1. Study on degradation of sulfadiazine in water by visible-light catalytic technology of Ag/g-C3N4.
- Author
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SONG Yali, ZHANG Xiaojing, ZHU Yibo, JIN Yalin, ZHANG Shuo, and ZHANG Hongzhon
- Subjects
SEWAGE ,INTERMEDIATE goods ,SULFADIAZINE ,WATER quality ,QUALITY factor - Abstract
Visible-light catalysis technology of Ag/g-C
3 N4 (silver/graphite carbon nitride) was applied to the removal of sulfadiazine in wastewater. The degradation effect of Ag/g-C3 N4 on sulfadiazine and water quality factors, degradation mechanismi, intermediate products and its degradation effect on sulfadiazine in actual water were investigated. The results showed that Ag/g-C3 N4 with a mass fraction of 5% could effectively degrade sulfadiazine under visible-light irradiation, with a removal rate of up to 98.3%, and the degradation process conformed to the pseudo-first-order kinetic model; the pH and alkalinity of the solution Ag/g-C3 N4 had little effect on the degradation of sulfadiazine, but the presence of humic acid in the solution inhibited the degradation of sulfadiazine; durng the degradation of sulfadiazine, •O2- and photogenerated holes were the main activities species ; the degradation process mainly produced 4 kinds of intermediate products, which were 2-aminopyrimidine, p-aminobenzenesulfonic acid, hydroxylated sulfadiazine, and nitrated sulfadiazine. When the Songhua River water and the secondaz effluent of domestic sewage were used as the water quality background, the removal rates of Ag/g-C3 N4 for sulfadiazine were 95.4% and 77.5%, respectively. [ABSTRACT FROM AUTHOR]- Published
- 2019
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