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Groundwater transit time distributions (TTDs) describe the spectrum of flow‐weighted apparent ages of groundwater from aquifer recharge to discharge. Regional‐scale TTDs in stream baseflow are often estimated from numerical models with limited calibration from groundwater sampling and suggest much younger groundwater discharge than has been observed by discrete age‐dating techniques. We investigate both local and regional‐scale groundwater TTDs in the Upper Middle Loup watershed (5,440 km2) overlying the High Plains Aquifer in the Nebraska Sand Hills, USA. We determined flow‐weighted apparent ages of groundwater discharging through the streambed at 88 discrete points along a 99 km groundwater‐dominated stream segment using 3H, noble gases, 14C, and groundwater flux measurements at the point‐scale (<7.6 cm diameter). Points were organized in transects across the stream width (3–10 points per transect) and transects were clustered in five sampling areas (10–610 m in stream length) located at increasing distances along the stream. Groundwater apparent ages ranged from 0 to 8,200 years and the mean groundwater transit time along the 99 km stream is >3,000 years. TTDs from upstream sampling areas were best fit by distributions with a narrow range of apparent ages, but when older groundwater from downstream sampling areas is included, the regional TTD is scale dependent and the distribution is better described by a gamma model (α ≈ 0.4) which accommodates large fractions of millennial‐aged groundwater. Observations indicate: (a) TTDs can exhibit spatial variability within a watershed and (b) watersheds can discharge larger fractions of old groundwater (>1,000 years) than commonly assumed. Plain Language Summary: The transit time distribution (TTD) of an aquifer describes the complete spectrum of groundwater transit times from the water table to discharge at an outlet such as a stream. TTDs indicate how susceptible aquifers may be to contamination, drought, or pumping. Despite their importance, TTDs are difficult to quantify and many approaches either overestimate the relative fraction of young groundwater discharge or have been conducted in small systems (areas <1,000 km2 or stream lengths <10 km). We measured the flow‐weighted transit time of groundwater through the streambed at 88 points along a 99 km stream in the Upper Middle Loup watershed (5,440 km2) in Nebraska, USA to estimate TTDs of the underlying High Plains Aquifer at various spatial scales. Transit times ranged from 0 to 8,200 years and the mean transit time is >3,000 years along the entire study stream with substantially older groundwater discharge downstream. Upstream TTDs were well‐fit by distributions with larger fractions of young groundwater (<15 years), but TTDs for the entire study stream were better fit by distributions that accommodate large fractions of millennial‐aged groundwater. Our findings suggest that TTDs can vary within a watershed and ancient groundwater may be a significant component of modern streamflow. Key Points: Groundwater age and flux along a 99 km stream overlying the High Plains Aquifer, USA yield transit time distributions (TTD) and meanGroundwater ages ranged from 0 to 8,200 years with mean age >3,000 years and increasing apparent age of baseflow downstreamTTD evolution with stream distance suggests streams overlying regional systems may intersect large fractions of millennial‐aged groundwater [ABSTRACT FROM AUTHOR]

Seasonally snow‐covered catchments in the western United States supply water to growing populations as both annual snowmelt‐driven streamflow and multi‐year groundwater recharge. Although interannual variability in streamflow is driven largely by precipitation, runoff efficiency (the ratio of streamflow to precipitation) in individual catchments varies by 50% or more. Recent work suggests that interannual variability in groundwater storage, inferred from winter baseflow, is a primary control on runoff efficiency, highlighting a need to quantify both the time scales on which groundwater storage varies and the hydro‐climatic drivers of storage. Using over a century of daily stream discharge data from 10 seasonally snow‐covered catchments in northern Utah, we find that temporal variability in winter baseflow, an index of groundwater storage, measured from mean daily January discharge, exhibits a 2–5‐ and 12–15‐year periodicity, driven by regional precipitation patterns and snowmelt dynamics. Specifically, multiple linear regression (MLR) modeling using antecedent hydro‐climatic variables demonstrates that winter baseflow (groundwater storage) was positively related to 3–4 years of antecedent annual precipitation, negatively related to the previous year's mean annual temperature, and positively related to 1–4 antecedent years of snowmelt rate and duration. Because antecedent baseflow (groundwater storage) is strongly related to runoff efficiency, these results suggest that more frequent and longer droughts in a future climate will reduce surface water supplies faster than otherwise expected. More broadly, these results highlight the importance of including the influence of antecedent climate on groundwater storage when modeling and managing water supplies from seasonally snow‐covered catchments. Key Points: Interannual changes in groundwater storage inferred from baseflow in 10 headwater catchments exhibit coherent 2–5 and 12–15 year periodicityInterannual variability in groundwater storage is related to 1–4 years of antecedent precipitation (+) snowmelt rate (+) and temperature (−)Groundwater storage in warmer/drier catchments is related to longer periods of antecedent climate than cooler/wetter catchments [ABSTRACT FROM AUTHOR]

A conceptual model, based on field observations and assumed physics of a perennial firn aquifer near Helheim Glacier (southeast Greenland), is evaluated via steady-state 2-D simulation of liquid water flow and energy transport with phase change. The simulation approach allows natural representation of flow and energy advection and conduction that occur in vertical meltwater recharge through the unsaturated zone and in lateral flow within the saturated aquifer. Agreement between measured and simulated aquifer geometry, temperature, and recharge and discharge rates confirms that the conceptual field-data-based description of the aquifer is consistent with the primary physical processes of groundwater flow, energy transport and phase change. Factors that are found to control simulated aquifer configuration include surface temperature, meltwater recharge rate, residual total-water saturation and capillary fringe thickness. Simulation analyses indicate that the size of perennial firn aquifers depends primarily on recharge rates from surface snowmelt. Results also imply that the recent aquifer expansion, likely due to a warming climate, may eventually produce lakes on the ice-sheet surface that would affect the surface energy balance. [ABSTRACT FROM AUTHOR]

[Display omitted] • Very high amounts of dissolved noble gases were identified in a deep desert aquifer. • Large water table fluctuations during past pluvial periods are reconstructed. • Hydrogeological settings highly affect the air entrapment and dissolution process. • Similar excess air dissolution patterns are identified in distinct desert aquifers. Illuminating past hydrological and climatological conditions in arid regions may provide insights into future trends in groundwater availability. The main objective of this study is to explore paleorecharge processes in the deep regional Nubian Sandstone Aquifer (NSA), which stretches below the hyperarid deserts of the Sinai Peninsula (Egypt) and the Negev (Israel), using dissolved noble gas data. Extremely high amounts of dissolved excess air (Ne concentrations up to 4 × solubility equilibrium) were observed in the ancient (81Kr-depleted) groundwater that was recharged during past pluvial epochs in the basin. The observed unique excess air signal and the clear spatiotemporal structure of the noble gas compositions in the aquifer are hypothesized to reflect two major characteristics of the groundwater system: (a) large-scale, long-term rises in the water table that facilitate the entrapment and dissolution of air bubbles under increased hydrostatic pressure, and (b) the geological settings in the southern recharge area in Sinai, including an almost horizontal position of the layers and intercalation of low-permeability rock formations within the aquifer, which inefficiently reject air bubbles from groundwater, thereby allowing for substantial entrapment of bubbles that dissolve as the water table rises. Enhanced dissolution of entrapped air was also observed in other paleo-groundwater-containing regional sandstone aquifers across North Africa, which, together with the recent findings from the NSA, suggest that large-scale water table fluctuations have likely extensively occurred during past pluvial periods over these (and possibly other) arid regions. A preliminary assessment of noble gas recharge temperatures (NGTs) indicates an apparent decoupling of surface and water table temperatures in the case of deep aquifers with a thick (hundreds of m) unsaturated zone. This observed decoupling calls for a re-evaluation of previously obtained NGT records and a need for future work to consider the modification of NGTs due to soil air fractionation and geothermal heating of the underlying deep unsaturated zones. [ABSTRACT FROM AUTHOR]