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AbstractThe primary heat transfer source in the conventional multi-cylinder drying of paper and board is conduction. Conduction is facilitated by high-tension contact with steam-heated cylinders, while convective drying, the main mass transfer source, operates as heated air flows over the article web in the pockets. This conduction process occurs at elevated temperatures and contact pressures to ensure effective contact between the wet paper web and the heated cylinders. The contact pressures and temperatures of the hot surface significantly influence the conductive drying characteristics. This research paper presents an experimental study that involves designing a simple lab-scale setup with in-situ and continuous sensing capabilities for various commercially available grades of paper and board. Embedded thermocouples measure the temperatures of the heated platen and the sheet, allowing the collection of flux data to determine heat transfer characteristics. The goal of this study is to ascertain the instantaneous contact coefficients for different basis weights as a function of moisture content. The acquired data will provide valuable insights and information toward process development, design, and simulation of the article drying process. [ABSTRACT FROM AUTHOR]

Abstract Temperature and humidity are the main factors that cause the decomposition of Nomex paper widely used as turn‐to‐turn insulation material of mining dry‐type transformers. In this study, for understanding the effect of ambient humidity and thermal aging on the properties of Nomex paper, specimens with the initial moisture content of 7% were aged in the oven for 168, 504, 672 h at 180°C, respectively. After thermal aging, corona discharge experiments of unaged and aged specimens with different aging degrees were carried out at different relative humidity (RH) levels from 10 to 70%. The characteristic parameters of corona discharge, such as the average discharge amplitude and the number of discharges, were measured. Then, the surface conductivity and the surface potential decay rate were measured. The morphology and attenuated total internal reflectance Fourier transform infrared spectroscopy were also analysed for explaining the difference of properties between unaged and aged specimens. The experiment results indicate that the average discharge amplitude decreases with the increase of RH or the deepening of the aging degree of specimens, but the number of discharges shows the reversal tendency. The changes in the physical structure and chemical composition, which is induced by the hydrolysis reaction of Nomex paper, accelerate the surface potential decay and increase the surface conductivity.

The influence of strain during drying is known to have a large effect on its mechanical properties like tensile strength, Young's modulus and hygroexpansion. In this study we investigate free and restrained dried paper and investigate the relation between the paper microstructure and its mechanical properties. The first part of the work investigates the development of the mechanical properties as well as paper internal stresses and strains (elastic-, inelastic- and hygrostrain) at different moisture contents during the drying process. Emphasis is put on the changes of hygrostrains and the paper hygroexpansion coefficient during drying. One main finding was that in constrained drying the drying stresses are considerably below the yield stress and, as a consequence, the deformations are mainly inelastic (creep) and only marginally elastic. In the second part we are analyzing the microstructure of free and restrained dried sheets by X-ray microtomography (μ -CT). From the μ -CT analysis relevant network parameters such as number of contact points, fiber bond area, free fiber length and fiber curl were extracted. Also a novel method to investigate the interface angle of the fibers in the vicinity of the bond sites was established. The results showed that the major difference from the drying procedure manifests itself in the out-of-plane curl of the fibers. Statistically number of contact points, bond area and in-plane curl were not different whereas in-plane curl and free fiber length were different. The interface angle appears to be slightly affected by the drying procedure but is overall very low. [ABSTRACT FROM AUTHOR]

A computationally efficient method to study the in-plane and out-of-plane dimensional instability of thin paper sheets under the influence of moisture changes is presented. The method explicitly resolves the bonded and the free segments of fibers in the sheet, capturing the effect of anisotropic hygroexpansion at the fiber level. The method is verified against a volumetric model. The importance of longitudinal fiber hygroexpansion is demonstrated in spite of the absolute value of longitudinal hygroexpansion being an order of magnitude lower than the transverse hygroexpansion component. Finally, the method is used to demonstrate the formation of macroscopic sheet curl due to a moisture gradient in structurally uniform sheets in the absence of viscoelastic or plastic constitutive behavior and through-thickness residual stress profiles. [ABSTRACT FROM AUTHOR]

Drying of paper during 2000–2018 is reviewed. The review includes new drying processes, multi-cylinder dryers, tissue and impingement drying, TAD-drying, infrared drying and energy use for drying of paper. It includes general aspects of infrared dryers but not drying of coated papers. Paper quality aspects, paper shrinkage and paper isotherms are not included. Impingement drying has been the most successful new technology with several applications while others such as impulse drying has not been commercialized mainly due to problems with paper quality parameters. One promising development is the introduction of steel instead of cast iron cylinders with increased heat transfer reducing the number of cylinders. Future research should focus on modeling the internal transport phenomena and to couple these phenomena to paper shrinkage and quality parameters. The influence of the fabric for the drying process needs more attention, understanding the drying process for new components such as microfibrillar cellulose in the stock and reducing energy use and increasing the amount of renewable energies for drying of paper. [ABSTRACT FROM AUTHOR]

Abstract A number of problems associated with dimensional stability of paper products have to do with hygroexpansion in response to changes in humidity or moisture content. The main underlying mechanism of hygroexpansion in paper is the effect of the change of fiber cross-sections transferred through fiber bonds. In fact, the transverse expansion of fibers can be an order of magnitude greater than the longitudinal expansion. Addressing such problems using modeling on the microscale is associated with large computational costs since both the bonds and the fibers need to be resolved. We present a method for modeling the hygro or thermal expansion of interconnected fiber networks modeled with beam elements and connected through beam-to-beam contact. Being a line structure, beams can only support pointwise contact, which poses a challenge for modeling the force transfer induced by the deformation of the cross-sections at the contact point. The idea of implementing the stress transfer is to use a concurrent multiscale approach in which the bond level is resolved in detail using the configuration of the fibers and the computed strains are passed over to the beam elements. We verify and prove the applicability of this approach by comparing it with continuum models. We demonstrate the advantage of using this approach in terms of its tremendous saving in time. The use of beam models for modeling the hygro- or thermal expansion of fiber networks enables considering relevant sizes in the problems involving dimensional stability, in particular those associated with embedded inhomogeneities. We will show the applicability of the model by providing insights into published experimental observations on the hygroexpansion properties of paper products. Finally, we will demonstrate that the use of a 2D model to simulate the inter-fiber bonds in a network, not only leads to underestimation of out-of-plane deformations, but also to overestimation of the contribution of the transverse deformation of fibers to the in-plane dimensional change of the network. [ABSTRACT FROM AUTHOR]

Heat and moisture treatments were shown to affect restoration of the capillary-porous structure of paper folders that was lost during drying. Thermodynamic functions of cellulose water of hydration were calculated for hydrothermal treatment over broad ranges of time and temperature. The effects of saturated vapor with high state parameters on paper strength were demonstrated. [ABSTRACT FROM AUTHOR]

The present study investigates the phenomenon of steam condensation in a rectangle horizontal channel with a mass flux range of 20–70 kg/m2/s and a vapor quality of 0.2–0.8. Mass flux and vapor quality were presented to primarily affect the heat transfer coefficient in shear-dominated flow regime, such as the mass flux is greater than 40 kg/m2/s. At the low mass flux, only slug flow, plug flow, and wave flow were observed. At the high mass flux, the wave flow and annular flow were observed even at the low-vapor quality, and the slug and plug flow were not found during the entire condensation process. Observed flow patterns agreed with Tandon’s flow pattern map. Four kinds of correlations are employed to predict the condensing heat transfer coefficient, and the result reveals that Cavallini’s correlation agrees with the experimental results relatively well. The measured pressure drop has a good agreement with the Lockhart–Martinelli correlation. [ABSTRACT FROM PUBLISHER]

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In this paper an original and exhaustive mathematical modelling of air impingement drying systems for the production of tissue paper in the Yankee-hoods configurations is reported, which offers the possibility to optimize its energy performance. The model takes into account many detailed operative parameters of the overall drying process with the aim to execute its energy and mass balance and to evaluate its energy performances. The validity of the mathematical model has been assessed by comparison with actual data from an existing tissue paper mill. Finally, the energy performances of two different layouts of the air system have been evaluated and compared. Changing the operative parameters of the drying process, such as air jet temperature and speed and moisture content of the extraction air, it is possible to obtain the same paper production with an energy saving of about 4.5%. In average, the layout with two parallel air circuits assure an energy saving of about 1% with respect to the layout with a single air circuit. [ABSTRACT FROM AUTHOR]

A novel methodology was used to create a highly porous foam-formed paper that is bonded with highly refined cellulose fiber. In this process, cellulose pulp suspension at various consistencies (0.5, 1.0, 1.5, and 2%) was dispersed in water, followed by foam formation under high shear forces in the presence of a surfactant. Various drying methods were used to achieve foam formation. These included freeze-drying (FD), vacuum-dewatered air-drying (VAD), and dewatered freeze-drying (VFD). Increasing the pulp's consistency and changing the drying techniques from freeze-drying to air-drying resulted in a more compact morphological structure and increased density of foam-formed paper samples. Densification of foam-formed samples was measured using a Dynamic Mechanical Analysis (DMA) machine and a sample with densification at lowest strain value was obtained by a 10 wt% addition of microfibrillated cellulose fiber (MFC). At 10 wt% MFC addition, denser foam-formed paper samples with enhanced microstructure were obtained. Air filtration efficiency and acoustic properties of foam-formed paper were also characterized and optimized by the addition of MFC. [ABSTRACT FROM AUTHOR]

Paper drying is a highly energy-intensive and complicated multivariate process. The dryer section plays an important role in the energy consumption of a paper machine, especially of thermal energy. A comprehensive method for assessing the energy performance of the dryer section was investigated in this study to improve energy efficiency. This method was divided into three component processes: energy and evaporation load audit, field test and observation, and energy flow analysis and energy efficiency estimation. In a case study, we found that the method could, in addition to analyzing the key factors that restrict drying efficiency, also depict the details of energy consumption clearly. At the same time, several significant energy-saving measures were suggested to improve the energy efficiency of the paper-drying process. [ABSTRACT FROM PUBLISHER]

This article introduces a method to validate heat of sorption measurements from isotherms by comparing them to direct measurements using reaction calorimetry. We have evaluated some frequently used single-temperature isotherm models (BET, GAB) as well as two multi-temperature isotherm equations (Anderson, Heikkilä). It turned out that the isotherm models with better isotherm curve fitting characteristics did not deliver the best results for the heat of sorption. Multi-temperature isotherm models such as the Heikkilä equation are able to deliver good results in terms of modelling the isotherm data and determining the heat of sorption. Single-temperature models fit the isotherm data better than multi-temperature models, but failed to deliver correct values for the heat of sorption. We specifically investigated the heat of sorption at very low moisture content, which is most relevant for paper drying. The resulting heat of sorption curves were analyzed with respect to their saturation behavior, which is expected to occur below BET monolayer moisture. The heat of sorption from the Heikkilä’s model was the only one to show the expected saturation at very low moisture content. [ABSTRACT FROM PUBLISHER]

The main paper conservation methods are presented, classified in the following categories: preparation of the intervention, disinfestation and disinfection/sterilization, surface/dry cleaning, wet cleaning, chemical stabilization, paper repairs, consolidation and strengthening. Treatment documentation is also discussed. The targets, the historical aspects, the general principles, the materials and equipment, the acceptance and criticism pertaining to each method are briefly reviewed, and the most important research for their evaluation is presented. Several paper stabilization strategies, such as deacidification and iron gall ink stabilization, applicable to paper are elucidated. Specific consolidation and strengthening methods for paper, such as lamination and paper splitting are also discussed. The review mainly focuses on the established methods, but experimental, abandoned or insufficiently documented methods are also included. Shortcomings and limitations of several methods were found in the literature, concerning health issues, limited effectiveness, adverse side-effects on the treated artefacts and restricted applicability. [ABSTRACT FROM AUTHOR]

The wet strength of paper is an important physical property, especially for household paper, e.g., paper towels, as well as for some functional paper grades. However, in the literature, various conditions of immersing the samples in water before testing have been reported, resulting in differences in their extent of saturation and inconsistency in the testing results. Also, the dryness of paper specimens before the wet-strength testing is a critical parameter for the wet strength of paper; however, this aspect has been neglected in the literature. In this editorial, the methods of examination for both the temporary and permanent wet strength are discussed. A more reasonable method is proposed, such that the wet strength is reported according to the immersion time and the initial dryness of the paper. As an option, the results may be expressed as a function of immersion time and initial dryness. In this way, the trend of temporary wet strength related to the immersion time in water can be expressed clearly and the permanent wet strength also can be evaluated comprehensively. [ABSTRACT FROM AUTHOR]

A numerical model of a vacuum dewatering process was established with a level-set method to simulate two-phase flow in a two-dimensional paper sheet model with constructed volume forces representing flow resistance in a three-dimensional environment. Nine cases of various volume force representations were investigated by comparing numerical and experimental data. Based on the dry content and dwell time relation, the best model is obtained when accounting for in-plane flow resistance at the paper–wire interface. Compared to the other numerical cases, considering the blockage of the pore space, the top layer of the wire plays an essential role in determining the flow resistance during the vacuum process. To validate the maximum dewatering rate obtained in the model, new experimental data with a higher frequency of sampling are needed. The computational time for the two-phase flow models in this study is extensively reduced due to the removal of the internal structure. This distinction enables time-efficient simulations of the vacuum dewatering process in which several dewatering parameters such as the level of the vacuum, the influence of a moving vacuum pulse, and higher basis weights could be investigated. [ABSTRACT FROM PUBLISHER]

Die interne Strukturbeschaffenheit von Papier spielt in den meisten Anwendungen eine wichtige Rolle. Um die Struktureigenschaften von Papier zu untersuchen messen wir die totale Reflexion sowie die totale Transmission im MIR mit Hilfe einer Ulbrichtkugel. Die modellbasierte Auswertung der Messdaten liefert die optischen Strukturparameter μ s und μ a. Diese zeigen deutliche Unterschiede zwischen den Proben, was durch die Quecksilberporosimetriemessdaten bestätigt wird. Die Kombination der beiden Messtechniken ermöglicht die Einsicht in die Strukturveränderungen von Papier während der Trocknung. The properties of the internal paper structure are important for most applications. In order to investigate the structural properties of paper we measure the total transmission and total reflection in the mid infrared by an integrating sphere. The modell based data processing delivers the microscopic optical parameters μ s and μ a. These clearly reveal the differences between the examined paper samples, which are further explained by the porosimetry measurement data. The combined approach involving both measurement methods enables insights into structural behaviour of a paper sample during drying. [ABSTRACT FROM AUTHOR]

Abstract: This study investigated the utilization of resin impregnated decorative and overlay paper wastes obtained from the edge trimming of partially cured, dried papers as a binder in the manufacture of the light medium density fiberboard (MDF). The light MDF panels were prepared from various mixtures of the softwood fiber and hammer-milled impregnated paper waste, 95/5, 90/10, and 80/20wt%. The results of the experiments showed that the dimensional stability and mechanical properties of the light MDF panels were improved by adding hammer-milled melamine impregnated paper waste. The resin impregnated paper waste could be evaluated as a binder for the manufacturing of the light MDF panels having better dimensional stability and mechanical properties than standard light MDF panels used in interior applications. [Copyright &y& Elsevier]

We present theory for the shrinkage on drying of the cross-sectional area of cellulosic fibres and show that this depends on their initial moisture content only. For the linear shrinkage of cross-sectional dimensions, an additional parameter is required, which we estimate from comparison of the theory with experimental data from the literature. We proceed to combine our model of fibre shrinkage with probabilistic theory for fibre contacts in random fibrous networks to obtain a model for the unrestrained shrinkage of isotropic paper sheets. The expression obtained depends only on the moisture content of fibres and the extent of inter-fibre contact and exhibits good agreement with experimental data for laboratory-formed paper sheets. The results have relevance to the commercial manufacture of paper and potential for application to the study of cellulose nano-composites. [ABSTRACT FROM AUTHOR]

Abstract: In this study, the determinability of time related colour changes in prints made using ink that dries on matte coated paper with the offset printing technique and infrared method, has been investigated with artifical neural networks after analysis of the experimental and numerical methods. In the experimental part a ECI 2002 CMYK test scale is printed on a 135g/m2 matte coated. The prints obtained were measured with a spectrophotometer at certain intervals and by converting the reflection data obtained into the CIELAB colour description spectrum, time related changes in printed colours have been determined. In the empirical study however, colour changes in prints made on matte coated paper using inks that dry with the infrared method are modelled numerically. The average deviation has been found to be 0.4%. As a result, artificial neural networks can be used with the aim to digitally calculate time related colour changes in the offset printing system. [Copyright &y& Elsevier]

Abstract: A set of inks was analyzed using Py/GC/MS technique. They were prepared following some ancient Armenian recipes and then analyzed after being dried in air to obtain solid samples. A simple analytical procedure was adopted which excludes any treatment of the samples and consists in introducing the solid sample directly into the injector of the furnace pyrolyzer. Inks were also written on whatman paper by calamum and analyses of papers containing ink were carried out. A real sample analysis was reported. Comparing the pyrograms it was possible to discriminate fragments derived from ink, from that formed by the decomposition of paper by the influence of ink. In order to understand the origin of the fragments formed during the pyrolysis of inks the standard compounds used to prepare them were carried out, too. [Copyright &y& Elsevier]

The article presents a study which determines the effect of high temperature on the drying rates of recycled paper and the sheet properties. It assesses the functionality and efficiency of a gas-fired paper dryer (GFPD) in both pilot- and full-scale set-ups. It cites that the best location for installing a high-temperature dryer is near the middle of the dryer chain. It notes that the findings aim to boost paper machine drying and production rates and improve overall mill power efficiency.

The extension of the Darcy law (the Forchheimer flow equation) relating second-order nonlinear pressure drop with flow velocity is studied during fast transient through air drying of sheets of porous biobased materials such as paper. A range of the paper materials with open structure consistent with tissue and towel products (basis weights 25 and 50 g/m2) made using different production processes are analyzed for the factor-specific influences with regard to changes in the fluid resistance from the removal of moisture from the material interstices. A characteristic dimension suitable for the drying process is applied from viscous and inertial momentum transport analysis. [ABSTRACT FROM AUTHOR]

The aim of this article is to develop an experiment and a procedure to investigate the restoration of water-damaged paper and archival materials using freeze drying in order to allow a reproducible test and comparison of the influence of different operating conditions on drying time and restored paper quality. Firstly, a reproducible method for the preparation of soaked samples simulating water-damaged paper has been developed. Then, the samples have been freeze-dried in a laboratory-scale apparatus that allowed monitoring the temperature as well as the weight of the samples. The technique of evaporative freezing, which reduces the drying time required, has been used in this case. An innovative procedure for the visualization of the progress of the drying process has been validated, thus allowing the validation of a simple phenomenological model of the time evolution of the ice core volume; in addition, data on the residual moisture of the dried paper sheets in different zones have been given. Finally, optimization of this particular drying process by using simple or more sophisticated approaches has been discussed. [ABSTRACT FROM AUTHOR]

The article presents a study which demonstrates the drying behavior of water saturated cellulose fibers to better understand the fiber-water interaction during the drying process in papermaking. The authors examine the relationship between the hard-to-remove (HR) water content and the water retention value (WRV) by using thermogravimetric analysis (TGA) and differential scanning calorimeter (DSC). They found that free bound water evaporated first, followed by trapped water, freezing-bound water and then nonfreezing-bound water. Based on the results, they suggest that a qualitative drying model of wood-based cellulose fibers must be used relative to its decreasing moisture ratio.

A novel process modeling tool to facilitate the study of how various process changes in the paper dryer section affect the mill-wide energy system has been developed. A model library with steady-state block models describing paper dryers, heat recovery equipment, and auxiliary systems on component level have been developed using the software Extend. Process models are then created from these block models using graphical programming. In this article, the characteristics of the developed tool are described and a case study where the tool is shown to be useful for analyzing the energy performance of a hybrid dryer section is presented. [ABSTRACT FROM AUTHOR]

The article discusses the study on the effect of precipitated calcium carbonate (PCC) paper filler on water removal from pine, eucalyptus and birch kraft pulps in the vacuum filtration process. The study was done through the measurement of average specific filtration resistances (SFR). The PCC particles can improve dewatering efficiency by attaching to the fibers by electrostatic attraction and reducing total surface area. It has been found out that the deposition reduces the total surface area of the stock and increases the dewatering efficiency, thereby reducing the SFR the suspension. In addition, when the anionic charge of the fibers increases, the deposition of PCC particles increases and filtration resistance decreases.

Paper lamination is a widely used method to consolidate fragile documents. Previous studies have presented a new method of lamination that allows the consolidation of documents before undertaking aqueous treatments. In this method a thin Japanese paper coated with an acrylic resin is applied on the fragile document by means of a heated press. In this work we optimised the preparation of the lamination sheets as well as the working procedures, and we were able to establish that our laboratory-made specimens are chemically stable, easily reversible and permeable to aqueous solutions. The latest property is of particular importance, since it allows a subsequent aqueous deacidification even for fragile documents. The laminated paper documents were further analysed by means of colorimetry and FTIR spectroscopy before and after accelerated ageing as well as by determination of the alkali reserve left on the coated paper, in order to compare our lamination method with other commercially available lamination sheets. [ABSTRACT FROM AUTHOR]

Fabriano paper was aged by irradiation with ultraviolet light (λ=310) in a veterometer for 300 hours. At fixed time intervals, samples of the paper under test were analysed by titanium dioxide photosensor to determine electrochemically the ‘environmental persistence’ index, by a suitable conductimeter method, to determine the specific conductivity variation and by thermogravimetry to determine the moisture content, the onset temperature of the cellulose degradation process and the value of the activation energy of the same process. The behaviour of these different types of indicators displayed approximately monotonous trends as a function of time. [ABSTRACT FROM AUTHOR]

Abstract: Paper drying is an exergy costly operation, so also a few percent saving may be of importance. The entropy production for the paper drying process was therefore optimised for a conventional multi-cylinder drying machine, the PM2 newsprint machine at Norske Skog ASA in Skogn, Norway. The machine has 51 cylinders grouped in three drying groups; the cylinders are either heated from the inside by steam, unheated or operated under vacuum conditions. The same inlet drying air is supplied in all upper air-pockets of the machine. Our drying model for the paper temperature profile was first compared with measured data from the machine. The total entropy production of the drying process was next calculated, and then minimised subject to a fixed outlet paper moisture content. Inlet humidity and cylinder group conditions were varied. Optimum conditions were obtained for a range of inlet air humidities, and for different cylinder groupings. We found that it was very favourable to increase the inlet air humidity. Other changes had a negligible effect on the total entropy production. The results further pointed to the need for a revision of the current paper drying model, as the second-law of thermodynamics was violated at high air humidities with this model. [Copyright &y& Elsevier]

The properties of recycled paper are strongly affected by shrinking during drying, which depends on the drying conditions. An experimental study of the shrinkage phenomenon during drying of paper is presented. Drying experiments were conducted in a drying oven with controlled temperature. The temperature influence on shrinkage extent, porosity, and apparent density of the paper was evaluated. Structural changes on the paper surface after drying were analyzed by scanning electronic microscopy. Thickness contraction, surface, and volumetric shrinkage were correlated as a function of the moisture content. Lower apparent density values and more porous paper samples were obtained for higher temperatures. [ABSTRACT FROM AUTHOR]

Studies from this laboratory have documented significant changes in properties when paper is dried in superheated steam rather than, as in all current processes, in air. Extending these investigations to additional important pulp types, to recycled pulps and to filled papers, using commercial furnishes from mills, has identified further grades of paper for which drying in superheated steam enhances key properties. For bleached chemithermomechanical pulps and blends with kraft pulp as used for tissue and toweling, strong paper resulted, with 10% higher bulk. Linerboard from 100% recycled old corrugated containers (OCC) is obtained with various strength properties increased by up to 21% with no densification, actually a 4% increase in bulk. Linerboard from high-yield (55–67%) virgin kraft pulps show 23 to 37% increase in strength and toughness. Filled papers containing 0–10% clay can be produced with the same brightness but about 23% higher tensile index when dried in superheated steam. [ABSTRACT FROM AUTHOR]

A general model for through drying of tissue was developed based on the equations of continuity in combination with correlations for heat and mass transfer. The model incorporates different geometric descriptions together with corresponding heat and mass transfer correlations for flow through cylindrical conduits and flow through packed beds of cylindrical fibers. At low intensities, i.e., at low airflow rates and low drying air temperatures, the model shows very good agreement with experimental data found in the literature and accurately predicts a period of constant drying rate due to saturation of the drying air. However, at higher drying intensities, the model predicts drying rates that are generally higher than what is found in experimental studies described in the literature. The model also predicts a period of constant drying rate that has not been observed in experiments at higher drying intensities. To illustrate the effect of nonuniform pore size distribution on the average drying rate, a model including a variable pore size distribution was developed. The results show that the early onset of the falling rate period in through drying at higher intensities could be explained by channelling effects caused by a nonuniform pore size distribution. [ABSTRACT FROM AUTHOR]

Studies from this laboratory have documented significant changes in properties when paper is dried in superheated steam rather than, as in all current processes, in air. Extending these investigations to additional important pulp types, recycled pulps, and filled papers, and using commercial furnishes from mills, has identified further grades of paper for which drying in superheated steam enhances key properties. For bleached chemithermomechanical pulps and blends with kraft pulp, as used for tissue and toweling, strong paper resulted with 10% higher bulk. Linerboard from 100% recycled old corrugated containers (OCC) is obtained with various strength properties increased by up to 21% with no densification, actually a 4% increase in bulk. Linerboard from high-yield (55–67%) virgin kraft pulps shows a 23 to 37% increase in strength and toughness. Filled papers containing 0–10% clay can be produced with the same brightness but 23% higher tensile index when dried in superheated steam. [ABSTRACT FROM AUTHOR]

A general, dynamic model describing the drying mechanisms of paper has been developed. The model includes shrinkage and predicts temperature, moisture, and pressure profiles. It has been evaluated against steady-state as well as dynamic measurements on a multicylinder paper dryer. The results revealed critical sections where low web strength and maximum gas pressure occur. Measurements of the outer cylinder temperature provide reliable information on the accuracy of the predicted moisture profile since they show the position where the paper surface is dry. [ABSTRACT FROM AUTHOR]

The present study investigates two models—two limiting cases—for the internal heat and mass transfer in a multicylinder dryer: the first model assumes that complete redistribution of heat and moisture in the thickness direction occurs instantaneously. The second model assumes that moisture transfer occurs only by vapor diffusion and that heat transfer takes place by conduction and condensation. The two models are written in dimensionless form, and applied for the same set of standard paper machine data. For basis weights below approximately 0.05 kg d.s./m2 the results are so close that the first, simple model is sufficient. A higher limiting basis weight—approximately 0.16 kg d.s./m2—was previously indicated by comparison of model predictions, assuming the simple model, to extensive sets of machine data from four different paper machines. [Copyright &y& Elsevier]

A mathematical model describing the heat and mass transfer in the dryer section of a paper machine has been applied to the production data from four paper machines. Model predictions for the machine speed are compared to actual machine speeds for a total of 163 data sets. The mathematical model assumes that the temperature and moisture content remain homogeneous in the thickness direction of the sheet. For three paper machines producing paper with basis weights ranging from 0.056 to 0.159 kg d.s./m2 the model predictions are adequate. For the paper machine producing the heaviest grades with basis weights ranging from 0.189 to 0.390 kg d.s./m2 the model predictions are flawed by a systematic error. For low machine velocities/high basis weights the machine velocity is over-predicted and for high machine velocities/low basis weights the machine velocity is under-predicted. This systematic error is caused by the assumption of homogeneous moisture content and temperature within the sheet being severely in error for thick sheets. [Copyright &y& Elsevier]

A three dimensional computational fluid dynamic investigation is carried out to predict the turbulent flow and surface heat transfer under an impinging air jet issuing normally from a single noncircular orifice in a plate held parallel to the target surface. Static pressure distributions, velocity fields and local as well as average Nusselt number on the impinged surface are presented for square, elliptic, and rectangular orifices and compared with those for a circular orifice. Effects of jet Reynolds number as well as spacing between the nozzle plate and the impinged surface are examined using a two-layerκ–η turbulence model. Results show flow structure similarities between the characteristics of rectangular and elliptic jets of equal aspect ratio. Further, it is observed that noncircular impinging jets can provide higher average heat transfer rates than corresponding circular jets for certain geometric parameters viz. nozzle-to-plate spacing and the size of the averaging area used to compute the average Nusselt number. [ABSTRACT FROM AUTHOR]

This article theoretically investigates the drying of uncoated paper with gas-fired infrared (IR) emitters installed within the drying section of a given commercial paper machine. Specifically, it presents the ideal location of two opposing IR emitters within the drying section. The ideal location of the two opposing IR emitters corresponds to the highest machine speed with specified average moisture content of paper sheet at the end of the drying section. This article also presents the average evaporation rate, temperature, and moisture content of the paper sheet as it travels through the drying section with the two opposing IR emitters operating at the optimum location. In addition, the temperature and moisture profiles in the sheet thickness direction, before and after the IR emitters, are provided. This article is not concerned with the potential effects of drying with IR emitters on paper sheet properties and machine runnability issues. [ABSTRACT FROM AUTHOR]

Moisture equilibrium isotherms are very important in drying and storage processes analysis. So, the DEQ/UEM process separation group is building a data bank for cellulose, paper, and textile isotherms and their fit with available literature equations. In this context, the experimental isotherms of a brazilian specific commercial paper, the KLABIN-PR KLAPAK commercial liquid package paper were obtained. The experimental equilibrium data were obtained by exposing the material to different ambient conditions of temperature and relative humidity controlled by the use of saline solutions. The samples were placed in glass flasks left inside an oven to provide a better adjust of temperature conditions, being periodically weighed until constant weight. KLAPAK moisture equilibrium isotherms were built from the obtained experimental results and temperature effects on its behavior were analyzed. Then, these results were fitted with the help of some models and equations available from literature. [ABSTRACT FROM AUTHOR]

The aim of this study was to find out what will happen to paper coating quality and material gradients if coating is dried in one air dryer at a high convection rate (150 kg/m2h). Different printing papers were coated, calendered and printed with pilot machines. The binder and pigment gradients of the coated, and also printed, samples were analyzed with LIPS (Laser Induced Plasma Spectrometry). It was found that drying affects the migration of starch, but not latex. Total air drying can be used to dry printing papers, if air temperature, velocity and moisture content can be separately controlled. The control of web temperature is more important for paper quality formation in a coater drying section than that of evaporation rate. [ABSTRACT FROM AUTHOR]

Based on the earlier studies the most common empirical correlations in the literature predict the impingement heat transfer coefficients rather well at low (close to 100°C) temperatures, but get inaccurate at higher temperatures. Impingement temperatures used in paper drying applications are typically 300 to 700°C, and there has been a need to improve the existing heat transfer correlations at high temperature area. This study presents experimental results of impingement heat transfer measurements with a laboratory-scale heat transfer test rig. Five nozzle configurations were measured. The parameters varied in the investigation were nozzle-to-plate distance, nozzle open area, nozzle diameter, impingement velocity and impingement air temperature. Regression model of heat transfer was developed based on the measurement data. A correction factor including the impingement and heat receiving surface temperatures is proposed. The correction factor can be used to improve the existing correlations at large jet to heat receiving surface temperature differences. [ABSTRACT FROM AUTHOR]

This article examines dynamic behavior of impingement drying. Dynamic relations between the drying variables and the paper moisture are determined and interactivity between the process variables is defined. According to the results, impingement drying is interactive and therefore an advanced control strategy is developed which is based on multivariable model predictive control. The performance of the proposed control strategy is studied by simulation and the simulation results are compared with the simulation results of the present control scheme. [ABSTRACT FROM AUTHOR]

Upon application of water based coating onto silicone-coated paper and during the subsequent drying process, the water permeates through the silicone layer into the paper substrate. At the same time, water evaporates from both the surface of the coated layer and throughout the paper layer. Initially, the evaporation rate from the wet coating surface may be dominant, but at longer times the bulk evaporation from the paper can dominate. Here a three-layer diffusion model for such a system is developed. Solutions obtained by Galerkin's method with finite element basis functions show that the hygroscopic nature of the paper leads to low drying rates at low moisture contents. Further, the model predicts that initially the coating dries to a moderately low residual moisture concentration faster than a coating applied on an impermeable substrate. However, at longer times, the predicted residual moisture of coatings applied on silicon-coated paper is higher than for a coating applied on an impermeable substrate. [ABSTRACT FROM AUTHOR]

Some current models for moisture diffusion in paper in the hygroscopic range are analyzed. In general, two types of diffusion models can be recognized. Models of the first type treat paper as a homogeneous medium with moisture flux that is proportional to the gradient in moisture content. Although useful in some instances this approach fails frequently because it homogenizes the internal dynamics and relaxation processes occurring within the paper material. Recent studies have shown that a subtler approach which treats paper as a composite of fibers and void spaces is more successful at describing moisture transport dynamics. A review of these studies along with a generalization of this approach to three dimensions is considered here. The parameters appearing in such models can be identified with the physical processes of diffusion through the void space and through the fiber matrix. Diffusivities in these individual phases are supplemented by a local kinetic coefficient representing moisture flux interchange between the void and fiber phases. When the local moisture exchange coefficient takes on large values, the fibers and the void spaces are at local equilibrium with no net exchange of moisture. Under such conditions, the model reduces to the simpler Fickian diffusion model with nonlinear moisture diffusivity equivalent to earlier models. [ABSTRACT FROM AUTHOR]

During through air drying the internal sheet drying history develops as a succession of local moisture content profiles in the sheet thickness dimension. These profiles were determined by interrupting the through drying of 180 g/m2 6-ply sheets, then quickly delaminating and determining the moisture content of each 30 g/m2 ply. On the through flow inlet side of the sheet, large moisture differences, about 0.4–0.6 kg/kg dry per 30 g/m2 ply, develop and move into the interior of the sheet provided that local moisture content is in the range 0.45–1.75 kg/kg. On the through flow exit side, moisture gradients only become significant for moisture content below about 1.25 kg/kg. From the through flow exit side of the sheet much of the water is removed by diffusion to the flow entry side where most evaporation into the through flow occurs. The kinetics of through drying reflect the interaction between these two mechanisms, local evaporation into the through flow and thickness direction diffusion. The moisture diffusivity–moisture content relation controls this balance. In any combination with cylinder drying to give some kind of hybrid dryer, through drying should be at the dry end where air permeability is highest and cylinder drying rate is lowest. [ABSTRACT FROM AUTHOR]

Local nonuniformity of moisture content during drying is doubly disadvantageous. Moisture nonuniformity reduces drying effectiveness, increasing drying cost or reducing drying capacity, and may decrease product quality for printing through effects such as cockling and curl. These problems can occur with the now dominant process of cylinder drying, but become much more acute with the various higher intensity drying techniques which are competing to become elements of the higher speed hybrid dryer sections of the future. For quantitative characterization of moisture nonuniformity a novel method applicable to paper being dried by various processes was developed, then demonstrated for one high intensity air convection process, through air drying. During drying, the local moisture content was determined for many 2.5 mm diameter sensing areas by very rapid scanning with a custom design 3-wavelength infrared paper moisture instrument. For local moisture nonuniformity thus determined, the coefficient of variation provides a standard basis for comparison between paper types and drying conditions. For kraft paper from 20 to 120 g/m2, the effects on local moisture nonuniformity were evaluated for drying intensity and for several paper parameters—formation, grammage, and initial moisture content. The drying nonuniformity index was found to parallel both formation quality and drying intensity. An unexpected finding was that over the 20–120 g/m2 range, local moisture nonuniformity passes through a maximum at 30 g/m2. Sheet initial moisture content produces the largest effect, with moisture nonuniformity index being both high and very sensitive to this parameter for initial moisture content above the fibre saturation point. Another finding from these unique measurements is that, for the same 2.5 mm diameter sensing areas, there is a clear correlation between moisture nonuniformity index and local grammage. [ABSTRACT FROM AUTHOR]

The reaction kinetics of drying, pyrolysis and combustion of paper sludge have been determined in a thermogravimetric analyzer (TGA). The effects of heating rate (5–30 K min−1) and sample weight (10–50 mg) on drying and pyrolysis of paper sludge have been determined. The kinetic parameters of char combustion are determined at the isothermal conditions (723–1173 K). For dehydration, pyrolysis and combustion of paper sludge, temperature can be divided into drying (−470 K), pyrolysis [low (470–660 K), medium (660–855 K)] and combustion (>855 K) ranges. From the kinetic parameters (frequency factor and activation energy) of water decomposition, two major degradable compounds are found and the experimental thermogravimetric curves predicted by those parameters. For char combustion, the reaction order is found to be unity. The char combustion is well expressed by the shrinking core model with chemical reaction controlling and the activation energy is changed from 24.3 to 10.14 kJ mol−1 K−1 at 873 K. [Copyright &y& Elsevier]

This investigation evaluates the changes in dryness and physical properties of impulse processed paper webs. A laboratory-scale platen press was used to process 60 g/m[SUP2] webs under a wide range of pressure impulses and temperatures (23-380°C). The heat transfer rate to the web was also varied by using two different platen materials (steel and copper). Both thermomechanical and bleached kraft pulps were tested, and the dryness, density, surface roughness, and Scott bond were measured for each trial. Results show that dewatering is enhanced with increased temperature, pressure, and nip residence time, while pressure pulse shape and platen material have little influence. An empirical correlation is given to relate sheet dryness to the key process variables. This correlation suggests that resulting dryness values are not unique; that is, different combinations of temperature, pressure, and nip residence time can be used to obtain a similar level of dryness. Physical reasoning was used to develop a second correlation that links the resulting dryness to the density of the completely dried web. Surface roughness decreased with increasing surface temperature, while Scott bond rose sharply under conditions of high temperature and long nip residence time. [ABSTRACT FROM AUTHOR]