1. Uranium in historical ceramic glazes: Determination by alpha radiation detection and comparison with other methods
- Author
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Vopat, Michal, Goliáš, Viktor, and Jelínek, Emil
- Subjects
alfa ,glaze ,XRF ,uranium ,glazura ,beta ,uran ,alpha ,methodics ,metodika - Abstract
In the Czech Republic yellow and ivory glazes with uranium in the Ditmar-Urbach and Terra Teplice companies were manufactured in the pre-war and inter-war period. The production of these glazes took place at the latest since the 1900, the material springs have existed since 1912. Their production ended in 1945. The most suitable method of non-destructive determination of uranium was the measurement of surface alpha activity on planar surfaces by a probe with a ZnS (Ag) scintillator constructed special for this bachelor thesis. Altogether 85 samples, evidence of this production, were measured. To determine the conversion of detected alpha activity to uranium content, an indirect calibration method was chosen to measure uranium content in three types of glazes by WDS analysis. In the studied set, uranium contents ranged from 0.2-2.2 % with the highest frequency ranging from 0.5-0.6 % U. 16 samples of yellow and ivory glazes were without added uranium with contents up to 322 ppm eU. Comparison of uranium contents determined by surface alpha activity measurement with area beta activity confirmed that the glazing does not form a saturated layer for beta radiation. Three types of glazes analyzed by WDS were also measured by XRF. By comparing uranium contents determined by both methods, it was found that...
- Published
- 2018