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Ignimbrites within calderas host intrusions with hazardous and/or economically significant hydrothermal systems. The Hvítserkur ignimbrite at Breiðuvík caldera, north-eastern Iceland, is intruded by basaltic dykes. Our data show that the ignimbrite immediately adjacent to the dyke is hard, dark-coloured, recrystallised quartz, plagioclase, and alkali feldspar with a low permeability and porosity and frequent macrofractures. At 1-2 m from the dyke, the ignimbrite is hard, dominantly glassy with pervasive perlitic microfractures, has high permeability, but low porosity and frequent macrofractures. A narrow zone of pervasive unlithified clay exists 2 m from the dyke. Beyond this, the ignimbrite is soft and zeolite-rich, has low permeability, high porosity and fewer macrofractures. The dyke intrusion promoted a narrow zone of welding, fracturing and perlitisation in the ignimbrite resulting in high permeability and focussed alteration. Our study shows how intrusions and their thermal aureoles create vertical pathways for, and horizontal barriers to, geothermal fluid flow.

The use of Mt. Epomeo Green Tuff (MEGT) as a building stone is widespread on Ischia Island (Italy). We assess here the fire resistance of MEGT by thermally stressing samples to temperatures up to 1000 °C. Porosity and uniaxial compressive strength increase and decrease from 44% and 4.5 MPa at ambient temperature to 48% and 1.5 MPa following exposure to 1000 °C, respectively. Complementary thermogravimetric and X-ray powder diffraction analyses, experiments that monitor acoustic emissions during heating/cooling, and microstructural observations highlight that these changes are the result of thermal microcracks, formed due to the breakdown of zeolites and clays (MEGT contains 35 wt.% analcime, 15 wt.% smectite, and 3 wt.% illite) at high temperature. Although the stability of structures built from MEGT will be jeopardised at high temperature, a very low thermal diffusivity requires that fires must burn for many hours to compromise the strength of a typical dimension stone: tuffs are tough in the event of fire.