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Mercury (Hg) speciation can affect its removal efficiency by adsorbents. This study assessed the removal of dissolved inorganic Hg(II) species (Hg(II)*), β-HgS nanoparticles (HgS NP), and Hg complexed with dissolved organic matter (Hg-DOM) by three sorbents: activated carbon (AC), sulfur-impregnated activated carbon (SAC), and organoclay (OC). The effect of ionic composition, solution ionic strength, and natural organic matter (NOM) concentration on the removal of each Hg species was also evaluated. The three adsorbents were all effective in removing Hg(II)*, Hg-DOM, and HgS NPs. Increasing ionic strength decreased the removal of Hg(II)* species due to the formation of ionic Hg species with lower affinity for the sorbents. Added NOM decreased the removal of Hg(II)* and HgS NPs by all sorbents with the OC sorbent being most susceptible to NOM fouling. On a surface area-normalized basis, the OC removed all types of Hg species better than the AC and SAC samples. Moreover, adsorbed Hg-DOM transformed to a β-HgS phase on the OC, but not for AC and SAC. These studies indicate that both Hg speciation and the water quality parameters need to be considered when designing sorbent-based emission controls to meet Hg removal targets., (Copyright © 2019. Published by Elsevier Ltd.)

Brines generated from oil and natural gas production, including flowback water and produced water from hydraulic fracturing of shale gas, may contain elevated concentrations of bromide (~1 g/L). Bromide is a broad concern due to the potential for forming brominated disinfection byproducts (DBPs) during drinking water treatment. Conventional treatment processes for bromide removal is costly and not specific. Selective bromide removal is technically challenging due to the presence of other ions in the brine, especially chloride as high as 30-200 g/L. This study evaluates the ability of solid graphite electrodes to selectively oxidize bromide to bromine in flowback water and produced water from a shale gas operation in Southwestern PA. The bromine can then be outgassed from the solution and recovered, as a process well understood in the bromine industry. This study revealed that bromide may be selectively and rapidly removed from oil and gas brines (~10 h(-1) m(-2) for produced water and ~60 h(-1) m(-2) for flowback water). The electrolysis occurs with a current efficiency between 60 and 90%, and the estimated energy cost is ~6 kJ/g Br. These data are similar to those for the chlor-alkali process that is commonly used for chlorine gas and sodium hydroxide production. The results demonstrate that bromide may be selectively removed from oil and gas brines to create an opportunity for environmental protection and resource recovery., (Copyright © 2013 Elsevier Ltd. All rights reserved.)

Nano-scale zero-valent iron (NZVI) particles are increasingly used to remediate aquifers contaminated with hazardous oxidized pollutants such as trichloroethylene (TCE). However, the high reduction potential of NZVI can result in toxicity to indigenous bacteria and hinder their participation in the cleanup process. Here, we report on the mitigation of the bactericidal activity of NZVI towards gram-negative Escherichia coli and gram-positive Bacillus subtilis in the presence of Suwannee River humic acids (SRHA), which were used as a model for natural organic matter (NOM). B. subtilis was more tolerant to NZVI (1 g/L) than E. coli in aerobic bicarbonate-buffered medium. SRHA (10 mg/L) significantly mitigated toxicity, and survival rates after 4 h exposure increased to similar levels observed for controls not exposed to NZVI. TEM images showed that the surface of NZVI and E. coli was surrounded by a visible floccus. This decreased the zeta potential of NZVI from -30 to -45 mV and apparently exerted electrosteric hindrance to minimize direct contact with bacteria, which mitigated toxicity. H(2) production during anaerobic NZVI corrosion was not significantly hindered by SRHA (p > 0.05), However, NZVI reactivity towards TCE (20 mg/L), assessed by the first-order dechlorination rate coefficient, decreased by 23%. Overall, these results suggest that the presence of NOM offers a tradeoff for NZVI-based remediation, with higher potential for concurrent or sequential bioremediation at the expense of partially inhibited abiotic reactivity with the target contaminant (TCE)., (Copyright © 2010 Elsevier Ltd. All rights reserved.)

Sequestration of polychlorinated biphenyls (PCBs) by activated carbon (AC) has been proposed as a remediation strategy for PCB-contaminated sediments. However, published PCB-AC adsorption isotherm data are sparse and, while sediment-derived dissolved organic matter (DOM) and biofilms are likely to be present in sediments, the impacts of these loadings have not been quantified. Batch laboratory experiments were undertaken to obtain equilibrium adsorption capacities, q(e), for 9 PCBs on virgin AC, DOM-loaded AC, and biofilm-covered AC. Isotherm data fit the Freundlich isotherm equation (average R2=0.94, n=27) over the range of aqueous concentrations studied ( approximately 0.1-1000 ng/L). Planarity effects were evident at low aqueous concentrations only (0.1-10 ng/L), where q(e) of three PCBs of similar hydrophobicity decreased with an increasing number of ortho-chlorines, indicating steric hindrances attenuated adsorption. The values of q(e) for DOM- and biofilm-loaded ACs were approximately one order of magnitude smaller than those on virgin AC when normalized by the available AC surface area, indicating that PCB adsorption likely occurred on specific regions of the AC structure. Nevertheless, virgin and loaded ACs used in this study had sufficiently high PCB adsorption capacities to warrant further study as an in-situ remediation alternative for PCB-contaminated sediments.