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1. Supramolecular interactions in the 1:2 co-crystal of 4,4′-bipyridine and 3-chlorothiophene-2-carboxylic acid.

Author

Prajina, Olakkandiyil, Muthiah, Packianathan Thomas, and Geiger, David K.

Subjects
*CARBOXYLIC acids, *BIPYRIDINE, *SUPRAMOLECULAR chemistry, *MOLECULAR interactions, *ASYMMETRY (Chemistry), *CRYSTAL structure
Abstract

The asymmetric unit of the title compound, 2C5H3ClO2S·C10H8N2, is comprised of a molecule of 3-chlorothiophene-2-carboxylic acid (3TPC) and half of a molecule of 4,4′-bipyridine (BPY). A distinctive O--H′N-based synthon is present. Cl′Cl and π-π stacking interactions further stabilize the crystal structure, forming a two-dimensional network parallel to the bc plane. [ABSTRACT FROM AUTHOR]

Published
2016
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