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The friction and wear of water-lubricated bearings has always been an engineering problem that we need to solve urgently. To investigate the influence of SiO 2 particle size and dispersion on the friction and wear properties of nitrile rubber. The friction and wear performance of rubber compounds (SiO 2 (nano) /NBR, SiO 2 (micr) /NBR and SiO 2 (TESP) /NBR) was tested by American Rtec multifunctional friction and wear test machine under the conditions of water lubrication and constant temperature. The results showed that the particle size of SiO 2 has a great impact on its dispersion in nitrile rubber, and the surface modification of SiO 2 can significantly improve its dispersion. SiO 2 (TESPT) /NBR showed a good friction coefficient under low-speed and high-load conditions. The wear of SiO 2 (nano) /NBR and SiO 2 (micr) /NBR, which was mainly the fatigue wear, was relatively serious. In contrast, the modified SiO 2 had a smaller particle size, better dispersion and stronger interfacial bonding with the nitrile rubber matrix. This significantly reduced the wear of SiO 2 (TESPT) /NBR, which was mainly the abrasive wear, and improved its wear resistance. • TESPT was used to modify the hydroxyl groups on the surface of nano-silica. • The escape and disintegration of SiO 2 (micr) and SiO 2 (nano) agglomerates during the wear process were characterized. • The effect of particle size and dispersion of SiO 2 on tribological properties of nitrile rubber was revealed. [ABSTRACT FROM AUTHOR]