1. The Effect of CO2 on Hydrogen Embrittlement Corrosion Behaviors of Tubular Steel P110 in Acid Solution Dissolved High H2S.
- Author
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Deng Hongda, Li Chunfu, and Cao Xianlong
- Subjects
- *
EMBRITTLEMENT , *HYDROGEN , *CORROSION fatigue of metals , *STEEL , *ELECTROCHEMISTRY - Abstract
Hydrogen embrittlement behaviors of tubular steel API-P110 in the acid solution dissolved 50% H2S and 50% CO2 or 50% H2S only were investigated by immersion test, sulfide stress cracking corrosion (SSC) at the constant loading, and electrochemical hydrogen permeation test. Effects of CO2 on hydrogen embrittlement corrosion behavior are discussed. Compared to that of steels without being corroded, in H2S and CO2S or H2S only, the tensile strength(σb), yield strength (σs) and elongation rate at rupture(δc) of steel decline; comparing with in H2S only, the strength and elongation of steel in H2S and CO2 decline less, embrittlement rate is low, the SSC susceptibility of steel lightens, and hydrogen permeation rate(J) decreases. In various corrosive environment, hydrogen permeation density (JH) dramatically increases to peak value as time goes on, then descend slowly until the steady state appears. In high H2S, CO2 improves compactness of corrosion scale, and decreases the content of FexSy in scale. Therefore, the amount of hydrogen permeation in H2S and CO2 is more than in H2S only, as results in the susceptibility of hydrogen embrittlement of steel decreases. [ABSTRACT FROM AUTHOR]
- Published
- 2011
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