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• Substitution factors for forest products for the Canadian context were developed. • Substitution factors ranging from 0.51 to 0.91 tC/tC were found. • They will lead to more accurate assessments of the forest GHG mitigation potential. • These factors will help governments to manage forest and fight climate change. Evaluating the climate change mitigation potential of the forest sector requires a holistic approach based on forest carbon (C) sequestration, C storage in harvested wood products (HWP) and substitution on markets. High uncertainty is associated with substitution factors, that express avoided fossil greenhouse gas (GHG) emissions from the use of forest-based products in replacement of GHG-intensive materials and fossil fuels. Few studies have focused on the development of substitution factors in Canada, resulting in the use of unrepresentative generic data. Here, we provide a framework to reduce uncertainties related to substitution factors for primary wood products in a Canadian context. A life cycle assessment framework is used to quantify fossil GHG emissions for a baseline and a wood-intensive scenario. For solid product substitution, we focused on the construction sector and analyzed a range of innovative wood buildings with steel and reinforced concrete as alternative materials. We found non-weighted averages of 0.80 tC/tC for sawnwood and 0.81 tC/tC for panels. For energy substitution, we analyzed cases with different specifications on biomass product, facility type and alternative fossil fuel source in non-residential heat production and biofuel transportation sectors. We found a non-weighted average of 0.80 tC/tC for non-residential heat production and 0.51 tC/tC for biofuel transportation, that can be interpreted as 0.91 tC/tC for heavy fuel oil, 0.69 tC/tC for light fuel oil and 0.68 tC/tC for natural gas substitution. These results provide a benchmark for substitution factors in Canada, to help guide forest management strategies for climate change mitigation. [ABSTRACT FROM AUTHOR]

• Hydrogen accounts for 5–10% of total energy in 2050 under 2 °C scenarios. • Hydrogen share increases for a 1.5 °C goal and reaches 15% if CCS is limited. • Transport is the largest consumer of hydrogen, followed by industry and power. • Synthetic hydrocarbons based on hydrogen and direct air capture are an option. • Holistic energy policy design is needed rather than heavy dependence on hydrogen. Hydrogen-based energy carriers, including hydrogen, ammonia and synthetic hydrocarbons, are expected to help reduce residual carbon dioxide emissions in the context of the Paris Agreement goals, although their potential has not yet been fully clarified in light of their competitiveness and complementarity with other mitigation options such as electricity, biofuels and carbon capture and storage (CCS). This study aimed to explore the role of hydrogen in the global energy system under various mitigation scenarios and technology portfolios using a detailed energy system model that considers various energy technologies including the conversion and use of hydrogen-based energy carriers. The results indicate that the share of hydrogen-based energy carriers generally remains less than 5% of global final energy demand by 2050 in the 2 °C scenarios. Nevertheless, such carriers contribute to removal of residual emissions from the industry and transport sectors under specific conditions. Their share increases to 10–15% under stringent mitigation scenarios corresponding to 1.5 °C warming and scenarios without CCS. The transport sector is the largest consumer, accounting for half or more of hydrogen production, followed by the industry and power sectors. In addition to direct usage of hydrogen and ammonia, synthetic hydrocarbons converted from hydrogen and carbon captured from biomass or direct air capture are attractive transport fuels, growing to half of all hydrogen-based energy carriers. Upscaling of electrification and biofuels is another common cost-effective strategy, revealing the importance of holistic policy design rather than heavy reliance on hydrogen. [ABSTRACT FROM AUTHOR]

In the context of modern science, there is a growing interest in the creation of novel porous materials capable of acting as sorbefacients for small gas molecules. This is critical in terms of innovative energy alternatives as well as a healthier environment. In an effort to overcome the consequences of global industrialization, one of humanity's most severe problems, intensive attempts have been made to prevent CO 2 from entering the carbon cycle, as the ever-increasing CO 2 pollution in the earth's atmosphere. Owing to their high porosity, presence of ultra-small pores, structural diversity, high stability, and excellent recyclability, researchers claim that zeolite–an inexpensively accessible sorbent–could be an excellent prototype for CO 2 sorption. Here, we provide an exhaustive review of re-engineered zeolites as a sustainable material for selective CO 2 capture and storage; the progress so far indicates fast removal of CO 2 , and more work conforming to simple scalability, energy and time efficiency application can be done to improve the challenges. [Display omitted] • Discussed the importance of size change from micro to nano level and their proficiency in Carbon capture and storage. • Role of reshaping changes and site selectivity enhancement in CO 2 monetization. • Role of biomass-based material on CO 2 sequestration has also been illustrated. • Strategies to promote circular economics by using wastes as precursors in synthesis of zeolites. • Discussed novel green technologies in constructing reshaped zeolite. [ABSTRACT FROM AUTHOR]