Background In China, the structure shift from just one-child family to both one-child and more-than-onechild families is happening. Exploring how the sibling relationships effect between adolescent personality impulsivity and aggressivity is of great significance for promoting adolescent mental health as well as maintaining social harmony and stability. Objective To investigate the effecting path of sibling relationships between personality impulsivity and aggressivity in adolescents, so as to provide references for the prevention of violent and aggressive behavior in adolescents. Methods From February to April,2023, a total of 1 200 students with sibling relationships from 12 primary and secondary schools in a county of Sichuan province were included by random sampling. Barratt Impulsivity Scale (BIS-11), Chinese Version of Buss & Perry Aggression Questionnaire (AQ-CV), and Sibling Relationship Questionnaire (SRQ) were used for cross-sectional investigation. Pearson Correlation Analysis was used to analyze the correlation between the scores of these scales. Bootstrap method was used to test the effecting path of sibling relationships between personality impulsivity and aggressivity. Results The total score of BIS-11 was positively correlated with that of AQ-CV as well as the scores of conflict and competition dimensions in SRQ (r=0. 485、0. 276、0. 280,P<0. 01), while negatively correlated with the score of warmth/intimacy dimension in SRQ (r=-0. 383,P<0. 01). The total score of AQ-CV was positively correlated with the scores of conflict and competition dimensions in SRQ (r=0. 387,0. 340,P<0. 01), while negatively correlated with the score of warmth/intimacy dimension in SRQ (r=-0. 304,P<0. 01). Within SRQ, negative correlations could be observed between the score of warmth/intimacy and scores of conflict and competition (r=-0. 307, -0. 375,P<0. 01), whereas positive correlation could be observed between the score of conflict and that of competition (r=0. 267,P<0. 01). The total effect of personality impulsivity level on aggressivity level in adolescent was 0. 480 (P<0. 01). Sibling relationships played a mediating role between personality impulsivity and aggressivity in adolescents. Meanwhile, the indirect effect values of warmth/intimacy, conflict and competition were 0. 054, 0. 075 and 0. 062, with the effect values accounting for 11. 21%,15. 70% and 12. 93%, respectively. Conclusion The personality impulsivity of adolescents can directly affect their aggressivity, and sibling relationships may act as an important channel connecting personality impulsivity and aggressivity. [ABSTRACT FROM AUTHOR]