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During the Al-killed steel continuous casting process, the molten steel corrosion and the accumulation of alumina inclusion deposits affect the submerged entry nozzle (SEN) wall surface, including the surface morphologies of the smooth wall, porous refractory wall, and clogged wall. The SEN wall surface morphology affects the boundary layer structure and alumina inclusions transport. In this study, a physical modeling method was adopted, and the surface morphologies simulation was realized by filling up the natural porous refractory material and inserting the real clog material in the polymethyl methacrylate SEN model. The velocity in the boundary layer was measured using the particle image velocimetry (PIV) technology, and the alumina inclusions transport path in the boundary layer was calculated by MATLAB software. The MATLAB codes combined the velocity data from the PIV measurement results and the inclusion transport equation. The four-quadrant analysis showed that sweep and ejection events existed in the boundary layer. The fluctuations of the velocity and the turbulent kinetic energy in the normal direction were increased in the porous refractory and the clogged wall boundary layer when the sweep and ejection events existed. The transport of the alumina inclusions with a diameter of 1–15 μm was affected by the ejection and the sweep events. The alumina inclusions moved toward the boundary in the sweep event. During the sweep event, the transport path of alumina inclusions with 1 μm diameter was close to the boundary; the alumina inclusions were more easily attached to the boundary. The alumina inclusions escaped from the boundary in the ejection event. In the porous refractory and the clogged walls, the alumina inclusion transport path in the normal direction was increased. When the SEN wall’s morphologies changed from smooth wall to porous refractory wall and clogged wall, the sweep event area proportion increased from 10.17% to 39.77%, and the ejection event area proportion decreased from 32.96% to 9.24%. Moreover, the sweep event’s probability increased from 25.83% to 28.24% when the morphologies of the SEN wall changed from smooth wall to porous refractory wall and clogged wall, which will increase the alumina inclusion deposition rate in the porous refractory wall and the clogged wall boundary.