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【Objective】The present paper aimed to study the occurrence form of cadmium (Cd) accumulation in soil aggregates of Cd-contaminated brown calcareous soil matrices of paddy fields in the Karst area of northwestern Guangxi, and to provide data reference for safe rice production in this type of Cd-contaminated paddy fields in the region. 【Method】The sampled soil aggregates were separated into five aggregates as ＞ 2.000 mm, 1.000-2.000 mm, 0.050-1.000 mm, 0.074-0.250 mm and ＜0.074 mm, the composition of soil aggregates particle size, Cd content of different particle size aggregates and their main occurrence patterns from 0-20, 20-30, 30-50 and 50-80 cm depth profiles in the Karst area of northwest Guangxi were studied.【Result】The proportion of 0.250-1.000 mm size aggregates in each profile was stable, above 30.00%, with no significant difference between profiles (P＞0.05), the proportion of ＞2.000 mm size aggregates in the 0-20 cm soil profile (tillage layer) was the largest (40.20%), and as the depth of the profile increased, the proportion of ＞2.000 mm size aggregates decreased rapidly, and the proportion of ＜0.250 mm size aggregates showed a gradual increasing trend. Analysis of the Cd content of agglomerates of different particle sizes showed that, in 0-20, 20-30 and 30-50 cm soil profiles, Cd was mainly enriched in ＞2.000 mm particle size aggregates, with contents as high as 2.22, 1.66 and 0.95 mg/kg, respectively, and in the 50-80 cm soil profile, Cd was mainly enriched in 1.000-2.000 mm particle size aggregates. ＞2.000 mm particle size aggregates contributed most to the whole soil Cd content in the 0-30 cm soil layer. The occurrence form of Cd in the aggregates at different profile depths showed obvious differences, the proportion of Cd in aggregates of all particle sizes in the 0-20 cm profile was mainly in the organic matter binding state, with the smallest proportion of Cd in the exchangeable state (except for ＜0.074 mm particle size aggregates), and the proportion of Cd in the exchangeable state in the aggregates increased greatly with the increase of the depth of the profile, when the profile depth was increased to under 30 cm, the Cd in the aggregates mainly existed in carbonate bound state, and with minimal content in the residue lattice state.【Conclusion】In the typical Cd-contaminated brown calcareous soil matrices of paddy fields in the Karst area of northwestern Guangxi, the Cd is mainly enriched in aggregates of ＞2.000 mm and 1.000-2.000 mm particle size, the Cd in the aggregates of each particle size in the 0-20 cm tillage soil is mainly in the form of organic matter bound state, and with the smallest proportion in the form of exchangeable state. With the increase of the profile depth, the proportion of exchangeable Cd increases greatly, while the proportion of Cd in the stable form decreases significantly. Therefore, in the actual production process, it should focus on improving the content of large particle size soil aggregates and avoiding excessive intensive ploughing and deep tilling, reducing the exchangeable state Cd content in the ploughed soil, and ultimately reducing the risk of excessive Cd in rice during rice production. [ABSTRACT FROM AUTHOR]

[Objective] The present paper aimed to investigate the effects of microplastics on the structure and carbon, nitrogen, phosphorus stoichiometric characteristics of red soil with different levels of iron enrichment, and to provide theoretical basis for guiding the improvement of soil quality and pollution management in red soil areas. [Method] Using subtropical red soil as the research object, low density polyethylene (M0, M1, M2) with 0, 0.1%, 1.0% mass and iron (Fe0, Fe1, Fe2) with 0, 10 and 20 g/kg mass were added through indoor cultivation experiments to simulate the pollution level of microplastics and the degree of iron enrichment in red soil. The distribution characteristics of water stable aggregates and the stoichiometric characteristics of carbon, nitrogen and phosphorus in red soil polluted by microplastics under different iron enrichment conditions were studied. [Result] Under the condition of Fe0o, compared with M0, the aggregate content (WSA), mean weight diameter (MWD) and geometric mean diameter (GMD) of M1 with particle size > 0.25 mm decreased, and the WSA, MWD and GMD of M2 increased significantly; Under Fe0, conditions, there was no significant difference in the stability indicators of aggregates among M0, M1 and M2; Under Fe2 conditions, both M1 and M2 significantly reduced the WSA, MWD and GMD of soil aggregates. In terms of carbon, nitrogen and phosphorus content and their stoichiometric characteristics, M1 and M2 under Fe0 conditions could significantly increase soil organic carbon content (SOC); Under Fe0, and Fe2 conditions, microplastic treatment had no significant effect on SOC. The total nitrogen content (TN) of the soil decreased significantly under Fe0, and Fe1, conditions, while microplastic treatment had no significant effect on TN under Fe2 conditions; The total phosphorus content (TP) of the soil showed M0 > M1 > M2. The changes in soil nutrients ultimately led to a significant increase in C/N, C/P and N/P of all microplastic treatments (except for Fe0, M1, Fe2 M1 and Fe2 M2). [Conclusion] The effects of different treatments on the stability of soil aggregates vary. Under the current existing red soil conditions, low micro plastic pollution can reduce the stability of soil aggregates, while high micro plastic pollution can increase the stability of soil aggregates. Under relatively light iron rich red soil conditions, both low and high microplastic pollution have no significant impact on the stability of soil aggregates. Under relatively high iron rich red soil conditions, both low and high microplastic pollution can reduce the stability of soil aggregates. M0reover, the changes in soil aggregate structure under different treatments led to significant differences in the stoichiometric characteristics of carbon, nitrogen and phosphorus in the soil. Overall, microplastic pollution can significantly improve the C/N, C/P and N/P of red soil. [ABSTRACT FROM AUTHOR]