1. Preparation and application of a new viscosity-reducing polycarboxylic acid superplasticizer.
- Author
-
WANG Wenjun, WANG Daozheng, ZHU Shun, and CHEN Nan
- Subjects
POLYCARBOXYLIC acids ,ACRYLIC acid ,CONCRETE testing ,CONCRETE additives ,MONOMERS ,CARBOXYLIC acids ,METHACRYLATES ,POLYETHERS - Abstract
The viscosity-reducing polycarboxylic acid superplasticizer PCZ-100 was synthesized from the copolymerization of methacrylate block polyether (JHE-220), acrylic acid (AA) and sodium methylallyl sulfonate (SMAS). The effects of monomer molar ratio, reaction temperature, amount of chain transfer agent and amount of initiator on the properties of superplasticizer were studied, and the effects of different ratios of viscose-reducing carboxylic acid and water-reducing carboxylic acid on the properties of concrete were tested. The results show that the optimum synthesis conditions of PCZ-100 are as follows: n (JHE-220) :n (AA) :n (SMAS)=1.0:3.5:0.3, the amount of chain transfer agent was 1.7% of the total weight of monomer, the amount of initiator was 1.2% of the total weight of monomer, the reaction temperature is 65~70 °C. The superplasticizer synthesized by the above formula and process can better reduce the viscosity of concrete and obviously improve the strength of concrete. [ABSTRACT FROM AUTHOR]
- Published
- 2023