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Fe(III)-loaded chitosan (CTS-Fe) composite was used for the first time to remove and recover phosphorus (P) from waste activated sludge (WAS) via anaerobic digestion (AD). The P transformation pathway and the effect of CTS-Fe addition on the AD process were investigated using batch experiments. The P fractionation results indicate that non-apatite inorganic phosphorus (NAIP) reduction in the solid phase of sludge at 20 g/L of CTS-Fe addition (6.72 mg/g-SS) was 2.4 times higher than that in the control (2.77 mg/g-SS, no CTS-Fe addition). This is probably brought about by the added CTS-Fe enhanced the reduction of Fe(III)-P compounds in the sludge with phosphate released into the liquid phase. CTS-Fe can efficiently recover 95% of P from the liquid digestate of WAS. Notably, partial Fe(III) on the CTS-Fe was reduced and effectively combined with P to form vivianite crystals on the CTS-Fe surface during the AD process. Characterization analysis demonstrated that ligand exchange and chemical precipitation were the dominant mechanisms for P removal/recovery. Furthermore, the addition of CTS-Fe increased methane production by 11.9 - 32.2% under the tested conditions, likely attributable to the enhanced hydrolysis of WAS under CTS-Fe supplementation. As the P-loaded CTS-Fe particles can be easily separated and recovered from the AD system and further reutilized in agriculture, this study could provide a new approach for simultaneous P removal/recovery and enhanced methane production from AD of WAS.

The sustainability of an agricultural system depends highly upon the recycling of all useful substances from agricultural wastes. This study explored the feasibility of comprehensive utilization of C, N and P resources in swine manure (SM) through short-term dry anaerobic digestion (AD) followed by dry ammonia stripping, aiming at achieving (1) effective total volatile fatty acids (VFAs) production and separation; (2) ammonia recovery from the digestate; and (3) preservation of high P bioavailability in the solid residue for further applications. Specifically, two ammonia stripping strategies were applied and compared in this work: (I) ammonia stripping was directly performed with the digestate from dry AD of SM (i.e. dry ammonia stripping); and (II) wet ammonia stripping was conducted by using the resultant filtrate from solid-liquid separation of the mixture of digestate and added water. Results showed that dry AD of the tested SM at 55 °C, 20% TS and unadjusted initial pH (8.6) for 8 days produced relatively high concentrations of total VFAs (94.4 mg-COD/g-VS) and ammonia-N (20.0 mg/g-VS) with high potentially bioavailable P (10.6 mg/g-TS) remained in the digestate, which was considered optimal in this study. In addition, high ammonia removal efficiencies of 96.2% and 99.7% were achieved through 3 h' dry and wet stripping (at 55 °C and initial pH 11.0), respectively, while the total VFAs concentration in the digestate/filtrate remained favorably unchanged. All experimental data from the two stripping processes well fitted to the pseudo first-order kinetic model (R(2) = 0.9916-0.9997) with comparable theoretical maximum ammonia removal efficiencies (Aeq, >90%) being obtained under the tested dry and wet stripping conditions, implying that the former was more advantageous due to its much higher volumetric total ammonia-N removal rate thus much smaller reactor volume, less energy/chemicals consumption and no foaming problems. After 8 days' dry AD and 3 h' dry ammonia stripping, the separated liquid containing VFAs and the recovered ammonia were both marketable products, and the solid residues with averagely higher C/N ratios of 25.7 than those of raw SM (18.0) meanwhile maintaining a relatively high bioavailable P content of 8.1 mg/g-TS can serve as better feedstock for methane fermentation.

A solar fluidized tubular photocatalytic reactor (SFTPR) with simple and efficient light collector was developed to degrade waste activated sludge (WAS) and simultaneously produce hydrogen. The photocatalyst was a TiO2 film doped by silver and silver compounds (AgX). The synthesized photocatalyst, AgX/TiO2, exhibited higher photocatalytic activity than TiO2 (99.5% and 30.6% of methyl orange removal, respectively). The installation of light collector could increase light intensity by 26%. For WAS treatment using the SFTPR, 69.1% of chemical oxygen demand (COD) removal and 7866.7 μmol H2/l-sludge of hydrogen production were achieved after solar photocatalysis for 72 h. The SFTPR could be a promising photocatalysis reactor to effectively degrade WAS with simultaneous hydrogen production. The results can also provide a useful base and reference for the application of photocatalysis on WAS degradation in practice.