Based on Euler-Euler two-fluid model, the gas and liquid flow control equations were established. Combined with the theory of condensation nucleation and droplet growth, the condensation properties of CO2 in a Laval nozzle were simulated. The results showed that both the mathematical models and numerical calculation methods used could reflect the process of gas condensation in the Laval nozzle accurately. The condensation wave of CO2 was not obvious due to its small latent heat of condensation. As the gas flow into the nozzle, the Mach number increased while pressure and temperature decreased, the undercooling increased up to 30 K, and then declined quickly to about 5 K after the occurrence of condensation. The process of nucleation showed a sharp both in time and space. Wilson point is about 2. 21 mm from the throat, the nucleation rate increased sharply from 0 to 2. 04 X 1021 m-3 • s-1 , while the number of droplets reached the order of 1015 instantly. After the formation of condensation core, gas molecules under certain degree of undercooling accumulated and liquefied on the droplets surface, causing droplet radius as well as humidity to increase rapidly. After the process of nucleation, the existing coagulation cores kept growing with the mathematical models and numerical calculation methods used could reflect the process of gas condensation in the Laval nozzle accurately. The condensation wave of CO2 was not obvious due to its small latent heat of condensation. As the gas flow into the nozzle* the Mach number increased while pressure and temperature decreased, the undercooling increased up to 30 K, and then declined quickly to about 5 K after the occurrence of condensation. The process of nucleation showed a sharp both in time and space. Wilson point is about 2. 21 mm from the throat, the nucleation rate increased sharply from 0 to 2. 04 X 1021 m-3 • s-1 , while the number of droplets reached the order of 1015 instantly. After the formation of condensation core, gas molecules under certain degree of undercooling accumulated and liquefied on the droplets surface, causing droplet radius as well as humidity to increase rapidly. After the process of nucleation, the existing coagulation cores kept growing with the droplet radius increasing to 1. 46 X 10-7 m and the humidity up to 0. 093 5 at the exit of the Laval nozzle. [ABSTRACT FROM AUTHOR]