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The global outbreak of the novel coronavirus has had a great impact on commercial areas, particularly in Wuhan, the first city in China affected by the epidemic. Exploring the changing pattern of these areas during the epidemic period is crucial for effectively restoring the urban economic level and promoting economic development on the basis of epidemic prevention and control in the post-epidemic era. The paper proposes a resilience analysis of urban commercial areas during the COVID-19 epidemic using time-series night-time light remote sensing data. Based on the constructed time-series night-time light remote sensing dataset and considering the urban impervious surface, the urban commercial area was extracted under multi-scale segmentation. Based on night-time light data before and after the epidemic, the resilience of representative commercial areas in Wuhan City, Hubei Province during the COVID-19 epidemic was analysed using a modified improved resilience assessment framework. The results showed that the lighting values of commercial areas and impervious areas decreased by up to 30% following the implementation of city lockdown measures. The change of light brightness in the commercial areas was more prominent, and the range of change is larger than that in the non-commercial areas. The lighting brightness of the commercial areas exhibited a significant downward trend throughout the entire lockdown period, and the downward trend will still remain for a period of time after unlocking. Among all the commercial areas, Wuguang commercial area demonstrated the highest recovery rate during the lockdown period and instantaneous recovery rate after the lockdown, with relatively low closure loss and the highest level of resilience.

The transmission and prevalence of Hand, Foot and Mouth Disease (HFMD) are affected by a variety of natural and socio-economic environmental factors. This study aims to quantitatively investigate the non-stationary and spatially varying associations between various environmental factors and HFMD risk. We collected HFMD surveillance cases and a series of relevant environmental data from 2013 to 2021 in Xi'an, Northwest China. By controlling the spatial and temporal mixture effects of HFMD, we constructed a Bayesian spatiotemporal mapping model and characterized the impacts of different driving factors into global linear, non-stationary and spatially varying effects. The results showed that the impact of meteorological conditions on HFMD risk varies in both type and magnitude above certain thresholds (temperature: 30 °C, precipitation: 70 mm, solar radiation: 13000 kJ/m2, pressure: 945 hPa, humidity: 69%). Air pollutants (PM2.5, PM10, NO2) showed an inverted U-shaped relationship with the risk of HFMD, while other air pollutants (O3, SO2) showed nonlinear fluctuations. Moreover, the driving effect of increasing temperature on HFMD was significant in the 3-year period, while the inhibitory effect of increasing precipitation appeared evident in the 5-year period. In addition, the proportion of urban/suburban/rural area had a strong influence on HFMD, indicating that the incidence of HFMD firstly increased and then decreased during the rapid urbanization process. The influence of population density on HFMD was not only limited by spatial location, but also varied between high and low intervals. Higher road density inhibited the risk of HFMD, but higher night light index promoted the occurrence of HFMD. Our findings further demonstrated that both ecological and socioeconomic environmental factors can pose multiple driving effects on increasing the spatiotemporal risk of HFMD, which is of great significance for effectively responding to the changes in HFMD epidemic outbreaks.

Semantic segmentation of airborne point clouds is crucial for 3D scene reconstruction and remote sensing in surveying applications. Current deep learning methods for point clouds primarily focus on effectively aggregating local neighborhood information. However, they often overlook the fusion of global context information and elevation features, which are vital for airborne point clouds. In this study, we propose Dense-LGEANet, a novel network with dense connected architecture and multiscale feature supervision based on our designed LGEA module. The key component of our LGEA module is the combination of the graph convolution block and the transformer block with elevation attention. It can effectively fuse local neighborhood information and global context information to improve the accuracy of semantic segmentation of airborne point cloud. Moreover, the designed dense connected network architecture can enhance the feature extraction capability for point cloud objects at different scales by facilitating interactions between multiple up-sampling and down-sampling layers. We have conducted multiple experiments on the public point cloud dataset. Experimental results show that our method can achieve an mIoU of 58.5% and an mF1 of 72.0% on the ISPRS Vaihingen 3D dataset, while an mIoU of 67.2% and an mF1 of 78.3% on the LASDU dataset. It demonstrates the superior performance of our network and the effectiveness of the proposed feature enhancement module and network architecture.

RGB-D image mapping is an important tool in applications such as robotics, 3D reconstruction, autonomous navigation, and augmented reality (AR). Efficient and reliable mapping methods can improve the accuracy, real-time performance, and flexibility of sensors in various fields. However, the currently widely used Truncated Signed Distance Field (TSDF) still suffers from the problem of inefficient memory management, making it difficult to directly use it for large-scale 3D reconstruction. In order to address this problem, this paper proposes a highly efficient and accurate TSDF voxel fusion method, RGBTSDF. First, based on the sparse characteristics of the volume, an improved grid octree is used to manage the whole scene, and a hard coding method is proposed for indexing. Second, during the depth map fusion process, the depth map is interpolated to achieve a more accurate voxel fusion effect. Finally, a mesh extraction method with texture constraints is proposed to overcome the effects of noise and holes and improve the smoothness and refinement of the extracted surface. We comprehensively evaluate RGBTSDF and similar methods through experiments on public datasets and the datasets collected by commercial scanning devices. Experimental results show that RGBTSDF requires less memory and can achieve real-time performance experience using only the CPU. It also improves fusion accuracy and achieves finer grid details.

The semantic segmentation task is an essential issue in various fields, including land cover classification and cultural heritage investigation. The CNN and Transformer have been widely utilized in semantic segmentation tasks due to notable advancements in deep learning technologies. However, these methodologies may not fully account for remote sensing images' distinctive attributes, including the large intra-class variation and the small inter-class variation. Driven by it, we propose a category attention guided network (CAGNet). Initially, a local feature extraction module is devised to cater to striped objects and features at different scales. Then, we propose a novel concept of category attention for remote sensing images as a feature representation of category differences between pixels. Meanwhile, we designed the Transformer-based and CNN-based category attention guided modules to integrate the proposed category attention into the global scoring functions and local category feature weights, respectively. The network is designed to give more attention to the category features by updating these weights during the training process. Finally, a feature fusion module is developed to integrate global, local, and category multi-scale features and contextual information. A series of extensive experiments along with ablation studies on the UAVid, Vaihingen, and Potsdam datasets indicate that our network outperforms existing methods, including those based on CNN and Transformer.

Three-Dimensional Ground Penetrating Radar (3D GPR) detects subsurface targets non-destructively, rapidly, and continuously. The complex environment around urban roads affects the positioning accuracy of 3D GPR. The positioning accuracy directly affects the data quality, as inaccurate positioning can lead to distortion and misalignment of 3D GPR data. This paper proposed a multi-level robust positioning method to improve the positioning accuracy of 3D GPR in dense urban areas in order to obtain more accurate underground data. In environments with good GNSS signals, fast and high-precision positioning can be achieved based on GNSS data using differential GNSS technology; in scenes with weak GNSS signals, high-precision positioning of subsurface data can be achieved by using GNSS and IMU as well as using GNSS/INS tightly coupled solution technology; in scenes with no GNSS signals, SLAM technology is used for positioning based on INS data and 3D point cloud data. In summary, this method ensures a positioning accuracy of 3D GPR better than 10 cm and high-quality 3D images of underground urban roads in any environment. This provides data support for urban road underground structure surveys and has broad application prospects in underground disease detection and prevention.

Radiometric correction is one of the most important preprocessing parts of unmanned aerial vehicle (UAV) multispectral remote sensing data analysis and application. In this article, a back propagation (BP) neural network-based radiometric correction method (BPNNRCM) considering optimal parameters was proposed. First, we used different UAV multispectral sensors (K6 equipped on the DJI M600, D-MSPC2000 equipped on the FEIMA D2000) to collect training, validation, testing and cross-validation data. Second, the radiometric correction results of BP neural network with different input variables and hidden layer node number were compared to select the best combination of input parameters and hidden layer node number. Finally, the radiometric correction accuracy and robustness of BP neural network considering the optimal parameters were verified. When the number of nodes in the input layer was five (digital number, UAV sensor height, wavelength, solar altitude angle, and temperature) and the number of nodes in the hidden layer was eight, the BP neural network had the best comprehensive performance in training time of train set and accuracy of validation/test set. In the aspect of accuracy and robustness, the absolute errors of test and cross-validation images' surface reflectance obtained by the BPNNRCM were all less than 0.054. The BPNNRCM had smaller average absolute error (0.0141), mean squared error (0.0003), mean absolute error (0.0141) and mean relative error (7.1%) comparing with empirical line method and radiative transfer model. In general, the research results of this article prove the feasibility and prospect of BPNNRCM for radiometric correction of UAV multispectral images.

The Qinghai–Tibet Railway is located in the most fragile and sensitive terrestrial ecosystem of the Qinghai–Tibet Plateau in China, and once the ecological environment is damaged, it is difficult to restore. This study, based on the Google Earth Engine platform, focuses on the section of the Qinghai–Tibet Railway from Xining to Jianghe. It utilizes Landsat series satellite imagery data from 1986 to 2020 to calculate the Remote Sensing Ecological Index (RSEI). This approach enables large-scale and long-term dynamic monitoring, analysis, and assessment of the ecological changes along the Qinghai–Tibet Railway corridor. The results indicate that (1) the average RSEI of the study area increased from 0.37 in 1986 to 0.53 in 2020, showing an overall trend of improvement. The ecological environment quality is mainly categorized as medium and good. (2) The quality of the ecological environment in the areas along the railway experienced fluctuations during different periods of railway construction and operation. From 1986 to 1994, after the first phase of the railway opened, the overall ecological environment showed a relative decline in quality. From 1994 to 2002, the ecological quality of 60% of the region saw slight improvements. During the extension construction of the second phase of the railway from 2002 to 2007, the regional ecology fluctuated again. However, from 2013 to 2020, during the operational period, a stable recovery trend was observed in the ecological environment. (3) The ecological environment in the study area is influenced by multiple factors. Different railway station areas exhibit strong spatial heterogeneity. The impact of single factors is significant, with the existence of spatial stratification and enhanced interactions among multiple factors. The strongest interactive effects are observed between land use types, the intensity of human activities, and temperature.

Image matching is a key prerequisite for image fusion. Currently, deep learning methods had shown great potential in matching. However, these methods mainly focus on optical images or area-based matching and their performance highly relies on the diversity of the training sets. This paper makes two major contributions to the synthetic aperture radar (SAR)-optical image feature matching task. First, we create a high-quality open SAR and optical patch dataset called SOPatch, which contains more than 650000 matching patch pairs. SOPatch is generated from a variety of satellite images (Sentinel-1, Sentinel-2, Gaofen-3, etc.) and contains a rich set of features (mountains, lakes, buildings, farmland, bare land, etc.), which can provide robustness to sensor and localization changes and train a model with good generalization ability. Similar to the HPatches (Balntas et al., 2017), we also add position and rotation noise to make the dataset more realistic and robust. Second, a local descriptor for SAR-optical matching called SODescNet is proposed. We first weaken the speckle noise of SAR by multiscale dilated convolution and channel attention mechanisms and then use DenseNet-CSP (cross stage partial) as the backbone for feature description. To reduce the difficulty of network training, we first use a Siamese network for pre-training and then fine-tune it via a pseudo-Siamese network. Extensive experiments show that our SODescNet is comparable or superior to state-of-the-arts.

Abstract Accurate understanding of the impacts of climate change on hulless barley and river in the Lhasa River Basin is of great significance to food security and water resources management in the plateau region. It is important to explore the relationship between hulless barley and river under the background of climate change for the comprehensive and coordinated development of agriculture and water conservancy. Based on the Google Earth Engine (GEE) cloud computing platform, the Random Forest algorithm was used to obtain the spatio‐temporal variation of hulless barley and river in the Lhasa River Basin from 2010 to 2020. The overall accuracy and Kappa coefficient of classification results were 89.54% and 85.96%, respectively. The average area and Normalized Difference Vegetation Index (NDVI) of hulless barley from 2010 to 2020 were 178.46 km2 and 0.69, respectively. The increase of accumulated precipitation, number of precipitation days, average dew point temperature (ADPT) and average wind speed (AWS) promoted the growth of hulless barley, with NDVI significant increasing rate of 0.0173 (R2 = 0.764, p

Unmanned aerial vehicles (UAVs) have been widely used in industry and daily life, where safety is the primary consideration, resulting in their use in open outdoor environments, which are wider than complex indoor environments. However, the demand is growing for deploying UAVs indoors for specific tasks such as inspection, supervision, transportation, and management. To broaden indoor applications while ensuring safety, the quadrotor is notable for its motion flexibility, particularly in the vertical direction. In this study, we developed an improved probabilistic roadmap (PRM) planning method for safe indoor flights based on the assumption of a quadrotor model UAV. First, to represent and model a 3D environment, we generated a reduced-dimensional map using a point cloud projection method. Second, to deploy UAV indoor missions and ensure safety, we improved the PRM planning method and obtained a collision-free flight path for the UAV. Lastly, to optimize the overall mission, we performed postprocessing optimization on the path, avoiding redundant flights. We conducted experiments to validate the effectiveness and efficiency of the proposed method on both desktop and onboard PC, in terms of path-finding success rate, planning time, and path length. The results showed that our method ensures safe indoor UAV flights while significantly improving computational efficiency.

Cultural traces under forests are one of the main problems affecting the identification of archaeological sites in densely forested areas, so it is full of challenges to discover ancient tombs buried under dense vegetation. The covered ancient tombs can be identified by studying the time-series features of the vegetation covering the ancient tombs on the multi-time series remote sensing images because the ancient tombs buried deep underground have long-term underground space structures, which affect the intrinsic properties of the surface soil so that the growth status of the covering vegetation is different from that of the vegetation in the area without ancient tombs. We first use the highly detailed DSM data to select the ancient tombs that cannot be visually distinguished on the optical images. Then, we explored and constructed the temporal features of the ancient tombs under the forest and the non-ancient tombs in the images, such as the radar timing-series features of Sentinel 1 and the multi-spectral and vegetation index timing-series features of Sentinel 2. Finally, based on these features and machine learning, we designed an automatic identification algorithm for ancient tombs under the forest. The method has been validated in Baling Mountain in Jingzhou, China. It is very feasible to automatically identify ancient tombs covered by surface vegetation by using the timing-series features of remote sensing images. Additionally, the identification of large ancient tombs or concentrated ancient tombs is more accurate, and the accuracy is improved after adding radar features. The paper concludes with a discussion of the current limitations and future directions of the method.

Grassland is the vegetation type with the widest coverage on the Qinghai-Tibet Plateau. Under the influence of multiple factors, such as global climate change and human activities, grassland is undergoing temporal and spatially different disturbances and changes, and they have a significant impact on the grassland ecosystem of the Qinghai-Tibet Plateau. Therefore, timely and dynamic monitoring of grassland disturbances and distinguishing the reasons for the changes are essential for ecological understanding and management. The purpose of this research is to propose a knowledge-based strategy to realize grassland dynamic distribution mapping and analysis of grassland disturbance changes in the region that are suitable for the Qinghai-Tibet Plateau. The purpose of this study is to propose an analysis algorithm that uses first annual mapping and then establishes temporal disturbance rules, which is applicable to the integrated exploration of disturbance changes in highland-type grasslands. The characteristic indexes of greenness and disturbance indices in the growing period were constructed and integrated with deep neural network learning to dynamically map the grassland for many years. The overall accuracy of grassland mapping was 94.11% and that of Kappa was 0.845. The results show that the area of grassland increased by 11.18% from 2001 to 2017. Then, the grassland disturbance change analysis method is proposed in monitoring the grassland distribution range, and it is found that the area of grassland with significant disturbance change accounts for 10.86% of the total area of the Qinghai-Tibet Plateau, and the disturbance changes are specifically divided into seven types. Among them, the type of degradation after disturbance mainly occurs in Tibet, whereas the main types of vegetation greenness increase in Qinghai and Gansu. At the same time, the study finds that climate change, altitude, and human grazing activities are the main factors affecting grassland disturbance changes in the Qinghai-Tibet Plateau, and there are spatial differences.

Hemorrhagic fever with renal syndrome (HFRS) is a zoonosis characterized by clinical features of high fever, hemorrhage, and renal damage. China has the largest number of HFRS cases worldwide, accounting for over 90% of the total reported cases. In this paper, we used surveyed HFRS data and satellite imagery to conduct geostatistical analysis for investigating the associations of rapid urbanization, water bodies, and other factors on the spatiotemporal dynamics of HFRS from year 2005 to 2018 in Xi'an City, Northwest China. The results revealed an evident epidemic aggregation in the incidence of HFRS within Xi'an City with a phenomenal fluctuation in periodic time series. Rapid urbanization was found to greatly affect the HFRS incidence in two different time phases. HFRS caused by urbanization influences farmers to a lesser extent than it does to non-farmers. The association of water bodies with the HFRS incidence rate was found to be higher within the radii of 696.15 m and 1575.39 m, which represented significant thresholds. The results also showed that geomatics approaches can be used for spatiotemporally investigating the HFRS dynamic characteristics and supporting effective allocations of resources to formulate strategies for preventing epidemics.

Brucellosis is a chronic infectious disease caused by brucellae or other bacteria directly invading human body. Brucellosis presents the aggregation characteristics and periodic law of infectious diseases in temporal and spatial distribution. Taking major European countries as an example, this study established the temporal and spatial distribution sequence of brucellosis, analyzed the temporal and spatial distribution characteristics of brucellosis, and quantitatively predicted its epidemic law by using different traditional or machine learning models. This paper indicates that the epidemic of brucellosis in major European countries has statistical periodic characteristics, and in the same cycle, brucellosis has the characteristics of piecewise trend. Through the comparison of the prediction results of the three models, it is found that the prediction effect of long short-term memory and convolutional long short-term memory models is better than autoregressive integrated moving average model. The first mock exam using Conv layer and data vectorizations predicted that the convolutional long short-term memory model outperformed the traditional long short-term memory model. Compared with the monthly scale, the prediction of the trend stage of brucellosis can achieve better results under the single model prediction. These findings will help understand the development trend and liquidity characteristics of brucellosis, provide corresponding scientific basis and decision support for potential risk assessment and brucellosis epidemic prevention and control, and reduce the loss of life and property.

How to combine science and technology with the humanities in the research on ancient cities to reveal ancient peoples’ urban planning thoughts is worthy of in-depth study. The capitals of the Western Han dynasty as well as the Sui and Tang dynasties were some of the greatest cities in the world at the time. This paper takes them as its subjects and puts forward a method to study the spatial relationship between ancient cities and the natural environment by combining spatial information technology and cultural analysis. Firstly, satellite images, elevation maps, urban ichnographies, and literature materials were collected and sorted to deeply understand the cultural thoughts involved in ancient urban planning; based on this, key element points were marked and rechecked on the spot, and the above drawings were accurately superimposed by GIS technology to form a geographic information base that integrated multisource information. Then, Python was used to construct a “decision model of spatial relationship between urban elements and natural elements”, and rules as well as parameters were set through man–machine collaboration. The decision model was used to test the geographic information base, and the information of strong correlations between urban objects and natural objects was outputted. The drawings were exported after screening, and a visual expression was realized with Illustrator software. The research results indicated that this analysis method was feasible, effective, and easy to promote. The new archaeological discoveries included eight important line segments with a 9:6 proportional relationship (which represents the balance of Yin and Yang) and two important line segments with a 9:5 proportional relationship (which represents the supreme imperial power) in the capitals of the Western Han dynasty as well as the Sui and Tang dynasties, and 16 contraposition lines in a positive direction or oblique 45° direction (which reflects the close relationship between urban elements and natural elements). We consider that the two capitals were intentionally closely related to natural environments such as mountain peaks and valley entrances in the planning stage, and that proportions and scales with profound humanistic meaning were selected. The capital of the Sui and Tang dynasties was specially aligned with the capital of the Western Han dynasty in space. These characteristics embody ancient Chinese Confucian cultural thoughts such as the “integration of yang and yin”, “harmony between nature and humans”, the “supremacy of emperors”, and the “use of numbers and shapes to convey meaning”.

The landslide susceptibility assessment based on machine learning can accurately predict the probability of landslides happening in the region. However, there are uncertainties in machine learning applications. In this paper, Artificial Neural Network (ANN), Random Forest (RF), Support Vector Machine (SVM), and Logistic Regression (LR) are used to assess the landslide susceptibility in order to discuss the model uncertainty. The model uncertainty is explained in three ways: landslide susceptibility zoning result, risk area (high and extremely high) statistics, and the area under Receiver Operating Characteristic Curve (ROC). The findings indicate that: (1) Landslides are restricted by influence factors and have the distribution law of relatively concentrated and strip-shaped distribution in space. (2) The percentage of real landslide in risk area is 86%, 87%, 82%, and 61% in SVM, RF, LR, and ANN, respectively. The area under ROC of RF, SVM, LR, and ANN, respectively, is 90.92%, 80.45%, 73.75%, and 71.95%. (3) Compared with the prediction accuracy of the training set and test set from the same earthquake, the accuracy of landslide prediction in the different earthquakes is reduced.

Transmission towers are easily affected by various meteorological and geological disasters. In this paper, a transmission tower tilt state assessment approach—based on high precision and dense point cloud from UAV LiDAR—was proposed. First, the transmission tower point cloud was rapidly located and extracted from the 3D point cloud obtained by UAV-LiDAR line patrol. A robust histogram local extremum extraction method with additional constraints was proposed to achieve adaptive segmentation of the tower head and tower body point cloud. Second, an accurate and efficient extraction and simplification strategy of the contour of the feature plane point cloud was proposed. The central axis of the tower was constrained by the contour of the feature plane through the four-prism structure to calculate the tilt angle of the tower and evaluate the state of the tower. Finally, the point cloud of tower head from UAV-based LiDAR was accurately matched with the designed tower head model from database, and a tower head state evaluation model based on matching offset parameters was proposed to evaluate tower head tilt state. The experimental results of simulation and measured data showed that the calculation accuracy of the tilt parameters of transmission tower body was better than 0.5 degrees, that the proposed method can effectively evaluate the risk of tower head with complex structure, and improve the rapid and mass intelligent perception level of the risk state of the transmission line tower, which has a wide prospects for application.

The landscape of ancient sites has changed greatly with the passage of time. Among all of the factors, human activities and the change in natural environment are the main factors leading to the change in site landscape. The Panlongcheng site, which is located in Hubei Province, China, has a history of 3500 years with the most abundant relics in the Yangtze River Basin during the Shang Dynasty. As a near-water site, the landscape of the Panlongcheng site is greatly affected by water level changes and water conservancy activities. In this paper, by using spatial information technology, the data obtained from land and underwater archaeological exploration were integrated to restore landscapes of Panlongcheng sites in different periods. After removing modern artificial features and topsoil, the landscapes of the sites before the Shang Dynasty, in the Shang Dynasty and modern time were reconstructed. Combining historical records of water level changes, the landscape and water–land distribution of the Panlongcheng site were compared. The analysis results reflect the interaction between water level changes and human activities in this region for thousands of years, and support the archaeological findings in the near-water area of the Panlongcheng site, which provides a new idea for the landscape reconstruction and analysis of near-water sites.

In this paper, we propose a novel approach for the extraction of highquality frames to enhance the fidelity of videogrammetry by combining fuzzy frames removal and baseline constraints. We first implement a gradient-based mutual information method to filter out low-quality frames while preserving the integrity of the videos. After frame pose estimation, the geometric properties of the baseline are constrained by three aspects to extract the keyframes: quality of relative orientation, baseline direction, and base to distance ratio. The three-dimensional model is then reconstructed based on these extracted keyframes. Experimental results demonstrate that our approach maintains a strong robustness throughout the aerial triangulation, leading to high levels of reconstruction precision across diverse video scenarios. Compared to other methods, this paper improves the reconstruction accuracy by more than 0.2 mm while simultaneously maintaining the completeness. [ABSTRACT FROM AUTHOR]

Existing indoor 3D mapping solutions suffer from high cost and poor portability. In this article, a low-cost and portable indoor 3D mapping approach using biaxial line laser scanners and a one-dimension laser range finder integrated with microelectromechanical systems is proposed. A multiple-sensor calibration approach is presented to perform the extrinsic calibration of the integrated 3D mapping system. The 2D point cloud acquired by the horizontal laser scanner and the orientation information obtained by the microelectromechanical systems are used as inputs for a simultaneous localization and mapping framework to estimate the 2D poses. The height information acquired by the laser range finder is then fused to obtain the 3D pose, which is applied to restore the actual position and orientation of the 2D point cloud generated by the tilted laser scanner to reconstruct the 3D point cloud of the indoor environment. The experimental results--three typical indoor scenes--demonstrate that the proposed approach can achieve accuracies of 3 cm and 2°. Therefore, the proposed approach is a low-cost, portable, and accurate solution for indoor 3D mapping. [ABSTRACT FROM AUTHOR]

Graphene-wrapped ZnO nanocomposites were fabricated by a simple solvothermal technology with a one-pot route. The structure and morphology of these as-fabricated samples were systematically characterized. The adding of graphene enhanced the content of the oxygen vacancy defect of the sample. All gas-sensing performances of sensors based on as-prepared samples were thoroughly studied. Sensors displayed an ultrahigh response and exceptional selectivity at room temperature under blue light irradiation. This excellent and enhanced toluene gas-sensing property was principally attributed to the synergistic impacts of the oxygen vacancy defect and the wrapped graphene in the composite sensor. The photo-activated graphene-wrapped ZnO sensor illustrated potential application in the practical detection of low concentrations of toluene under explosive environments.

An efficient continuous-flow nitration process of o-xylene at pilot scale was demonstrated. The effects of parameters such as temperature, ratio of H2SO4 to HNO3, H2SO4 concentration, flow rate, and residence time on the reaction were studied. Under the optimal conditions, the yield of products reached 94.1%, with a product throughput of 800 g/h. The main impurities of this continuous-flow nitration process were also studied in detail. Compared with batch process, phenolic impurity decreased from 2% to 0.1%, which enabled the omission of the alkaline solution washing step and thus reduced the wastewater emission. The method was also successfully applied to the nitrification of p-xylene, toluene, and chlorobenzene with good yields.