‐mediated processes. The enrichment of W is most evident in altered ultramafic rocks comprising serpentine, resulting in additional covariations between MgO, LOI, and W/Th. The W isotope composition of serpentinized komatiites reflects the composition of younger intruding granitoids. We therefore infer the latter as a possible source of W‐rich fluids. The Badampahar Group samples exhibit little W isotope variability. A well‐resolved 182W deficit of −6.2 ± 2.9 ppm was determined in a single komatiite sample, which indicates an unknown fluid source, currently not represented in any other unit of the Singhbhum Craton. Plain Language Summary: The tungsten (W) isotope composition of ancient rocks can be used to trace processes that occurred during Earth's early evolution. However, interactions between rocks and fluids may alter the W concentration and therefore influence the interpretation of W isotope data. To identify the source of such fluids and the processes by which they affect the W isotope composition of rocks, we analyzed ancient rock samples from South Africa and India. The isotope composition of rocks with a low W concentration reflects that of the modern Earth. Therefore, they do not trace the processes that occurred during Earth's early evolution. Samples from South Africa with untypically high W concentrations show a different isotopic composition. The variation in the W isotope signature correlates with other chemical indices that are susceptible to modification by fluid‐related processes. This shows that the W within the rocks is derived from an external fluid source and not from their original magmatic source. Samples with the highest W enrichment have a similar isotope composition as spatially associated intrusive rocks. By inference, the latter likely represent the source of W‐rich fluids. The samples from India show similar enrichment in W, indicating similar fluid‐related processes and W sources at both localities. Key Points: The magmatic sources of metavolcanic rocks from the Onverwacht Group and the Badampahar Group do not exhibit W isotope anomaliesNegative W isotope signatures in the Onverwacht Group are likely derived from fluids sourced from younger intrusive granitoidsFelsic intrusive rocks are a major source of W‐rich fluids in Paleoarchean greenstone units [ABSTRACT FROM AUTHOR]

The north‐dipping Hout River Shear Zone (HRSZ), which marks the boundary between the high‐grade Limpopo Complex in its hanging wall and the low‐grade granite‐greenstone terrane of the Kaapvaal Craton in South Africa in its footwall, is a deep‐crustal shear zone that controlled emplacement of hot Limpopo Complex granulites over and against low‐grade granite‐greenstones during exhumation at ~2.72–2.62 Ga. This major shear zone controlled migration of large volumes of hydrous fluids released during devolatilization of underthrusted greenstones that infiltrated into hot overlying granulites, establishing a retrograde anthophyllite‐in isograd and associated zone of retrograde rehydrated granulite that bounds the Limpopo Complex in the south. Here, we report new petrological data based on mineral equilibrium modelling of amphibolites from the Rhenosterkoppies Greenstone Belt (RGB) located in the immediate footwall of the HRSZ and discuss evidence that these rocks also interacted with high‐temperature fluids that infiltrated along the HRSZ. This study provides an important perspective of the interaction of hot granulites with underthrusted relatively cold greenschist‐facies rocks along the steeply north‐dipping section of the HRSZ, and shows that evidence for such interaction is restricted to a relatively narrow zone in the footwall of the HRSZ termed a hot‐iron‐zone. The peak mineral assemblage of a garnet‐free amphibolite from the RGB (magnesio‐hornblende + plagioclase + quartz + clinopyroxene + titanite + ilmenite) yielded the peak P–T condition of 7–8 kbar and 640–680°C with H2O content of 3.5–3.8 mol%. Clinopyroxene is replaced by actinolite + quartz and epidote + quartz symplectites by a post‐peak hydration event at <5 kbar and <590°C caused by elevated H2O content in the rock (>4.0 mol%), possibly related to fluid infiltration along the HRSZ. Mineral equilibria in a garnet‐bearing amphibolite records a prograde path from 5 to 7 kbar and 540–630°C to the peak conditions at 7.6–8.7 kbar and 620–650°C. A clockwise P–T path suggesting rapid compression and decompression has been inferred for the amphibolites from the RGB, possibly because of pressure increase related to overthrusting of the high‐grade terrane (Southern Marginal Zone of the Limpopo Complex) onto the low‐grade granite‐greenstone terrane, followed by rapid exhumation. The quantity of H2O associated with the amphibolite‐facies metamorphism in the RGB was elevated from the peak stage (M(H2O) = 3.5–3.8 mol%) to the retrograde stage (M(H2O) = 4.0–4.5 mol%) of metamorphism in the RGB, possibly suggesting fluid infiltration not only from internal sources but also from external sources. The results of this study indicate that a H2O‐bearing fluid, which infiltrated along the HRSZ, affected both the footwall and the hanging wall sections of the shear zone, although the effect on the footwall section was limited. [ABSTRACT FROM AUTHOR]

We report abundant small calcareous mounds associated with fossilized kerogenous microbial mats in tidal-facies sandstones of the predominantly siliciclastic Moodies Group (ca. 3.22 Ga) of the Barberton Greenstone Belt (BGB), South Africa and Eswatini. Most of the bulbous, internally microlaminated mounds are several centimeters in diameter and formed at the sediment-water interface contemporaneously with sedimentation. They originally consisted of Fe-Mg-Mn carbonate, which is now largely silicified; subtle internal compositional laminations are composed of organic matter and sericite. Their presence for >6 km along strike, their restriction to the inferred photic zone, and the internal structure suggest that mineral precipitation was induced by photosynthetic microorganisms. Similar calcareous mounds in this unit also occur within and on top of fluid-escape conduits, suggesting that carbonate precipitation may either have occurred abiogenically or involved chemotrophic metabolism(s) utilizing the oxidation of organic matter, methane, or hydrogen, the latter possibly generated by serpentinization of underlying ultramafic rocks. Alternatively or additionally, carbonate may have precipitated abiotically where heated subsurface fluids, sourced by the intrusion of a major Moodies-age sill, reached the tidal flats. In summary, precipitation mechanisms may have been variable; the calcareous mounds may represent "hybrid carbonates" that may have originated from the small-scale overlap of bioinduced and abiotic processes in space and time. Significantly, the widespread occurrence of these stromatolite-like structures in a fully siliciclastic, high-energy tidal setting broadens search criteria in the search for life on Mars while their possible hybrid origin challenges our ability to unambiguously identify a biogenic component. [ABSTRACT FROM AUTHOR]

Greenstone belt dynamics are a key to understanding the formation and evolution of continental crust but the scarcity, commonly poor exposure, strong deformation, and high metamorphic grades of many Archaean supracrustal rocks preserved in greenstone belts often hinder geological insights. Exceptionally, the largely siliciclastic Palaeoarchaean (ca. 3.22 Ga) Moodies Group, uppermost unit of the Barberton Greenstone Belt (BGB) in South Africa and Eswatini, allows a detailed understanding of regional depositional processes and stratigraphic architecture due to its low degree of deformation, considerable thickness, generally good exposure, and diverse sedimentary facies. We here investigate the Powerline Road Syncline (PRS) and the adjacent Maid-of-the-Mists Syncline (MMS), two east-west-trending, tightly to isoclinally folded, locally northwardly overturned synclines in Moodies Group strata in the central BGB. The northern and southeastern margins of the PRS and the southern to southwestern margin of MMS are bounded by the bedding-parallel 24-Hour-Camp Fault. Along this fault, Moodies Group strata and stratigraphically underlying units of the Auber Villiers Formation of the upper Fig Tree Group structurally overlie lower Fig Tree strata above Onverwacht Group strata. Stratigraphic architecture and palaeocurrent analysis of Moodies Group strata in both synclines document a northeastward (depositionally downdip) facies transition from proximal fan delta conglomerates to fluvial- to coastal-plain and estuarine sandstones in which thick foresets likely represent subtidal channel fills. The overall deepening-and fining-upward trend in this sequence, corresponding to an increasing mineralogical maturity of sandstones, is partially obscured by local hydrothermal alteration which was contemporaneous with sedimentation, minor volcanism, and sill intrusion. Moodies Group conglomerates and sandstones were largely shed from the rising Onverwacht Anticline to the southwest. Lithologies and stratigraphy in the PRS-MMS region closely resemble strata of the lower Moodies Group in the Sadddleback Syncline, located nearby to the north but across the Inyoka Fault. If the 24-Hour-Camp Fault was part of a group of extensional faults accompanying the rise of the Onverwacht Anticline and of tonalitic-trondhjemitic-granodioritic plutons around the BGB margins at ca. 3 224 Ma, it would have acted as one of numerous basin-bounding normal faults during early Moodies time. This would place the deposition of Moodies Group strata in the PRS-MMS region in a supra-detachment fault environment which was subsequently tightly folded. [ABSTRACT FROM AUTHOR]

This study investigates the structural control of the numerous gold occurrences in the southern part of the Barberton Greenstone Belt in the Malolotja and Steynsdorp areas. The gold-bearing event distribution is studied using field structural geology associated with a petrological and microstructural analysis. Three major tectonic events have been identified in quartz veins and direct country rocks. The first event (De) created a regional schistosity (Se), probably associated with an early thrusting event. The second event (Df) is related to a large-scale folding, which formed the anticline at Steynsdorp and synform at Malolotja. It resulted from a main E–W direction of shortening and is responsible for the folding of the Se schistosity. It formed a N–S-striking axial planar cleavage (Sf), observed and associated with the emplacement of the main gold-bearing veins. The mineralised system exhibits a complex vein network, in which shallow dipping veins have developed coevally with steep west- and east-dipping veins. A third deformation event (Dl) produced by NE–SW shortening is related to the late barren hydrothermal quartz vein formation. Mineralogically, the veins are filled with abundant quartz, and scarce tourmaline and feldspars. Alteration halos composed of neoformed tourmaline and plagioclase within a talc and white mica matrix developed specifically during the late Dl event. A model of regional deformation giving rise to large-scale folds and quartz vein formation formed in response to E–W and NE–SW directions of shortening globally is proposed and discussed in this paper. [ABSTRACT FROM AUTHOR]

The ca. 3.5 Ga Bon Accord Ni deposit was located in the Barberton Greenstone Belt of the Kaapvaal Craton, South Africa, and contained a unique assemblage of Ni-rich minerals including trevorite (NiFe2O4). It was initially interpreted as a metamorphosed extraterrestrial body, recently ruled out by Cr isotope data, and subsequently as a fragment of the Archean Earth's core. More recent suggestions have highlighted similarities between Bon Accord and Archean magmatic sulfide mineralization. We present a geochemical (rare earth element [REE], halogen, and highly siderophile element [HSE] abundance) and isotopic (noble gases, Zn, Cr, and Re-Os) study to elucidate the origin of this enigmatic body. Bon Accord is enriched in the REE relative to primitive mantle (PM), with a pattern resembling that of Aldepleted komatiites. The bulk material has >10 PM Os and Ir, >100 - PM Ru, Pt, Pd, and Re, and radiogenic 187Os/188Os. Trevorite, silicates, and two bulk-rock samples are consistent with chondritic to sub-chondritic initial 187Os/188Os at the time of formation. The new REE data implicate a komatiite precursor in the formation of Bon Accord, and the HSE data bear striking similarities to those of Ni-enriched Archean magmatic sulfide deposits. Enrichment in the heavier Zn isotopes supports desulfurization of a sulfide (isotopically light) deposit during serpentinization to produce the trevorite-dominated body. We conservatively estimate this process could have mobilized as much as -9.2 x 104 tonnes of H2S, offering an intriguing possibility for sourcing of the sulfur that fixes the historically important gold mineralization in the Barberton Greenstone Belt. [ABSTRACT FROM AUTHOR]

This study presents multiple sulphur isotope (32S, 33S, 34S, 36S) data on pyrites from silicified volcano‐sedimentary rocks of the Paleoarchean Onverwacht Group of the Barberton greenstone belt, South Africa. These rocks include seafloor cherts and felsic conglomerates that were deposited in shallow marine environments preserving a record of atmospheric and biogeochemical conditions on the early Earth. A strong variation in mass independent sulphur isotope fractionation (MIF‐S) anomalies is found in the cherts, with Δ33S ranging between −0.26‰ and 3.42‰. We explore possible depositional and preservational factors that could explain some of this variation seen in MIF‐S. Evidence for microbial activity is recorded by the c. 3.45 Ga Hooggenoeg Formation Chert (HC4) preserving a contribution of microbial sulphate reduction (−Δ33S and –δ34S), and a c. 3.33 Ga Kromberg Formation Chert (KC5) recording a possible contribution of microbial elemental sulphur disproportionation (+Δ33S and –δ34S). Pyrites from a rhyo‐dacitic conglomerate of the Noisy Formation do not plot along a previously proposed global Felsic Volcanic Array, and this excludes short‐lived pulses of intense felsic volcanic gas emissions as the dominant control on Archean MIF‐S. Rather, we suggest that the MIF‐S signals measured reflect dilution during marine deposition, early diagenetic modification, and mixing with volcanic/hydrothermal S sources. Given the expanded stratigraphic interval (3.47–3.22 Ga) now sampled from across the Barberton Supergroup, we conclude that large MIF‐S exceeding >4‰ is atypical of Paleoarchean near‐surface environments on the Kaapvaal Craton. [ABSTRACT FROM AUTHOR]

The nature of the early Archean ocean floor remains a topic of important debate. There are relatively few well-preserved occurrences worldwide where such terrains may be studied in detail because of structural dismemberment, metamorphic overprinting and pervasive early stage hydrothermal alteration to recent weathering. The 3.41-Ga dominantly mafic formations of the Nondweni Greenstone Belt (NGB) covering 270 km2 in the south-eastern Kaapvaal Craton comprise submarine volcanics that exhibit a wide range of textural features, including pillows, chill zones and brecciated flow tops, and various spinifex textures, including the rare platy pyroxene type, cumulate layers, and tuffs. Channelized subaqueous lava lakes that underwent fractionation are capped by thick spinifex-textured units and pillows. Early stage seafloor alteration is regionally variable, ranging from intense to minimal, with preservation of original mineralogy in many areas. Mafic volcanic rocks of the NGB contrast with those of the Barberton Greenstone Belt both in the style of volcanism and in the associated compositional range of komatiitic basalt to basalt with a complete absence of high-Mg komatiites. Olivine-phyric rocks, or derivatives thereof, are largely absent and pyroxene is the main controlling phase with orthopyroxene in the most primitive komatiitic basalts and clinopyroxene in the evolved lava lake sequences. The abundance of orthopyroxene typifies the long-standing silica-enriched character of the Kaapvaal Craton. Three exceptionally well-preserved and well-exposed sequences were studied utilizing hand-drilled samples and deep coring providing unprecedented stratigraphic and textural detail and field controls for more than 400 samples. A unifying feature of the mafic volcanics of the NGB is the range of compositions and ratios of incompatible elements most clearly illustrated by a series of high- and low-Ti compositional lineages reflecting differing sources or degrees of mantle partial melting. Sharp boundaries between high- and low-Ti flow successions indicate sudden changes in the melting regimes or the interaction of flow sequences from different volcanic centres. Th/Nb ranges from 0.1 to 0.2 and reveals crustal contamination of primitive lavas. The primary magma that gave rise to the most primitive komatiitic basalts with 19.5% MgO was derived from partial melting of a mantle plume source in the garnet stability field. Trace element modeling shows that the sequences studied in detail have been modified by fractionation and crustal contamination with the most likely contaminant being the Ancient Gneiss Complex (3.43–3.66 Ga), which is extensively exposed in Eswatini and probably underlies the Paleoarchean terrains in the southern Kaapvaal Craton. The geotectonic setting was likely that of a submerged felsic crustal platform as enclaves within an oceanic plateau. [ABSTRACT FROM AUTHOR]

The NASA Mars 2020 Perseverance rover is currently exploring Jezero crater, a Noachian–Hesperian locality that once hosted a delta–lake system with high habitability and biosignature preservation potential. Perseverance conducts detailed appraisals of rock targets using a synergistic payload capable of geological characterization from kilometer to micron scales. The highest-resolution textural and chemical information will be provided by correlated WATSON (imaging), SHERLOC (deep-UV Raman and fluorescence spectroscopy), and PIXL (X-ray lithochemistry) analyses, enabling the distributions of organic and mineral phases within rock targets to be comprehensively established. Herein, we analyze Paleoarchean microbial mats from the ∼3.42 Ga Buck Reef Chert (Barberton greenstone belt, South Africa)—considered astrobiological analogues for a putative ancient martian biosphere—following a WATSON–SHERLOC–PIXL protocol identical to that conducted by Perseverance on Mars during all sampling activities. Correlating deep-UV Raman and fluorescence spectroscopic mapping with X-ray elemental mapping, we show that the Perseverance payload has the capability to detect thermally and texturally mature organic materials of biogenic origin and can highlight organic–mineral interrelationships and elemental colocation at fine spatial scales. We also show that the Perseverance protocol obtains very similar results to high-performance laboratory imaging, Raman spectroscopy, and μXRF instruments. This is encouraging for the prospect of detecting microscale organic-bearing textural biosignatures on Mars using the correlative micro-analytical approach enabled by WATSON, SHERLOC, and PIXL; indeed, laminated, organic-bearing samples such as those studied herein are considered plausible analogues of biosignatures from a potential Noachian–Hesperian biosphere. Were similar materials discovered at Jezero crater, they would offer opportunities to reconstruct aspects of the early martian carbon cycle and search for potential fossilized traces of life in ancient paleoenvironments. Such samples should be prioritized for caching and eventual return to Earth. [ABSTRACT FROM AUTHOR]

Past orbital parameters of the Moon are difficult to reconstruct from geological records because relevant data sets of tidal strata are scarce or incomplete. The sole Archean data point is from the Moodies Group (ca 3.22 Ga) of the Barberton Greenstone Belt, South Africa. From the time‐series analysis of tidal bundles from a well‐exposed subaqueous sand wave of this unit, Eriksson and Simpson (Geology, 28, 831) suggested that the Moon's anomalistic month at 3.2 Ga was closer to 20 days than the present 27.5 days. This is in apparent accordance with models of orbital mechanics which place the Archean Moon in a closer orbit with a shorter period, resulting in stronger tidal action. Although this study's detailed geological mapping and section measuring of the site confirmed that the sandstone bed in question is likely a migrating dune, the presence of angular mud clasts, channel‐margin slumps, laterally aggrading channel fills and bidirectional paleocurrents in overlying and underlying beds suggests that this bedform was likely located in a nearshore channel near lower‐intertidal flats and subtidal estuarine bars; it thus carries risk of incomplete preservation. Repeated measurements of foreset thicknesses along the published traverse, measured perpendicular to bedding, failed to show consistent spectral peaks. Larger data sets acquired along traverses measured parallel to bedding along the 20.5 m wide exposure are affected by minor faulting, uneven outcrop weathering, changing illumination, weather, observer bias and show a low reproducibility. The most robust measurements herein confirm the periodicity peak of approximately 14 in the original data of Eriksson and Simpson (Geology, 28, 831). Because laminae may have been eroded, the measurements may represent a lower bound of about 28 lunar days per synodic month. This estimate agrees well with Earth–Moon dynamic models which consider the conservation of angular momentum and place the Archaean Moon in a lower orbit around a faster‐spinning Earth. [ABSTRACT FROM AUTHOR]

Ultramafic-mafic layered complexes are important but not-well studied components of Archaean granitoid-greenstone terranes. In the vicinity of the Barberton Greenstone Belt (BGB), at least 27 such complexes are intimately associated with the supracrustal succession. The petrogenesis of one of these layered bodies, the Stolzburg Complex (SC), is explored, together with its relationship to the surrounding Barberton volcanic succession. Previous models for the origin of Barberton layered complexes proposed a variety of mechanisms, such as single chamber subvolcanic sills, ponded lavas, and alpine-type tectonites. In contrast, the present work suggests that emplacement mostly occurred as sheeted sills of crystal slurries into the country rocks. Unlike the subvolcanic sills model, whereby each complex grew through repetitive magma injection and differentiation in a single chamber, the preferred model regards the layered bodies as ‘stacks’ of discrete intrusions, where each magmatic unit represents a distinct sill. Through comparison of trace element geochemistry (i.e., trace element ratios and patterns), the Lower and Upper divisions of the SC are inferred to be petrogenetically related, but compositionally distinct from the enveloping Nelshoogte volcanic rocks. The trace element geochemistry of the Lower and Upper divisions of the complex is indistinguishable. While the SC ultramafic rocks display an Al-undepleted character, Nelshoogte metavolcanics can be classified as Al-depleted komatiites and komatiitic basalts. [ABSTRACT FROM AUTHOR]

One of the major challenges in early Earth geology is the interpretation of the nature of the crust and tectonic processes due to the limited exposures of Archean rocks. This question is predominantly addressed by numerical modeling, structural geology, geochemical analyses, and petrological approaches. Here we report on the reconstruction of one of the oldest, well-preserved volcano-sedimentary sequences on Earth, the 3.28-3.22 Ga Fig Tree Group in the Barberton Greenstone Belt, South Africa, based on geochronology, provenance, and stratigraphy to provide new constraints on the nature of tectonic processes in the Archean. The Fig Tree basin was asymmetric and the onset of deposition varied across the greenstone belt. The Fig Tree Group is now preserved in east-west oriented bands of fault-bounded structural belts with those preserved in the southern parts of the greenstone belt showing an onset of deposition at 3.28 Ga, those in the center at 3.26 Ga, and those in the north at 3.24 Ga. Stratigraphically, the rocks display a general up-section trend from deeper to shallower-water deposition and/or from finer- to coarser-grained sedimentary rocks. Associated with this up-section stratigraphic trend, the sedimentary rocks show a change in provenance from more regionally similar to more locally variable, and an increase in felsic volcanic activity, especially toward the closure of Fig Tree deposition. The data is consistent with formation of the Fig Tree Group in a compressional tectonic setting by deposition in a foreland basin that experienced progressive accretion of crustal terranes onto a northward prograding fold-and-thrust belt. [ABSTRACT FROM AUTHOR]

It is unresolved when eolian processes began to significantly affect global mean sand composition and texture through abrasion and enhanced sorting. Reports of Proterozoic eolian textures and sedimentary structures are common, in particular from 1.8 Ga on, but the Archean (4.0–2.5 Ga) geologic record possesses only seven reported eolian occurrences which generally do not manifest more than a few diagnostic features of eolian transport. We investigate in detail sandstone units within the Moodies Group (ca. 3.22 Ga) of the Barberton Greenstone Belt, South Africa, one of the oldest well-preserved terrestrial–marine sandy successions. Eight examined locations show terrestrial facies associations, high degrees of compositional and textural maturity, and large-scale foresets; however, none show convincing evidence of eolian transport but several can be excluded with confidence. In comparison to recent eolian strata, grains are generally slightly too coarse-grained, too angular, and mostly too poorly sorted. The common presence of shale laminations, granules, rare pebbles, and shale rip-up clasts demonstrates that the investigated strata were either of aqueous origin or had been formed by eolian processes but were subsequently aqueously reworked. This is vexing because the sandy-gravelly fluvial, coastal floodplain, and estuarine depositional environments of Moodies Group strata may have been hospitable to potentially powerful and long-lasting Archean eolian processes. Early Archean eolian strata may have had a limited depositional area, may have been extensively reworked, or formed under non-actualistic conditions. Thus, the significance of eolian processes on early Earth and their potential contribution to the high degree of textural and compositional maturity of Archean quartzarenites remains poorly constrained. [ABSTRACT FROM AUTHOR]

The deep upper mantle is the main source of high-temperature magmatism, but the only known naturally occurring samples of high-pressure mantle constituents are mineral inclusions in diamonds. Trace elements in olivine crystals from the 3.33 Ga Commondale Greenstone Belt in South Africa reveal that these crystals formed in the deep upper mantle as high-pressure phenocrysts, and some perhaps even formed in the mantle transition zone (410-600 km) where they began as wadsleyite. The crystals were entrained within ascending komatiite magma and conveyed to the surface. The olivine crystals have the highest contents of Al2O3 (0.3 wt%) recorded in any terrestrial olivine, which is indicative of formation at high pressure. The deep mantle gave rise to Archean komatiites, extraordinarily hot magmas (up to 1700 °C), which provide insight into Earth's early mantle evolution and the formation of most ancient continental and oceanic crust. In spite of extensive research since their discovery over 50 years ago, the origins of komatiites have remained contentious. Plumes--thermochemical instabilities originating at the core-mantle boundary--are the most likely source, but no direct evidence of a deep mantle origin of komatiite has yet been recognized. [ABSTRACT FROM AUTHOR]

Data-driven methods have increasingly been applied to solve geoscientific problems. Incorporation of data-driven methods with hypothesis testing can be effective to address some long-standing debates and reduce interpretation uncertainty by leveraging larger volumes of data and more objective data analytics, which leads to increased reproducibility. In this study, lithogeochemical data from regionally persistent Archean shale units were aggregated from literature, with special reference to the Kaapvaal Craton of South Africa—namely, shales from the Barberton, Witwatersrand, Pongola, and Transvaal Supergroups—and the Belingwe and Buhwa Greenstone Belts of the Zimbabwe Craton. We examine the feasibility of using machine-learning algorithms to produce a geochemical classification and demonstrate that machine learning is capable of accurately correlating stratigraphy at the formation, group, and supergroup levels. We demonstrate the ability to extract highly useful scientific findings through a data-driven approach, such as geological implications for the uniqueness of the sediment compositions of the Central Rand and West Rand Groups. We further demonstrate that when lithogeochemistry and machine-learning algorithms are used, only about 50 samples per geological unit are necessary to reach accuracy levels of around 80%–90% for our shale samples. Consequently, for many traditional tasks, such as rock identification and mapping, some expensive analyses and manual labor can be replaced by an abundance of cheaper data and machine learning. This approach could transform large-scale geological surveys by enabling more detailed mapping than currently possible, by vastly increasing the coverage rate and total coverage. In addition, the aggregation of historical data facilitates data reuse and open science. These results justify the need to bridge data- and hypothesis-driven techniques for the stratigraphic correlation and prediction of rock units, which can improve the accuracy of the inferred stratigraphic correlation and basin setting. [ABSTRACT FROM AUTHOR]

A new lithostratigraphic framework based upon a review of historic data, field mapping and remote sensing, including aerial photography, high-resolution airborne aeromagnetic and radiometric data, is proposed for the Archaean geology along the southeastern margin of the Kaapvaal Craton, South Africa. A synthesis of new and existing data reveals that previously accepted lithostratigraphic schemes require complete revision, with reinterpretations identifying multiple major shear zones and previously unidentified granitoid successions along the margin of the craton. In this new lithostratigraphic framework, lithologies of the Southern Syncline previously correlated with the Nsuze Group of the Pongola Supergroup, are redefined as greenstone lithologies associated with the Ilangwe Greenstone Belt. The geology of the Nkandla region can be subdivided into five distinct geophysical domains including: (i) an extension of the Ilangwe Greenstone Belt, (Domain 1) which is subdivided into; a lower volcanic succession, the Thathe Formation, comprising pillow and amygdaloidal volcanics; the adjoining Sabiza Formation, comprising pillow volcanics exposed in the southeast of the study area; the volcano-sedimentary Mtshwili Formation, which overlies the Thathe and Sabiza formations, consisting of quartz (sericite) schist, phyllite, metavolcanics and iron formation; the Nomangci Formation, which occurs as a region of highly deformed quartz-kyanite-sericite schists, and the Simbagwezi Formation, which comprises maroon to green phyllites and schists in the north of the study area. (ii) granitoids of the Impisi Granitoid Suite (Domain 2) which border the greenstone succession to the north, intruding the Nomangci and Simbagwezi formations. (iii) a southern complex of sheared granitoids termed the Umgabhi Granitoid Suite (Domain 3), which intrudes the Thathe, Sabiza and Mtshwili formations. (iv) The two remaining domains, comprise the Mesoproterozoic Mfongosi and Ntingwe Groups (Domain 4) and Mesoarchaean volcano-sedimentary sequences of the Pongola Supergroup (Domain 5). [ABSTRACT FROM AUTHOR]

Komatiites and sedimentary rocks sampled during the International Continental Drilling Program (BARB1-2–3-4–5) in the Barberton greenstone belt, South Africa, were analyzed for 146Sm-142Nd systematics. Resolved negative μ142Nd values (down to −7.7 ± 2.8) were identified in komatiites from the 3.48 Ga Komati Formation and this signature correlates with low Hf/Sm ratios measured in these samples. The negative μ142Nd point to a source with subchondritic Sm/Nd ratio which formed during the Hadean. No analytically resolvable 142Nd anomalies were measured in crustal detritus-rich, Si-rich, Ca-Fe-rich sediments and cherts from the Buck Reef (3.42 Ga) and the Fig Tree Group (3.23–3.28 Ga). Our new measurements are incorporated into a larger set of 147Sm-143Nd and 176Lu-176Hf data to better understand the 142,143Nd-176Hf isotope signatures in the mantle source at the time of komatiite crystallization. Our calculations show that the 142,143Nd-176Hf isotope signatures and Hf/Sm ratios cannot be produced by recycling into the komatiite source of detrital sediments like those sampled in the Barberton area. Only cherts have the required trace element characteristics – low Hf/Sm, radiogenic ε176Hf –but the trace element concentrations in the cherts are so low that unrealistic amounts of chert would need to be added. We propose a four-stage model for the formation of these rocks. Negative μ142Nd and low Hf/Sm ratios developed during the crystallization of a deep magma ocean soon after Earth accretion. The material that ultimately became the source of komatiites was a residual liquid produced by 50% crystallization leaving a bridgmanite/ferropericlase/Ca-perovskite cumulate. The Lu-Hf and Sm-Nd isotope systems were decoupled at this stage. After extinction of 146Sm around 4 Ga, parent/daughter ratios fractionated during a melt extraction event. With this model we explain the positive ε176Hf and slightly negative ε143Nd in these samples. The 3.55 Ga Schapenburg komatiites in another part of the Barberton belt share similar chemical signatures, supporting our model of fractionation in a deep magma ocean early in Earth's history. [ABSTRACT FROM AUTHOR]

This study presents new field and petrological observations combined with geochemical data on a range of komatiitic to tholeiitic volcanic rocks from the ca. 3.48 Ga mid-lower Komati Formation type-section of the Barberton Greenstone Belt, South Africa. A range of mafic-ultramafic rocks is identified across a 1.44 km profile, leading to the proposition of a new preliminary volcanic architecture for the mid-lower Komati Formation type-section. Major, trace and rare earth element (REE) data in conjunction with Lu-Hf isotopic constraints indicate that the tholeiites, newly recognized highmagnesium basalts, basaltic komatiites and komatiites in the volcanic sequence have a primitive mantle signature with no geochemical affinity to Archaean or modern-day supra-subduction zone boninites. The whole rock initial εHf values of spinifex and massive komatiite flows in the lowermost part of the Komati type-section are negative, ranging between -1.9 and -3.1, whereas the second overlying spinifex and massive flow unit records positive initial εHf values between +0.5 and +4.7. A new geodynamic model involving crustal contamination of the mafic-ultramafic lavas is proposed for the Barberton mid-lower Komati Formation type-section, involving mantle plume-crust interaction. The new observations and data indicate that the komatiites erupted as a result of a mantle plume from a hot (>1 600oC) mid-Archaean mantle, in which the earliest volcanic flows were variably affected by crustal contamination during their ascent and eruption. The possibility of incorporation of lower crustal material and/or recycled crust residing in the mantle source region cannot be excluded. This indicates that modern-style plate tectonic processes, such as subduction, may not have been a requirement for the formation of the 3.48 Ga Barberton komatiite suite, with implications for the hydration state, geodynamic processes and secular thermal evolution of the Archaean mantle. [ABSTRACT FROM AUTHOR]

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and electron microprobe analysis (EMPA) techniques were used to determine the mineralogy and chemistry of dominant sulphide and associated gold deposits at the Fairview Gold Mine of the Barberton Greenstone Belt (BGB). The rocks and ore mineral associations at the Fairview Mine indicate mesothermal (orogenic) conditions for the gold deposit. The whole rock chemistry of the Fairview Mine reflects calc-alkaline affinities, and felsic provenance is revealed by high SiO2, K2O, Al2O3, and TiO2, and low Fe2O3, MgO, Ni, and Cr contents. The mineral assemblages of the Fairview Mine rocks and ores indicate three phases of metamorphisms; regional prograde, thermal, and retrograde metamorphism, which caused zonation and heterogeneity of the ore minerals. The principal ore minerals in this deposit are pyrite, arsenopyrite, pyrrhotite, chalcopyrite, and rare sphalerite, as well as minor gold. The obtained results revealed that sulphides of the Fairview Mine are divided into two types (generations) varying in their morphology, association, and elemental composition. The old type 1 is porous, anhedral, heterogeneous, contains inclusions and rich in As, Ni, Co, and Au compared to type 2. Trace-element distribution and occurrence mode of gold at Fairview mine reflect two phases of gold mineralization. The first stage is associated with sulphides (mainly pyrite and arsenopyrite), whilst the second phase is free-lode hosted by silicates (mainly quartz). [ABSTRACT FROM AUTHOR]

The ~3.22 Ga Moodies Group, Barberton Greenstone Belt (BGB), South Africa, provides a unique window into Archaean sedimentary, magmatic and ecological processes. In the central BGB, a regional mafic complex, consisting of a genetically related major mafic sill, a peperitic dyke stockwork, and extensive basaltic lava flows affected thick quartzose sandstones of the Moodies Group. We argue that epithermal hydrothermalism associated with this magmatic event occurred, at least in part, syndepositionally and in places destroyed, in other places preserved the abundant benthic microbial mats in terrestrial- and coastal-facies sandstone of this unit. We differentiate four principal types of hydrothermal alteration: (1) Sericitization resulted from ubiquitous feldspar breakdown; (2) iron-oxide alteration replaced the original matrix by fine-grained iron oxide; (3) silicification replaced matrix and most nonsilica grains by microcrystalline silica and locally preserved kerogenous microbial mats; and (4) hydraulic fracturing at shallow depth brecciated consolidated Moodies Group sandstone and created closely spaced, randomly oriented fractures and quartz-filled veins. Because stockwork intrusion locally interacted with unconsolidated water-saturated sediment and because the dykes connect the sill with the mafic lava but also follow zones of structural weakness, we suggest that hydrothermalism associated with this magmatic event occurred syndepositionally but was also - within the resolution of radiometric age data - contemporaneous with tight regional folding. We conclude that microbial organisms in Paleoarchaean coastal (tidal, estuarine) environments may have been formerly widespread, possibly even abundant, but are nearly nowhere preserved because they were easily degradable. Preservation of Early Archaean microbial mats in a thermal aureole in the central BGB was controlled by the "just right" degree of heating and very early hydrothermal silicification. [ABSTRACT FROM AUTHOR]

The Inyoni shear zone represents an important tectonic boundary between (i) the ca. 3.45 Ga high-pressure amphibolite facies, granite-greenstone domain south of the Barberton greenstone belt, termed the Stolzburg terrane, and (ii) the ca. 3.29 to 3.23 Ga rocks of the trondhjemitic Badplaas pluton to the west. The Stolzburg terrane is separated from the greenschist facies rocks of the rest of the Barberton greenstone belt by the Komati fault, which records >10 km uplift of the Stolzburg terrane relative to the lower-grade rocks of the greenstone belt at ca. 3.23 Ga. A number of studies within the Stolzburg terrane have documented high-pressure amphibolite facies metamorphism that occurred concurrently with exhumation, with the lowest apparent geothermal gradients documented in the Inyoni shear zone, where strong constraints on the age of metamorphism are most limited. In addition, different studies on Inyoni metamorphism have produced significantly different temperature estimates. This study utilizes garnet Sm-Nd geochronology in combination with P-T modelling to directly date the metamorphism and re-evaluate the P-T conditions of the Inyoni shear zone. Two petrologically distinct samples produce similar P-T evolutions. A heterogeneous sample with both garnet-bearing and garnet-absent domains gives up-P evolutions reaching conditions of 550 to 675°C and 7 to 10 kbar, whereas a homogenous sample containing garnet and clinopyroxene produces a similar dominantly up-P evolution reaching peak conditions of 650°C and 8 to 10 kbar. Sm-Nd garnet ages of 3 201.6 ± 4.7 Ma (MSWD = 1.02) and 3 200.3 ± 5.3 Ma (MSWD = 0.44) were obtained from two samples of the homogenous garnet and clinopyroxene-bearing amphibolite. The Sm-Nd garnet geochronology provides accurate ages for the metamorphism of the Inyoni shear zone, with age results suggesting activity on the Inyoni shear zone may have continued after the regional metamorphism at ca. 3.23 Ga previously established by zircon U-Pb geochronology. However, 147Sm decay constant uncertainty leaves open the possibility that Inyoni garnet growth could have coincided with the previously recognized 3.23 Ga regional metamorphism. [ABSTRACT FROM AUTHOR]

The formation and evolution of Palaeoarchaean De Kraalen and Witrivier Greenstone Belts (DKGB and WGB) of the Kaapvaal Craton are poorly known. Here we report zircon and rutile in situ U-Pb ages and zircon Hf isotopic data from a variety of supracrustal rocks. The zircon cores from a metamafic amphibole-bearing gneiss from the DKGB give a protolith age of 3 441 ± 5 Ma, whereas the zircon mantle domains give a metamorphic age of 3 211 ± 16 Ma. The 176Hf/177Hft values for all zircon domains give a tight cluster around 0.280596 ± 0.00006 (2 SD). U-Pb analyses of zircon for an amphibolite intercalated with thin calc-silicate layers from the WGB give a single crystallisation age of 3 230 ± 3 Ma, but the Hf isotope ratios of these zircon grains define two different populations. The first population yields 176Hf/177Hf~3.23 Ga = 0.28064 ± 0.00004, corresponding to eHf~3.23 Ga = 2.4 ± 1.9 (2SD) and Hf model ages between ca. 3.51 to 3.30 Ga. These are Hf isotope characteristics for zircons from a relatively juvenile source extracted from a depleted mantle source ca. 0.28 to 0.07 Ga prior zircon crystallisation. The second population yields 176Hf/177Hf~3.23 Ga = 0.28093 ± 0.00004 with eHf~3.23 Ga = 8.1 ± 1.3 (2SD). These Hf data combined with the 206Pb/207Pb ages lead to isotope ratios that lie above those of Depleted Mantle. The unusually high Hf isotope signature for the cores of the zircons from the WGB amphibolite most likely represent a contribution from an early highly depleted mantle source. A rutile in situ U-Pb age of 3.085 Ga from a recrystallised quartzite indicate that the rocks from the DKGB experienced slow cooling following the 3.21 Ga metamorphic event or (partial) resetting due to elevated geothermal gradient caused by the ca. 3.1 Ga intrusions of the Vrede Granitiod Suite. The latter interpretation is preferred because ~145 Ma of slow cooling from the amphibolite facies conditions of peak metamorphism to the blocking temperature for mass diffusion of Pb in rutile is unlikely. While the Zr-in-rutile temperature of ca. 710°C at 7 kbar for DKGB most likely records the peak temperature of the ~3.23 to 3.21 Ga event. The trace element concentrations of the metamorphic rutile grains within the quartzite of the DKGB indicate that the source rock was enriched in Cr. Either due to silification during hydrothermal alteration of the (ultra)mafic country rock or during deposition in an atmosphere that allowed for chromite grains to be part of the sediment. [ABSTRACT FROM AUTHOR]

The nature of Earth's earliest crust and the processes by which it formed remain major issues in Precambrian geology. Due to the absence of a rock record older than ~4.02 Ga, the only direct record of the Hadean is from rare detrital zircon and that largely from a single area: the Jack Hills and Mount Narryer region of Western Australia. Here, we report on the geochemistry of Hadean detrital zircons as old as 4.15 Ga from the newly discovered Green Sandstone Bed in the Barberton greenstone belt, South Africa. We demonstrate that the U-Nb-Sc-Yb systematics of the majority of these Hadean zircons show a mantle affinity as seen in zircon from modern plume-type mantle environments and do not resemble zircon from modern continental or oceanic arcs. The zircon trace element compositions furthermore suggest magma compositions ranging from higher temperature, primitive to lower temperature, and more evolved tonalite-trondhjemitegranodiorite (TTG)-like magmas that experienced some reworking of hydrated crust. We propose that the Hadean parental magmas of the Green Sandstone Bed zircons formed from remelting of mafic, mantle-derived crust that experienced some hydrous input during melting but not from the processes seen in modern arc magmatism. [ABSTRACT FROM AUTHOR]

Homogenized melt inclusions in olivine were studied in Archean komatiites from the Barberton Greenstone Belt, Weltevreden Formation in South Africa (3.3 Ga), Abitibi Greenstone Belt in Canada (2.72 Ga), and the Belingwe Greenstone Belt in Zimbabwe (2.69 Ga). Contamination of the komatiite melts with crustal material enriched in Rb, Cl, and H2O during the crystallization of olivine is demonstrated. Uncontaminated melts have mantle Rb/Nb ratios but are significantly enriched in Cl and H2O relative to K and Ce, respectively, exhibiting similar incompatibility during crystallization and partial mantle melting. These observations suggest the presence of a chlorine- and water-enriched mantle source before 3.3 Ga. The excess Cl and H2O contents in the komatiites are assumed to result from the interaction of partially molten mantle plumes with the mantle transition zone. The most likely source of Cl and H2O enriching the deep mantle is the oceanic lithosphere that endured a seafloor alteration. We conclude that the recycling of the altered oceanic lithosphere into the mantle, probably via subduction, began in the first billion years of the Earth's history. Delamination of the Archean crust could not cause transport of chlorine and water into the deep mantle. [ABSTRACT FROM AUTHOR]

The discovery of komatiites, first in South Africa and then in many other Archean greenstone belts, with MgO concentrations of 20–30% and eruption temperatures of more than ∼1600 °C, showed that some parts of the mantle were hotter in the Archean than they are now. Since their discovery there have been many speculative proposals as to how such magmas can form. At present melt is produced by mantle upwelling, because the solidus temperature gradient of the mantle is steeper than that of isentropic decompression gradient at depths of less than 300 km. In contrast, in the lower half of the upper mantle the solidus gradient is shallower than the isentropic gradient, and, therefore, isentropic upwelling cannot generate melt. At the base of the upper mantle limited melting can occur, either in the thermal boundary layer at the base of the upper mantle, or in the upper part of the lower mantle where the solidus gradient is steeper than the isentropic gradient. In both cases melting can occur at depths of more than 600 km, where Ca perovskite, CaPv, is a stable phase on the solidus. A surprising feature of the partitioning between melt and solid CaPv is that most trace elements are compatible in the solid. Partitioning into CaPv can, therefore, account for the low concentrations of such elements in komatiites. The temperatures required to generate such magmas in plumes need be no more than ∼50 °C above those of Phanerozoic plumes. The presence of komatiites in the Archean, therefore, requires plume temperatures in the first half of the Earth's history to have been somewhat hotter than they are now, but does not constrain the average temperature of the Archean upper mantle. [ABSTRACT FROM AUTHOR]

On the basis of phylogenetic studies and laboratory cultures, it has been proposed that the ability of microbes to metabolize iron has emerged prior to the Archaea/Bacteria split. However, no unambiguous geochemical data supporting this claim have been put forward in rocks older than 2.7–2.5 giga years (Gyr). In the present work, we report in situ Fe and S isotope composition of pyrite from 3.28‐ to 3.26‐Gyr‐old cherts from the upper Mendon Formation, South Africa. We identified three populations of microscopic pyrites showing a wide range of Fe isotope compositions, which cluster around two δ56Fe values of −1.8‰ and +1‰. These three pyrite groups can also be distinguished based on the pyrite crystallinity and the S isotope mass‐independent signatures. One pyrite group displays poorly crystallized pyrite minerals with positive Δ33S values > +3‰, while the other groups display more variable and closer to 0‰ Δ33S values with recrystallized pyrite rims. It is worth to note that all the pyrite groups display positive Δ33S values in the pyrite core and similar trace element compositions. We therefore suggest that two of the pyrite groups have experienced late fluid circulations that have led to partial recrystallization and dilution of S isotope mass‐independent signature but not modification of the Fe isotope record. Considering the mineralogy and geochemistry of the pyrites and associated organic material, we conclude that this iron isotope systematic derives from microbial respiration of iron oxides during early diagenesis. Our data extend the geological record of dissimilatory iron reduction (DIR) back more than 560 million years (Myr) and confirm that micro‐organisms closely related to the last common ancestor had the ability to reduce Fe(III). [ABSTRACT FROM AUTHOR]

Data on the carbon and oxygen isotopic composition of carbonates from the rocks of the Giyani greenstone belt, Kaapvaal craton, South Africa are presented. This belt is immediately adjacent to the Hout River Shear Zone, along which the Southern Marginal Zone (SMZ) of the Limpopo granulite complex is overthrusted onto the Kaapvaal craton. The δ13C values are –2.1 and –2.2‰ for carbonates from two metapelite samples, –5.1‰ for a meta ultrabasite sample, and –7.1 and –7.7‰ for two metabasite samples, respectively. The δ18О values are 17.1 and 17.5‰ for carbonates from the metapelites, 14.3‰ for carbonates from the metaultrabasite, and 12.9 and 13.0‰ for carbonates from the metabasites. The comparison of the data obtained to the published data on the isotopic composition of carbonates from the rocks of the different greenstone belts indicates both hydrothermal (in the metabasites and the metaultrabasite) and sedimentary (in the metapelites) origins of the carbonate material in the rocks studied. Based on the comparison of these data to δ13C of magnesite that formed in ultrabasic granulites during the interaction of the Limpopo complex with the craton, the graphite and fluid inclusions in leucocratic garnet-bearing granitoids that transported fluids, and the carbon isotopic composition of graphite from metapelites of the SMZ, it is concluded that the carbon source was located outside the SMZ and represented a heterogeneous carbonate-bearing lithologies. It could be carbonate-bearing volcanogenic–sedimentary sequences of the greenstone belts of the Kaapvaal craton, which underwent prograde metamorphism during the interaction with the SMZ granulites. [ABSTRACT FROM AUTHOR]

Formations on the northwestern flank of the Barberton Greenstone Belt have hosted over 85% of all the gold recovered from the ca. 3550 to 3000 Ma Barberton Supergroup since early discoveries in 1872. This sector of the greenstone belt also happens to coincide with a complex tectonic architecture resulting from successive stages of folding and faulting superimposed onto a complex lithostratigraphy. Of particular importance has been the influence of two diapiric granitoid intrusions that caused added structural complexity following their emplacement ca. 3227 to 3250 Ma. Of these the larger Kaap Valley Pluton invaded the area north of present day Barberton town causing the separation of the greenstones into a northern arm (Jamestown Schist Belt) and a southern sector which remained attached to the main greenstone belt (Moodies Hills). The ballooning pluton produced vertical as well as horizontal flattening stresses, the latter reactivating earlier high-angle faults and resulting in subhorizontal strike-slip movements, particularly along the Barbrook Fault Zone, which acted as a right-lateral strike-slip fault. Formations north of this fault were buckled, following progressive deformation in the region known as the Sheba Hills, into major synclinal folds (Eureka and Ulundi Synclines) with folded axial planes that dip steeply to the south, southeast or east. The second granitoid intrusion (Stentor Pluton), which has been extensively modified by subsequent magmatic events, caused significant flattening of greenstone belt rocks in the northeastern part of the Barberton Greenstone Belt (Three Sisters region) as well as in other areas rimming the granitic body. Combined, the two plutons produced a wide range of interference and reactivated structures particularly affecting a triangular region extending from the Jamestown Schist Belt into the area occupied by the New Consort Gold Mine and areas to the east. This paper attempts to outline, in the simplest manner, the geological and structural evolution of the main gold-producing region of the Barberton Goldfield. The principal aim is therefore to highlight the structural influence of the diapiric plutonism and the manner in which the plutons contributed significantly to the horizontal reactivation of pre-existing regional faults, which in turn, resulted in the progressive deformation of a heterogeneous lithological terrane. [ABSTRACT FROM AUTHOR]

Gold production in Fairview Mine in the Barberton Greenstone Belt, South Africa, is focused on high-grade, steeply plunging ore shoots contained within a gently undulating system of spaced, low-displacement, broadly bedding-parallel faults, and shear zones, collectively referred to as the Main Reef Complex. This shear zone system is developed in metaturbiditic sedimentary rocks of the Mesoarchean Fig Tree Group on the steep western limb of the regional (D3), refolded, and distinctly arcuate Ulundi Syncline. Shear zones are preferentially localized along lithological contacts with pronounced rheological contrasts, particularly pronounced along the limbs of tightly infolded ultramafic schist against Fig Tree Group metasedimentary rocks. The main ore shoot of the MRC at Fairview shows a steep southeasterly plunge that can be traced for > 2000 m down-plunge, parallel to the fold hinge (F3b) that refolds the Ulundi Syncline. Fabrics and structures in the ore shoot record combined top-to-the NW thrust sense and dextral strike-slip kinematics and strongly constrictional strains interpreted to indicate dextral transpression and associated steep extrusion of the rocks during progressive NW-SE (D3) shortening. A combination of structural and lithological controls govern ore-shoot formation and gold mineralization. The main ore shoot corresponds to dilational jog geometry that developed during dextral transpression, bedding-parallel shearing consistent with the flexural-slip refolding (F3b) of the Ulundi Syncline. High-grade pockets correlate with sheared, commonly dismembered, graphite-rich and sulfide-mineralized shale units, testifying to the preferential fluid focusing and strain localization into incompetent shale units during deformation. Cross-cutting relationships with other auriferous reefs from the Fairview Mine complex indicate a late timing of the MRC-type mineralization, underlining the complex fluid focusing and utilization of differently orientated structures with different kinematics during progressive deformation and either episodic or protracted fluid flow events. [ABSTRACT FROM AUTHOR]

Archean spherule layers represent the only currently known remnants of the early impact record on Earth. Based on the lunar cratering record, the small number of spherule layers identified so far contrasts to the high impact flux that can be expected for the Earth at that time. The recent discovery of several Paleoarchean spherule layers in the BARB5 and CT3 drill cores from the Barberton area, South Africa, drastically increases the number of known Archean impact spherule layers and may provide a unique opportunity to improve our knowledge of the impact record on the early Earth. This study is focused on the spherule layers in the CT3 drill core from the northeastern Barberton Greenstone Belt. We present highly siderophile element (HSE: Re, Os, Ir, Pt, Ru, and Pd) concentrations and Re‐Os isotope signatures for spherule layer samples and their host rocks in order to unravel the potential presence of extraterrestrial fingerprints within them. Most spherule layer samples exhibit extreme enrichments in HSE concentrations of up to superchondritic abundances in conjunction with, in some cases, subchondritic present‐day 187Os/188Os isotope ratios. This indicates a significant meteoritic contribution to the spherule layers. In contrast to some of the data reported earlier for other Archean spherule layers from the Barberton area, the CT3 core is significantly overprinted by secondary events. However, HSE and Re‐Os isotope signatures presented in this study indicate chondritic admixtures of up to (and even above) 100% chondrite component in some of the analyzed spherule layers. There is no significant correlation between HSE abundances and respective spherule contents. Although strongly supporting the impact origin of these layers and the presence of significant meteoritic admixtures, peak HSE concentrations are difficult to explain without postdepositional enrichment processes. [ABSTRACT FROM AUTHOR]

• Extraterrestrial organic matter is detected by EPR in 3.33 Ga sediments. • It is associated with Ni-Cr-rich ferrite "cosmic" spinel nanoparticles. • A challenge for the research for organic traces of extinct life in Mars. Electron paramagnetic resonance (EPR) analysis of carbonaceous, volcanic, tidal sediments from the 3.33 Ga-old Josefsdal Chert (Kromberg Formation, Barberton Greenstone Belt), documents the presence of two types of insoluble organic matter (IOM): (1) IOM similar to that previously found in Archean cherts from numerous other sedimentary rocks in the world and of purported biogenic origin; (2) anomalous IOM localized in a 2 mm-thick sedimentary horizon. Detailed analysis by continuous-wave-EPR and pulse-EPR reveals that IOM in this layer is similar to the insoluble component of the hydrogenated organic matter in carbonaceous chondrites, suggesting that this narrow sedimentary horizon has preserved organic matter of extraterrestrial origin. This conclusion is supported by the presence in this thin layer of another anomalous EPR signal at g = 3 attributed to Ni-Cr-Al ferrite spinel nanoparticles, which are known to form during atmospheric entry of cosmic objects. From this EPR analysis, it was deduced that the anomalous sedimentary layer originates from deposition, in a nearshore environment, of a cloud of tiny dust particles originating from a flux of micrometeorites falling through the oxygen-poor Archean atmosphere. [ABSTRACT FROM AUTHOR]

• Archean barite in the Barberton Greenstone Belt was deposited along unconformities. • Barium was sourced from cold springs venting to the surface through fractures. • Sulfate was sourced from photolysis reactions in the atmosphere. • Deposition involved Ba-bearing spring water contacting sulfate-bearing meteoric water. • Barite geochemistry carries little information on composition of Archean sea water. Small sedimentary barite deposits are widespread in the 3.258–3.225 Ga Fig Tree Group, Barberton Greenstone Belt (BGB), South Africa. This report explores the stratigraphy of these units, the types of barite present, their depositional settings, and the controls on sedimentation in the Barite Valley area. Five morphological types of barite are recognized: masses of irregularly layered bladed barite termed barite plugs, mounded barite, barite splays, flat-layered bladed barite, and barite sand. In all areas studied, barite deposition was closely associated with active faults and fractures in the underlying rock sequences that are inferred to have been conduits by which barium-bearing fluids made their way to the surface. The barite deposits are also associated with unconformities below, within, and/or above the barite layers. Associated sedimentary rocks show evidence of deposition within intertidal, fan delta, and shallow water to subaerial settings. Previous sulfur isotopic studies have shown that the sulfate originated by photolysis in the atmosphere. We infer that the barite was deposited where barium-bearing, shallow subsurface waters vented to the land surface via mostly small, cool springs and interacted directly with sulfate-bearing meteoric waters, probably often rainwater, triggering barite precipitation. Plug barite marks spring vents, mounds developed in pools, and the outflow systems were characterized by layered bladed barite with increasing barite sand toward more distal settings. Associated thin jasper beds are thought to have formed by oxidation of sedimentary pyrite and siderite by meteoric waters carrying photolysis-produced oxidants, probably H 2 O 2 and perhaps O 2. The Barite Valley barite deposits do not appear to have developed in open marine or evaporitic settings and their geochemistry may carry little information on the composition of Archean sea water or nature of the underlying crust. [ABSTRACT FROM AUTHOR]

Highlights • Sediments were derived largely from shallow erosion of the BGB itself. • Deposition occurred in small-scale systems adjacent to local uplifts. • Onset of deposition was likely diachronous across the greenstone belt. • Adjacent structural belts show different evolution in provenance and lithology. • Structural belts may not have formed in spatial proximity to one another. Abstract Sedimentary rocks provide a valuable record of non-uniformitarian Paleoarchean tectonic processes. The rocks of the 3.28–3.23 Ga Mapepe Formation mark the initiation of orogenesis in the Barberton Greenstone Belt, South Africa. However, reconstruction of the Mapepe basin(s) is challenging because the rocks occur in fault-bounded structural belts that are characterized by lateral heterogeneity and whose correlation remains uncertain. We have studied the petrography, geochemistry, and detrital zircon geochronology from outcrop and drill core samples from two adjacent structural belts, the Manzimnyama Syncline and the Eastern Barite Valley area, to evaluate the timing of basin formation, correlate between these two adjacent areas, and provide constraints on the character of tectonic uplift. In the Eastern Barite Valley area sedimentation was initiated at about 3260 Ma. The section includes a lower, deep-water unit of mainly mudstone overlain by a shoaling-upward sequence of fan-delta sandstone and conglomerate. The sandstone throughout the formation was derived by erosion of local uplifts of the underlying greenstone-belt sequence except at the top of the section where sedimentation was dominated by dacitic volcaniclastic sediments dated at 3239 Ma. In contrast, rocks of the Mapepe Formation in the Manzimnyama Syncline area, 1–2 km south of the Eastern Barite Valley area, record the initiation of sedimentation at about 3277 Ma with deposition of a rhyolitic tuffaceous unit followed by persistent deep-water sedimentation of banded iron formation, banded ferruginous chert, and turbiditic sandstone. Siliciclastic sediments are immature and were derived by erosion of older supracrustal greenstone-belt rocks. No Fig Tree age volcanism younger than 3260 Ma is recorded in this belt. Overall, Mapepe sedimentary rocks record the formation of numerous local uplifts of underlying supracrustal rocks with periodic volcanic activity, and the dispersal of debris to form mainly small fan-deltas flanked by deep-water systems. The contrasting ages, lithologies, depositional settings, and provenance of the sedimentary rocks in the now adjacent Eastern Barite Valley and Manzimnyama Syncline belts suggest that they were deposited in either different parts of a large, complex Fig Tree basin or represent separate basins that have been juxtaposed during post-Fig Tree tectonism and shortening. [ABSTRACT FROM AUTHOR]

Documenting evidence of fossil microbial life on early Earth is made difficult by the paucity of suitable Archean sedimentary rocks, their common metamorphic overprint, the small outcrop areas, and the small size of the objects of interest. Although a large number of putative microfossils dating back as far as 3700 Ma have been described, the syngeneity and biogenicity of many occurrences is debated, and some of the proposed fossils have been found to be either contaminants or abiotic artefacts. The ~3200 Ma Moodies Group of the Barberton Greenstone Belt (BGB), South Africa, contains locally abundant and remarkably well-preserved microbial mats which show indirect evidence of photosynthetic activity. They also contain microstructures which strongly resemble remains of microbial cells. Detailed morphological and geochemical analyses, however, show that these structures mostly represent fragments of volcanic tephra. Our study demonstrates that opaque microstructures within microbial mats can potentially be misidentified as microfossils even when a strict protocol is followed. It also posits the question to which degree volcanic air-borne fertilization contributed to the remarkable growth rate, high mechanical tenacity and wide extent of these oldest tidal microbial mats in siliciclastic environments. [ABSTRACT FROM AUTHOR]

Graphical abstract Highlights • Gold-quartz veins along optimally orientated low-angle brittle-ductile thrusts. • Lithological and structural controls of auriferous reefs. • Fluid pressure driven fault-fracture mesh and ore-shoot formation. • Deformation related to post fold lock-up NW-SE regional shortening. Abstract The Hope reef forms part of a number of high-grade mineralized, but hitherto undocumented auriferous shear zones at Fairview Mine in the Barberton Greenstone Belt in South Africa, collectively referred to as the hanging-wall reefs. The reefs are hosted by steeply-dipping greywacke units of the Fig Tree Group on the western limb of the regional-scale Ulundi syncline. The currently mined shallow Hope reef represents a top-to-the northwest, low-angle thrust that formed as a secondary accommodation structure during continued NW subhorizontal shortening after the lock up of the Ulundi syncline. Northwest shortening strains correspond to the main phase of upright regional folding (D 2/3) in the greenstone belt. The formation of shear and extensional vein sets documents fault-valve behaviour along the low-angle thrust, driven by close-to-lithostatic fluid pressures and under very low differential stresses (<5 Mpa). High-grade ore shoots in the plane of the shallow reef delineate lithologically and structurally controlled interconnected fault-fracture meshes. Bedding planes in Fig Tree greywacke units have provided suitably orientated anisotropies that promoted the development of a wider, anastomosing shear-zone system. The shear zones envelop lithons of relatively competent greywacke units. Slip transfer from shears into the competent lithons induced extensional and shear fractures and the formation of an interconnected fracture network in and between lithons recording a net dilation of up to 50-60 vol%. Individual lithons show extents of 20–25 m2, but ore shoots defined by imbricated lithons cover areas of several hundred square metres. Mutually cross-cutting extensional veins sets and local domains of normal slip point to transient stress switches related to periods of post-slip relaxation and rapid fluid pressure build up prior to the restoration of horizontal stresses and reverse slip along the shallowly dipping reef. The hanging-wall reefs at Fairview Mine underline the formation of mineralized reefs in the Barberton gold district with vastly different orientations, structural and lithological controls, either in sequence or broadly contemporaneous, but during the late-stage shortening of the greenstone belt. The absolute timing of this deformation and associated hydrothermal events remain unclear. [ABSTRACT FROM AUTHOR]

This review paper reports on the discovery of komatiites and the impact this has had on the geosciences internationally. Komatiites were first discovered by Richard and Morris Viljoen in the Barberton greenstone belt of South Africa and proposed as a new class of ultramafic volcanic rock with >18 wt% MgO. Komatiites are in places associated with spinifex textures (elongated bladed and plumose olivine crystals). The discovery and petrological study of komatiites and understanding of the field controls have given rise to intense debate about their mantle origin, water content and geodynamic setting of eruption. The observation that komatiites are found predominantly in the Archean and to some extent in the Palaeoproterozoic, has led to the proposition that the early Earth was much hotter (by c. 400 °C) than the present day. However, some workers have challenged this model involving secular cooling of the Earth since Archean times. These workers argue that komatiites formed in a cooler Archean subduction zone, rather than in a mantle plume. Komatiites of the mid-to late-Archean have also proven to be important economically (e.g. Yilgarn Craton, Australia; Superior Craton, Canada) as they host important nickel-sulphide deposits. Today, novel petrological techniques (e.g. secondary ion microprobe analyses of olivine melt inclusions) are being applied to komatiites to address important outstanding questions in the geosciences, including the question of whether or not plate tectonics was operating in the early Archean. • Komatiites were discovered in 1969 in the Barberton greenstone belt, South Africa. • Significance of komatiites (ultramafic volcanics) to the geosciences is explored. • Origin of komatiite spinifex textures is explored. • Komatiites are found largely in the Archean suggesting the early mantle was hotter. • Debated aspects: their mantle origin, water content, and geodynamic setting. [ABSTRACT FROM AUTHOR]

The Stolzburg Complex is a prominent and well-preserved Palaeo- to Mesoarchaean layered ultramafic-mafic complex in the vicinity of the Barberton Greenstone Belt. Whole rock Sm-Nd, Lu-Hf and 142Nd isotopic data obtained from a variety of lithologies, and augmented by major and trace element geochemistry, are presented to examine petrogenesis, magma source composition, and mantle differentiation as well as the geodynamic setting of emplacement. Geochemically, all samples are characterized by unfractionated normalized trace element patterns (La/Lu chond. = 0.7–2.3, La/Gd chond. = 0.6–1.7, Sm/Lu chond. = 0.9–1.4) associated with weak HFSE anomalies (Nb/[0.5Th + 0.5La] PRIMA = 0.5–2.3). Trace element concentrations vary as a function of mineralogy, but differences in trace element compositions are unsystematic across lithologies. The coherence of trace element characteristics is consistent with a common mantle source that underwent moderately large degrees of melting at mantle pressures within the spinel stability field. Whole rock Sm-Nd and Lu-Hf data yield well-defined apparent isochrons corresponding to ages of 3367 ± 62 (n = 12, MSWD = 1.5) and 3396 ± 36 (n = 11, MSWD = 2.1), respectively. Initial Hf and Nd isotopic compositions vary from +3.3 to +5.7 and + 0.9 to +1.7, respectively, indicative of derivation from slightly to moderately depleted mantle source(s). Isochron ages and a regressed initial Hf isotopic composition of +4.0 ± 0.9 (at 3.4 Ga) contrast with an established U-Pb emplacement age (zircon, titanite) of 3.25 Ga and ε Hf values for zircon of −2.5 to +3.0. Hydrothermal alteration or weathering, incorporation of evolved pre-existing (continental) crust and fractionation by high-pressure phases prior to melt extraction can all be ruled out to have significantly affected isotope systematics. Protracted magma chamber activity and non-synchronous emplacement of unrelated gabbroic magmas also fail to fully account for the discrepancy between whole rock and mineral age and isotopic data. Instead, the coherence in apparent isochron ages and variability of initial Hf and Nd isotopic composition is adequately explained by reworking (partial or near-complete remelting) of aged mafic-ultramafic (likely oceanic) crust in staging chambers with compositions indistinguishable from newly formed magmas. Thus, apparent isochrons represent mixing lines and do not record timing of crystallization. A subset of samples was also analyzed for 142Nd isotopic compositions to trace preserved mantle heterogeneities caused by early Archaean crust-mantle differentiation. The results (μ142Nd = −2.3 ± 2.2 to +1.7 ± 2.1) are not resolvable from the modern mantle value, indicating that 142Nd-enriched or depleted mantle reservoirs had not remained isolated from convective homogenization in the asthenosphere, or the volume of mantle underlying the layered complex was too small to sample mantle heterogeneities. The Stolzburg Complex was possibly emplaced in ancient oceanic lithosphere, followed by pervasive but inhomogeneous Ca-metasomatism as documented by exposed rodingites. [ABSTRACT FROM AUTHOR]

Understanding the architecture of the West African craton at depth is essential to be able to reconstruct its evolution. Our study focuses on the crustal imaging of structures and geometries characterizing the crust of the Leo-Man shield with broadband and long period magnetotelluric data collected in southern Burkina Faso and covering a 220 km long profile. The resulting 3D resistivity crustal model highlights the distribution of the granite-greenstone assemblages with depth showing excellent correlation with mapped surficial lithologies. The whole crust of southern Burkina Faso is resistive, with lateral as opposed to vertical major resistivity contrasts, reflecting the location of major-scale shear zones characterizing this part of the Baoulé-Mossi domain. Ground gravity data acquired along the same line as the MT data were also modeled and show relatively good correspondence with the resistivity model. The new resistivity and gravity models compared with results from joint inversion of gravity and aeromagnetic data highlight significant changes between the greenstone belts and granitoid domains along the profile. The comparison of the geophysics with the geology enables us to define new depth constraints of the main tectonic features in the area. The observed large scale dipping shear zones favour the model of crustal building through major parallel thrust faults. [ABSTRACT FROM AUTHOR]

The occurrence of Early Archean barite deposits is intriguing since this type of sediment requires high availability of dissolved sulfate (SO 4 2− ), the oxidized form of sulfur, although most authors argued that the Archean eon was dominated by reducing conditions, with low oceanic sulfate concentration (<10 μM) relative to present day levels of 28,000 μM. In order to better assess the redox state of the paleo-atmosphere and -oceans, we examined Fe and S isotope compositions in a sedimentary sequence from the 3.2 Ga-old Mendon and Mapepe formations (Kaapvaal craton, South Africa), recovered from the drill-core BBDP2 of the Barberton Barite Drilling Project. Major elements were also analyzed to constrain the respective imprints of detrital vs metasomatic processes, in particular using Al, Ti and K interrelations. Bulk rock Fe isotope compositions are linked to mineralogy, with δ 56 Fe values varying between −2.04‰ in Fe sulfide-dominated barite beds, to +2.14‰ in Fe oxide-bearing cherts. δ 34 S values of sulfides vary between −10.84 and +3.56‰, with Δ 33 S in a range comprised between −0.35 and +2.55‰, thus supporting an O 2 -depleted atmosphere (<10 −5 PAL). Iron isotope variations together with major element correlations show that, although the sediments experienced a pervasive stage of hydrothermal alteration, the rocks preserved a primary/authigenic signature predating subsequent hydrothermal stage. Highly positive δ 56 Fe values recorded in primary Fe-oxides from ferruginous cherts support partial Fe oxidation in a reducing oceanic environment (O 2 < 10 −4 μM), but are incompatible with a model of complete oxidation at the redox boundary of a stratified water column. Iron oxide precipitation under low O 2 levels was likely mediated by anoxygenic photosynthesis, and/or abiotic photo-oxidation processes. Our results are consistent with global anoxic conditions in the 3.2 Ga-old sediments, implying that the barite deposits were most likely sourced by atmospheric photolysis of S gases produced by large subaerial volcanic events, and possibly SO 4 2− produced by magmatic SO 2 disproportionation in hydrothermal systems. [ABSTRACT FROM AUTHOR]

Recognition of oceanic crust in Archean greenstone belts has remained a controversial and unresolved issue, with implications for understanding early Earth geodynamics. In the search for early Archean oceanic crust, we present a multi-pronged approach to test for the presence of an ophiolite-type sequence preserved in the Paleoarchean Barberton greenstone belt (BGB) of South Africa. New field observations are combined with detrital U-Pb zircon geochronology and geochemistry on fresh drill-core material from the Kromberg type-section sequence of mafic-ultramafic rocks in the 3.56-3.33 Ga Onverwacht Group of the BGB. Trace element geochemistry indicates that the Kromberg metabasalts were derived from the primitive mantle. The εNd values and Nd model ages of the metabasalts record a depleted Archean mantle source similar to CHUR (chondritic uniform reservoir) with no continental (tonalite-trondhjemitegranodiorite [TTG]) crustal contamination. U-Pb geochronology by laser ablation-inductively coupled plasma-mass spectrometry on detrital zircons from an uppermost chert unit indicate a homogeneous age distribution and a gabbroic source in the greenstone belt, in direct contrast to zircons from felsic conglomerates structurally underlying the Kromberg sequence. Collectively, the new data and field observations indicate that the 3.33 Ga Kromberg mafic-ultramafic sequence formed in a juvenile oceanic setting and represents a remnant of tectonically accreted oceanic crust. The identification of oceanic crust preserved as dismembered allochthons in the BGB suggests that horizontal plate tectonic processes were operating on the Archean Earth as early as Mesoarchean times. [ABSTRACT FROM AUTHOR]

Gold occurs in a variety of ancient geological environments in South Africa, the most well-known being the unique Witwatersrand Basin in the central part of the Kaapvaal Craton. Outside of the Witwatersrand Basin significant quantities of gold have been recovered from Archaean greenstone belts of the 3500 to 2700 Ma Kaapvaal Craton as well as from various occurrences in the 2600 to 2200 Ma Transvaal Supergroup. Very little gold has been found in younger formations. Archaean greenstone belts in South Africa are characterised by substantial sequences of ultramafic (komatiitic) volcanic rocks generally overlain by mafic volcanic successions which, in turn, are overlain in some cases by greywacke-shale sequences and younger arenaceous lithologies. Highly sheared and carbonate altered ultramafic zones, together with the immediately surrounding country rock, host some of the most important gold deposits on the Kaapvaal Craton. In the northern part of the Barberton Greenstone Belt, shearing tends to be most intense along the contact of the ultramafic schists of the Zwartkoppie Formation and the overlying greywackeshales, the contact being marked by the presence of a chert "bar" or banded iron formation (BIF) horizon. Gold mineralisation occurs below, above and/or within the more competent and fractured chert/BIF marker horizon. The locus of gold mineralisation is typically controlled by the rheological characteristics of the wallrocks in the proximity of the shear systems, e.g. the ductile greywacke-shale strata are tightly folded with sub-parallel mineralised shear zones, while competent arenaceous rocks have yielded in a brittle manner resulting in high-angle mineralised fractures. Extensive carbonate alteration in ultramafic rocks is often present along, and in the vicinity of, shear zones where potassium alteration results in a vivid green coloration due to the formation of fuchsite (Cr-mica) and where zones of silicification and quartz veining are closely associated with gold, arsenic and antimony mineralisation. Where mafic rocks act as more competent and fractured hosts to mineralisation, carbonate alteration results in the breakdown of ferromagnesian minerals and the liberation of considerable quantities of silica, manifested as silicification and as mineralised quartz veins. The breakdown of mafic minerals results in "bleaching" of the rocks as carbonate minerals replace ferromagnesian minerals, but may also result in the development of green, brown or black schists depending on the composition of the host rocks. One or more of the above alteration rock types and mineralisation styles is present in virtually all of the greenstone-hosted gold deposits of the Kaapvaal Craton. Wherever available, geochemical data is consistent with alteration fluids of relatively uniform composition but the style of the resultant mineralisation is ultimately dependent on the nature of the host rock.Greenstone gold deposits are irregularly distributed, both in terms of their size and distribution. Only about 1% of greenstone deposits can be regarded as successful mines, while the vast majority remain as showings. Geographically, these gold deposits are preferentially located along litho-structural features where both fluid flow and wallrock conditions were suitable for mineralisation. These criteria are restricted to major structural nodes, significant lineaments, or lithological units, with the result that the stronger mineralising systems tend to be concentrated in finite gold "camps" which host the larger deposits and numerous styles of mineralisation, e.g., the Sheba-Fairview Complex on the refolded arcuate Eureka and Ulundi synclines. Gold hosted in BIFs is a widespread association, but rarely economic except where the nature of the mineralisation allows for economic extraction, e.g., in the Kraaipan Greenstone Belt, where the volume of BIF is large enough to contain the mineralised fracture system. Gold in the Paleoproterozoic Transvaal Supergroup occurs in the lowermost Black Reef Formation quartzites as detrital accumulations in conglomerate channels, but more abundantly as epithermal veins in the dolomite of the overlying Malmani Subgroup and shale of the Pretoria Group as vertical cross-cutting veins and sub-horizontal reefs emplaced along parting planes. The quartz-carbonate-sulphide veins differ from Archaean ores in that gold rarely impregnates the wallrocks; they contain significant carbon which impedes gold recovery, and they contain silver, copper, arsenic, bismuth, lead and zinc in addition to gold. [ABSTRACT FROM AUTHOR]

The Mendon Formation is the uppermost unit of the 3.5–3.26 Ga Onverwacht Group in the Barberton Greenstone Belt, South Africa. It consists of a cyclic stack of komatiitic volcanic units separated by thin cherty sedimentary layers. In most areas, the uppermost Mendon Formation is a sedimentary interval characterized by black chert, banded black-and-white chert, and banded ferruginous chert, although the detailed patterns of lithofacies in different sections are more complex. Previously reported zircon U/Pb ages suggest that Mendon deposition could represent more than 70 Myr of time between ∼3334 Ma and ∼3260 Ma. This study presents sedimentological and petrographic observations of the upper Mendon Formation from across the central part of the Barberton Greenstone Belt in order to investigate sediment sources, depositional processes, and environments of sedimentation. The dominant mode of sedimentation was quiet settling of carbonaceous grains and, in the deepest sections below storm wave base, fine ferruginous material, resulting in finely laminated black and grey chert. In situ carbonaceous laminations are rare, suggesting that benthic microbial mat growth had little direct influence on deposition. The hemipelagic background deposition was punctuated by occasional inputs of fine pyroclastic debris, formation and deposition of silica granules, and reworking by infrequent storm events. Storm deposits are represented by coarse-grained, poorly-sorted intraclast breccias, some of which include distinctive intraclasts sampling lithofacies that are not observed in situ . Despite considerable lateral variability, correlative temporal trends are resolvable in many Mendon sections: there is an upward-deepening of the overall depositional setting recorded in the oldest upper Mendon sections, consistent with the previous interpretation that Mendon time was characterized by rifting (Lowe, 1994a, 1999a). Younger Mendon cycles include thick, relatively ferruginous basal sections, interpreted to reflect the deepest water deposition. These sections are capped by black chert and silicified ashes with more evidence of disturbance and reworking by storms, reflecting gradual shoaling. This sedimentological analysis is broadly consistent with previous geochemical and tectonic analyses and provides a better picture of depositional patterns during uppermost Onverwacht time, before the distinct change in tectonic regime marked by impact spherule layer S2 and the onset of Fig Tree Group orogenesis and related siliciclastic deposition. [ABSTRACT FROM AUTHOR]

Zircon age data for felsic metavolcanic rocks of the Sandspruit and Theespruit formations, the two oldest supracrustal components in the Palaeoarchaean Barberton Greenstone Belt, show that these two successions are time-equivalent and constitute one single volcanic event at ca. 3530 Ma. The Sandspruit felsic rocks are ubiquitously metasomatized, intensely deformed and intruded by, and tectonically interlayered with, ca. 3450 Ma granitoid sills that are probably part of the Theespruit Pluton. One metasomatized Sandspruit sample contains abundant metamorphic zircons with a weighted mean 207 Pb/ 206 Pb age of 3220.1 ± 1.6 Ma, reflecting a widespread metamorphic event in parts of the eastern Kaapvaal craton in South Africa and Swaziland. Several samples of felsic metavolcanic rocks of the Theespruit formation confirm a previously established magmatic emplacement age of ca. 3530 Ma, but slightly older rocks up to 3552 Ma were found in the easternmost exposure of the Theespruit sequence near the South African/Swaziland border and may represent a lower lithostratigraphic level than exposed farther west. Hf-in-zircon isotopic data for most felsic metavolcanic rocks confirm earlier results suggesting that these rocks predominantly originated from melting of a felsic continental basement, possibly related to the oldest, ca. 3660–3550 Ma components of the Ancient Gneiss Complex in Swaziland. However, several Sandspruit samples also suggest that a juvenile source was involved in their generation, perhaps a mafic underplate. We see no evidence in the geochemistry and isotopic signatures of felsic volcanic rocks of the Sandspruit and Theespruit formations for partial melting of a metabasaltic protolith and for Palaeoarchean oceanic crust that formed in connection with subduction. We rather favor a plateau-type setting on older continental crust. [ABSTRACT FROM AUTHOR]

Lithic sandstones of braided-fluvial to supratidal facies in the Paleoarchean Moodies Group (∼3.22 Ga, Barberton Greenstone Belt, South Africa) include several regionally traceable units with common to abundant, in places rock-forming, nodular concretions of megaquartz pseudomorphs after gypsum, barite and calcite. Concretionary accumulations are stratiform and commonly associated with aqueously reworked, fine-grained, tuffaceous sediment of originally rhyodacitic composition and can grow to fist-sized agglomerates in crusts tens of m in lateral extent. Weathering of tuffaceous material and feldspar delivered alkali cations such as Ca, Ba, and K, while carbonates were likely supplied by silicate weathering of mafic to ultramafic volcanic rocks during exposure to a CO 2 -rich atmosphere. Sulfate ions were partly delivered by oxidative pyrite dissolution which may have included microbial and abiotic disproportionation of volcanic S or SO 2 . Concretionary growth apparently took place under pedogenic to early diagenetic conditions within unconsolidated granular sediment in the vadose zone, dominated by seasonal fluctuations of the groundwater level under evaporitic conditions. The concretions likely represent the oldest terrestrial evaporites known to date and form part of the oldest known compound paleosols. Their formation and composition constrain the local occurrence of sulfate in the Archean atmo- and hydrosphere, their interaction with the emerging biosphere, Archean weathering regime, local climate, and vadose-zone hydrodynamics. [ABSTRACT FROM AUTHOR]

A response from the author of the article "Paleo-to Mesoarchean polymetamorphism in the Barberton Granite-Greenstone Belt, South Africa: Constraints from U-Pb monazite and Lu-Hf garnet geochronology on the tectonic processes that shaped the belt: Discussion" in the previous issue is presented.

A letter to the editor is presented in response to the article "Paleo-to Mesoarchean polymetamorphism in the Barberton Granite-Greenstone Belt, South Africa: Constraints from U-Pb monazite and Lu-Hf garnet geochronology on the tectonic processes that shaped the belt" in the previous issue.

In conjunction with major, trace and rare earth element data, this study presents the first whole-rock Lu Hf isotope analyses of mafic-ultramafic rocks of the c. 3.3 Ga Kromberg type-section in the Barberton greenstone belt of South Africa. Three compositionally distinct volcanic rock types are identified namely Group 1 metabasalts, Group 2 metabasalts and komatiitic metabasalts. Group 1 metabasalts are Fe Mg tholeiitic with compositions that plot close to the Primitive Mantle composition, have isochron intercept ε Hf(t) value of 0.01 ± 0.4 and Eoarchean Hf model ages. Group 2 metabasalts have very high Al 2 O 3 /TiO 2 ratios (c. 50), small negative Nb anomalies, LREE-depleted slightly concave up REE patterns, and negative ε Hf(t) values. The komatiitic basalts variably record small negative Nb anomalies in a primitive mantle normalized plot. Group 1 metabasalts and cumulate peridotites (wehrlites) yield a Lu Hf isochron age of 3.340 ± 0.190 Ga (95% confidence level). The highly variable major and trace element geochemistry of the rocks in the sequence implies highly dynamic and variable mantle melting environments. The Group 2 metabasalts have geochemical characteristics similar to that of boninites and are interpreted to have formed from a shallow, refractory mantle source. Group 2 metabasalts are argued to have formed in a proto-plate tectonic back-arc basin involving crustal contamination, whereas Group 1 metabasalts likely formed from within a deep mantle plume. [ABSTRACT FROM AUTHOR]

Hydrothermal vein systems illustrate the spatial and temporal evolution of structural permeabilities along the Sheba Fault, the first-order fault structure in the Sheba-Fairview complex of gold mines in the Archaean Barberton greenstone belt. The fault juxtaposes competent Moodies Group metapsammites against rheologically weaker metaturbidites and intercalated serpentinites of the Fig Tree and Onverwacht groups. Strain localization into the weaker lithologies results in the pronounced asymmetric zonation of the fault into a fault core and a fault-damage zone. The fault core in the weaker Fig Tree and Onverwacht lithologies is characterized by the transposition of earlier bedding and pervasive foliation development. In contrast, hydrothermal veining, alteration and mineralization are confined to competent Moodies Group rocks that form the tens of meter wide damage zone in the immediate footwall of the fault core. Vein systems of the Sheba West ore body disclose the multistage evolution of the fluid flow system along the fault. An early phase of crackle-breccia formation and associated carbonate (dolomite) alteration is regionally widespread and largely pre-dates the main phase of gold mineralization. Crackle breccias are overprinted by successive sets of subhorizontal and subvertical extension (mode I) veins, steeply inclined shear veins and moderately-dipping late-stage cataclasites. The orientation and controls of the vein sets demonstrate their formation during (1) progressive NW-SE directed subhorizontal shortening, and (2) waning fluid pressures from lithostatic values (mode I veins) to sub-lithostatic fluid pressures (mode II shear veins and cataclasites). The economic-grade mineralization of the Sheba West ore body relates to an undulation of the controlling Sheba Fault that corresponds to a releasing bend during top-to-the-NW thrusting. The vein systems along the Sheba Fault illustrate the controls of permeability structures as a result of lithological and rheological contrasts, geometric variations (fault bends) and fluid-pressure fluctuations during faulting. [Display omitted] • Fault zone architecture and hydrothermal fluid flow. • Lithological competence contrast and localization of deformation and alteration. • Late-stage mineralization during regional NW-SE shortening. • Fault zone structural anisotropies, fracturing, dilation and fluid-focusing. • Gold mineralization associated with the Sheba Fault. [ABSTRACT FROM AUTHOR]

The 3.45 Ga old felsic volcanic rocks from the Barberton Greenstone Belt of southern Africa include a submarine succession of felsic lavas and volcaniclastic rocks and shallow subvolcanic intrusions. Sea floor alteration strongly affected rock compositions shortly after emplacement, making comparisons with coeval intrusions challenging. We analysed well-preserved quartz-hosted melt inclusions from the felsic rocks, which offers a unique opportunity to gain insight into pre-alteration melt compositions. Melt inclusion compositions are then compared with whole-rock analyses to evaluate the significance of the volcanic complex in the context of Archaean felsic magmatism in the Barberton Greenstone Belt. Whole-rock immobile trace element concentrations, including high-field strength and rare earth elements, indicate strong similarities with coeval tonalite–trondhjemite–granodiorite intrusions. These same geochemical characteristics distinguish these rocks from other Archaean felsic rocks in the Barberton Greenstone Belt (e.g. the 3.54 Ga Theespruit Formation), which have characteristically higher Th, Nb and REE. Low CaO (≤ 1 wt.%) and relatively high Nb and Th (mostly ≤ 9 and ≤ 13 ppm, respectively) in comparison with least altered whole-rock samples, and the presence of negative Eu anomalies are consistent with the melt inclusions being relatively evolved, rather than representing primitive compositions. Melt inclusion analyses suggest the presence of two melts with varying K 2 O/Na 2 O. Melt inclusions from extrusive samples, which contain remnants of K-feldspar phenocrysts, have K 2 O/Na 2 O > 1 by weight, whereas subvolcanic intrusions, which contain Na-rich plagioclase, have K 2 O/Na 2 O < 1. Moderately high Cl contents (Cl ≤ 0.7 wt.%) of melt inclusions may record interaction of the melting protolith with sea water prior to melting. We speculate that the varying K 2 O/Na 2 O in the felsic volcanic rocks was due to melting of a greenstone succession heterogeneously affected by sea floor alteration. [ABSTRACT FROM AUTHOR]