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Growing concern on climate change has supported technologies that reduce carbon dioxide emissions. The emission factor of the Brazilian grid electricity is low due to hydropower dominance. However, new hydropower plants have migrated to the Amazon region, with likely social and environmental consequences and rainfall shortage has demanded costly fossil fueled power plants. The grid's emission factor is increasing and new renewable energy alternatives such photovoltaic (PV) are one option to diversify the electricity mix. However, PV systems' efficiency in Brazil varies depending on the climatic region of its installation. This work evaluated the variance in CO 2 emissions reduction of grid connected PV systems for low-income housing in different Brazilian climatic regions. The analysis was based on the PV system, installed in low-income housing projects. Electricity generation was determined through RETScreen and CO 2 emission reductions were determined considering the emission factor of the national grid electricity. Variation of CO 2 emission reductions among bioclimatic regions reached up to 12%. Therefore, PV systems should be adopted in all low-income housing projects in Brazil, regardless of their region, to reduce household's expenditures, CO 2 emissions, and democratize the technology. • PV systems' efficiency varies depending on the climatic region of its installation. • Variance in CO 2 emissions reduction of grid connected PV systems is evaluated. • CO 2 emission reductions vary by up to 11.5% according to the bioclimatic region. • PV systems should be adopted in all low-income housing projects in Brazil. [ABSTRACT FROM AUTHOR]

Biotechnology, the fifth technological wave preceding the sixth wave of Sustainability, is crucial for achieving the 2023 Agenda's Sustainable Development Goals (SDGs), especially in biodiverse Brazil. This review uses composite indicators to compare Brazil with the USA across static and temporal evolutions. Technology Readiness Levels (TRL) 4 and 5 were assessed using patents from 2000 to 2019. Patents from 2000 to 2019 reveal a TRL gap at 4–5 in Brazil, skewed towards academic articles (TRL3), indicating lag behind the USA at TRL5. Brazil's patent growth rate surpasses the USA's by eightfold. Specialization between Brazilian academia and the nation converges. The revealed technological advantage and the distance between academies and between countries are nearing unification. Brazil focuses on SDG3 (Good Health and Well-Being) and SDG7 (Affordable and Clean Energy) but must intensify efforts on SDG2 (Zero Hunger), SDG6 (Clean Water and Sanitation), SDG13 (Climate Action), SDG14 (Life below Water), and SDG15 (Life on Land). The USA concentrates its technologies in SDG3 (Good Health and Well-Being). USA's modern biotech navigates the fifth wave, while Brazil's traditional biotech must modernize, focusing on SDG9 (Industry, Innovation, and Infrastructure) and SDG17 (Global Partnerships for Sustainable Development), requiring government policies for mid-range TRLs. [ABSTRACT FROM AUTHOR]

Sugarcane straw is identified as a potential energy feedstock to increase bioenergy production, but advances are required in understanding the straw removal impacts on soil organic carbon (SOC) stability and storage. The main objective of this study was to evaluate the quantity, quality and physical protection of SOC under areas with different straw removal rates over a six-year period. A field experiment was conducted in randomized blocks with four replications, including the following straw removal treatments: total removal (TR), high removal (HR), low removal (LR), and no removal (NR), corresponding to the quantities of 0, 5, 10 and 15 Mg ha−1 of dry straw maintained on soil surface, respectively. Effects of straw removal on SOC stocks and its temporal dynamics, as well as the rates of carbon (C) incorporated into the soil were evaluated to a 0.3-m depth. The effects on particulate organic matter (POM) and mineral-associated organic matter (MAOM) fractions were evaluated through physical fractionation of SOM. Finally, it was evaluated the distribution of aggregates, the C content of aggregates and the C preservation capacity (CPC) in fractions of aggregates. Our findings revealed that TR and HR decreased SOC stocks at 0.0–0.1 m and 0.0–0.3 m depths. The data indicated that about 24% of the C added via straw were retained in soil, and NR showed a SOC accumulation rate of 1.42 Mg ha-¹ year-¹ relative to baseline. Low straw removal increased POM (46.2%) and MAOM (12.4%) in surface layer as compared to TR. The straw maintenance in the field increased the proportion of soil macroaggregates, resulting in higher amounts of C preserved in this fraction. Our findings suggest that maintaining 10 Mg ha-¹ of straw was enough to favor physical protection and sustain storage of SOC over time. Therefore, the surplus of straw could be removed to produce bioenergy, although this management may hinder soil C sequestration and its benefits for sugarcane production and climate change mitigation. • High and total removal rates of sugarcane straw reduced soil carbon stocks. • Low straw removal increased POM (46.2%) and MAOM (12.6%) compared to total removal. • Straw retention increased soil aggregation and preserved C in macroaggregates. • Low removal rate was enough to sustain physical protection and storage of soil C. [ABSTRACT FROM AUTHOR]

Plastics account for 4.5% of global greenhouse gas (GHG) emissions, which are hard-to-abate due to the use of fossil fuels as feedstock. Our study develops a cradle-to-gate life cycle assessment of bioethylene production, exploring 33 pathways across Brazil, the EU, and the US. It aims to understand whether substituting fossil-based ethylene with bioethylene contributes to lowering carbon emissions, and in which of the relevant bioenergy-producing regions/countries the valorisation of biofuels as feedstocks would provide a less carbon-intensive bioethylene production. Results indicate that bioethylene production through catalytic dehydration of sugarcane bioethanol in Brazil presents lowest GHG emission. This pathway could deliver up to −2.1 kg CO 2 e/kg ethylene when accounting for biogenic carbon storage in long-lived applications such as infrastructure. In contrast, beef tallow performs the poorest as a raw material, regardless of whether land-use change (LUC) emissions are considered. When biogenic carbon storage is factored out, none of the pathways outperforms conventional fossil-based steam cracking; however, some are within the fossil-based range indicating potential indirect benefits through reduced refinery utilisation. Our study underscores that biomaterials production as a climate mitigation strategy must be on par with circular economy measures and the conservation of native forestry ecosystems. These results are particularly relevant to policymakers and industries seeking to align polymer manufacturing with sustainability objectives. • Bio-ethylene cradle-to-gate GHG emissions were assessed for 33 pathways. • Sugary, starch, lignocellulosic and oily crops are raw materials for bio-ethylene. • Local specificities such as biogenic carbon storage and land-use are critical to LCA GHG emissions. • Sugarcane bioethanol dehydration route yielded 2.1 kgCO 2 e captured per of kg ethylene. • Climate mitigation and circular economy policies must be designed coherently. [ABSTRACT FROM AUTHOR]

Deep decarbonization scenarios indicate a decline in fossil oil usage in the coming decades, meaning that oil refineries must adapt. This work evaluates the refining sector in deep decarbonization pathways using Brazil as a case study. BLUES – a national integrated assessment model – is employed to investigate the evolution of the sector in mitigation scenarios until 2050. The production of feedstocks for the petrochemical industry, of fuels for the aviation and maritime sectors, and biomass co-processing are analyzed. These strategies may bring resilience to the sector. The potential for avoiding emissions in refineries' operations is also explored. Findings show that the refining sector operates at 70% and 74% of its nameplate capacity in decarbonization scenarios. These results are used as the starting point for a detailed analysis of Brazilian refineries. Results show that the employment of refineries' assets for purposes aligned with decarbonization targets, along with emissions mitigation in the sector, reduces risks of carbon lock-in and of asset stranding. To our knowledge, this is the first study that evaluates emissions mitigation in the refining sector and also uses an integrated assessment model to investigate oil refining repurposing and co-processing options in the context of decarbonization. • The refining sector is evaluated using an integrated assessment model for Brazil. • A comparison is made between business- as -usual and decarbonization scenarios. • Opportunities for refineries' assets and mitigation measures are explored. • Opportunities for refineries depend on their location and type of processing units. • Risks of carbon lock-in and asset stranding can be reduced. [ABSTRACT FROM AUTHOR]

Future projections indicate an expansion for both food and energy demands, which can increase pressure on land use, while there is an urgent global need for climate change mitigation. Bioenergy is foreseen as key option to meet future energy demands and reduce greenhouse gas (GHG) emissions, however its sustainability depends on locations and regional characteristics. Simultaneously, agricultural production models that co-produce food, feed, and energy offer sustainability synergies and co-benefits, but site-specific sustainability assessments of their large-scale implementation are missing. This study presents a bottom-up approach to assess spatially explicit sustainability aspects of bioenergy-livestock integrated systems (BLI) in Brazil and shed light on their contribution to future energy demands, to climate change mitigation targets, and their impacts on selected ecosystem services, including bioenergy production, climate change mitigation, reduction of food competition, biodiversity conservation, and avoided deforestation. The proposed integration considers livestock intensification and use of biofuels by-products as animal feed supplement, taking advantage of synergies between these two value chains. The expansion of the BLI system in the Center-South region of Brazil produce up to 89 billion liters of ethanol, enough to meet future domestic ethanol demands from multiple shared socioeconomic pathways and generating surpluses for export. This production takes place on 16 million hectares of pastureland within the Sugarcane Agroecological Zoning, excluding the Amazon and Pantanal biomes, and biodiversity hotspots. BLI expansion mitigate up to 250 million tonnes of CO 2 eq and generate 15 billion dollars of profits. The best locations to maximize the selected ecosystem services are west of São Paulo, east of Mato Grosso do Sul, and the south-central region of the states of Goiás. This study may encourage the formulation of enhanced public policies for the integration of bioenergy and livestock value chains and guide a sustainable large-scale deployment of BLI systems. • Bioenergy and livestock integration (BLI): co-production of food, feed and energy. • BLI systems: 89 billion liters of ethanol and 250 million tonnes of CO 2 eq mitigated. • Enough ethanol to meet future Brazilian demands and surplus to be exported. • Biomass expansion only on pastureland inside Sugarcane Agroecological Zoning. • Without land displacement and deforestation of native vegetation. [ABSTRACT FROM AUTHOR]

[Display omitted] • Carbon sequestration potential of the clay fraction. • Determination of the carbon saturation deficit of each mineral of the clay fraction. • Identification of the equation for the prediction of carbon sequestration potential. • Identification of land uses with the greatest carbon sequestration potential. The capacity of soil to sequester carbon (C) is a key process that promotes the reduction of CO 2 in the atmosphere. Soils can absorb as much as 20% of anthropogenic carbon emissions, which can contribute to mitigate climate change. This capacity relies on the organo-mineral association, which includes different minerals, Fe and Al oxides, which have a critical soil organic carbon (SOC) sorption surface. Based on an equation of the potential C saturation deficit of fine soil particles (<20 μm/silt and clay fractions) for tropical regions, this study investigated the SOC sequestration potential of the clay fraction for soils in Piracicaba region, São Paulo State, Brazil as influenced by the clay minerals. This potential was fitted to a spatial regression model for soil depths 0–20 cm and 80 to 100 cm. In the surface layer, the sequestration potential was mostly explained by the relative abundance of soil minerals (Kaolinite, Hematite, Goethite and Gibbsite) determined using vis-NIR-SWIR spectroscopy. A direct relationship was observed with Goethite and Gibbsite, indicating that low concentrations would reduce the sequestration potential. At 80 to 100 cm depth, Kaolinite and Hematite explained most variation in SOC sequestration potential. Additionally, the C associated with the mineral fraction and the C saturation potential as a function of minerals were modeled and a strong importance of hematite in the C sequestration and stabilization cycle was identified at both depths. The individual mineral contribution to SOC sequestration potential was also mapped, which identified high contributions of goethite and gibbsite for deep soil layers. The influence of land use on the carbon sequestration potential of minerals was observed, with the greatest potential being found in areas with pasture and cropping mosaics and grassland and forest mosaics, with a high presence of kaolinite and hematite. These minerals have a greater potential for carbon sequestration at greater depths and, therefore, could be critical in climate change mitigation strategies. [ABSTRACT FROM AUTHOR]

Bioenergy production from sugarcane can be one of the sustainable means of mitigating climate change. This was the central idea of the Conference, "Carbon Balance in the Sugar-Energy Sector," held in Brazil on September 14, 2021. The various panels showed that sugarcane stakeholders, including scientists, farmers, industrialists, and investors, are committed to making large-scale sugarcane production a key ingredient in the mitigation of climate change. Their strategies include sustainable land use and management practices to increase soil carbon sequestration; the large-scale production of biofuel, bioelectricity and bioproducts; negative emission industrial technologies; industrial waste recycling; and sector-specific policies rewarding farmers with carbon credits for avoided greenhouse gas emissions. Therefore, the sugarcane sector is not only key to promoting the social-economic development of Brazil, but also to promoting energy transition, curbing greenhouse gas emissions and consequently, reducing global warming and climate change. • Conference Report: 2021 Carbon balance in the sugar-energy sector. • Carbon Balance in the Sugar-Energy Sector 2021 Conference held by Luiz de Queiroz College of Agriculture (Esalq), University of São Paulo (USP), Piracicaba-SP, Brazil on September 14, 2021. • Sugarcane-derived bioenergy is a key ingredient in fighting climate change while simultaneously maintaining a balanced ecosystem (including enhanced soil health and increased capacity to sequester carbon) and promoting socio-economic development [ABSTRACT FROM AUTHOR]

• Bioenergy-livestock integrated systems can alleviate pressure on land resources. • BLI has potential to meet global future biofuel demands and climate mitigation targets. • Production of feed using bioenergy by-products is techno-economically feasible. • Biofuels from integrated systems can reduce GHG emissions compared to fossil fuels. • There is still room to further explore the integration of bioenergy-livestock value chains. Bioenergy is seen as a key option to meet future energy demands and mitigate climate impacts. However, large-scale deployment of bioenergy can cause an additional pressure over land resources and correspondent sustainability impacts. Enhanced land management practices are fundamental to intensify land-based outputs under different climate mitigation scenarios. Bioenergy-livestock integration (BLI) is a win-win strategy to climate mitigation while ensuring food and fibers demands from the society by using bioenergy by-products as animal feed to release land to additional industrial crops production. This study comparatively assesses BLI opportunities in Brazil to better understand the sustainability issues of the alternatives for integration of these value chains, highlighting the key techno-economic and environmental aspects. When compared to conventional systems, the BLI systems present positive techno-economic impacts and lower greenhouse gas emissions, reaching mitigations up to 32 % and 22 % for meat and ethanol production, respectively. The expansion of BLI systems in Brazil could meet projected biofuels future demands, using less than 20 % of the expected area for this expansion. Potential expansion areas are concentrated in Center-South region of Brazil. BLI systems can be further advanced by including other synergies, such as codigestion of sugarcane vinasse and cattle manure, integration of flex ethanol plants with biodiesel plants, maximization of biofuels by-products as animal feed, and inclusion of novel promising alternative industrial crops such as macauba, sweet sorghum, energy cane and short rotation eucalyptus coppice. However, we identify many potential barriers including the operational complexity, specific know-how, and necessity of economic incentives. This study may provide important insights for strategic and integrated polices for both agricultural and livestock sections as the proper sustainability assessment of an early stage of the deployment of enhanced BLI systems may help to meet global future demands of energy while also contributing to climate change targets. [ABSTRACT FROM AUTHOR]