1. 铬铁复合掺杂锂离子筛的制备及其吸附性能研究.
- Author
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李 珍, 高建明, 赵 茜, and 郭彦霞
- Abstract
The Li+ adsorption and separation from low concentration solution by lithium-ion sieve has become one of the most promising methods due to the high selectivity, adsorption capacity and adsorption rate towards lithium ion (Li+). However, the industrial application of lithium manganese oxide ion-sieve is limited due to its difficult recovery, high Mn dissolution loss rate and poor circulation performance. In this paper, the spinel-structure chromium-iron composite doped lithium-ion sieves were prepared by high-temperature solid state reaction method using LiOH·H2O, MnO2, Fe2O3, and Cr2O3 as raw materials. The effects of Cr doping amounts and calcination temperature on the phase structure, adsorption performance, and Mn dissolution loss rate of the lithium-ion sieve precursors were investigated. The results showed that the adsorption capacity of the synthesized lithium-ion sieve could reach 27.30 mg/g and the Mn dissolution loss rate was only 0.43% when the molar ratio of Li, Mn, Fe and Cr was 1∶2∶0.05∶0.05 and the calcination temperature was 550 °C. The selection adsorption experiments showed that the lithium-ion sieve presents excellent selection performance for Li+. Furthermore, the recycling performance of chromium-iron doped lithium-ion sieve showed that the adsorption capacity could still remain 89% of the second cycle (18.51 mg/g) after five cycles, which is greater than 56% of the undoped lithium-ion sieve. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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