1. 锂吸附剂在油气田卤水中的性能评价.
- Author
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陈立, 马骏, 高源, 谭遥, 高云云, 熊福军, and 顾俊杰
- Subjects
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OIL field brines , *ADSORPTION capacity , *SERVICE life , *WATER-gas , *GAS well drilling - Abstract
Objective Oil and gas fields brine contains impurities such as petroleum and suspended solids, which have potential impacts on the adsorption and separation of lithium resources. This papper studies the feasibility of lithium adsorption extraction from gas field water and the adaptability of mainstream adsorbents in the market for lithium extraction. Methods The study compared the effects of pH and temperature on the adsorption and desorption efficiency of three types of powder adsorbents: aluminium-based, titanium-based, and manganese-based adsorbents. Aluminium-based adsorbent was selected, and the effects of adsorbent morphology, brine, and brine feed flow rate on adsorption and desorption efficiency were studied, and its cycling stability was evaluated. Results Under the optimal conditions, the saturated adsorption capacities of the three adsorbents are approximately 7.9 mg/g, 12.5 mg/g and 15.3 mg/g, respectively. In this experiment, the ratio of sodium to lithium and potassium to lithium in the desorption solution of aluminum adsorbent is better than that of titanium-based and manganese-based adsorbents, and the dissolution loss rate of titanium and manganese adsorbents is 20 and 70 times that of aluminum-based adsorbent, respectively. The service life during long-term operation is significantly shorter than that of aluminum series adsorbents. The ceramic membrane was used to remove suspended solids and petroleum from brine before the lithium extraction. Under the conditions of 20 BV of brine feed, 12 BV/h of brine feed flow rate, 10 BV of desorption water volume, and 10 BV/h of desorption flow rate, the adsorption capacity of aluminum molding adsorbent, as well as the concentration of lithium in tail brine remain stable in ten consecutive cycles of single-column experiments, with an average lithium adsorption rate of 79.2%. Conclusion It is feasible to use the adsorption method to extract lithium resources from the brine of Longwangmiao gas field. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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