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Nutrients recovery has become a meaningful solution to address shortage in the fertilizer production which is the key issue of nations' food security. The concept of municipal wastewater is based on its ability to be a major potential source for recovered nutrients because of its vast quantity and nutrient-rich base. Microbial fuel cell (MFC) has emerged as a sustainable technology, which is able to recover nutrients and simultaneously generate electricity. In this study a two-chambered MFC was constructed, and operated in a continuous flow mode employing artificial municipal wastewater as a substrate. The effects of hydraulic retention time (HRT) on the recovery of nutrients by MFC were studied. The COD removal rates were insignificantly influenced by varying HRT from 0.35 to 0.69 d, that were over 92%. Furthermore, the recovery rate of nutrients was insignificantly affected while increasing the HRT, which fluctuates from 80% to 90%. In contrast, the maximum power generation declined when HRT increased and the lowest one was 510.3 mV at the HRT of 0.35 d. These results demonstrate that the lab-scale double chamber MFC using municipal wastewater as the substrate can provide a highly effective removal strategy for organic matter, nutrients recovery and electricity output when operating at a specific HRT.

Immobilizing La(OH)3 nanoparticles (NPs) to porous hosts has been widely applied to inhibiting their inherent aggregation as well as the subsequent low utilization efficiency of La. In this study, a series of rice husk biochars (RHBCs) with high mesoporous rates were prepared and the effects of host pore structure and point of zero charge (pHpzc) on phosphate adsorption by La-modified RHBCs was particularly focused. Characterization results confirmed that La(OH)3 NPs were both confined in the pore channel and external surface of RHBCs. Adsorption kinetics and isotherms showed that La-modified RHBCs with higher mesoporous rates of the host showed a faster adsorption rate and La-modified RHBCs exhibited superior La utilization efficiency than many reported La-incorporated adsorbents. Phosphate could be effectively captured over a wide pH of 3–10 due to the high pHpzc of La-modified RHBCs. Moreover, the La-modified RHBCs showed satisfactory affinity towards phosphate in the presence of coexisting anions and the phosphate adsorption by La-RHBC9 was enhanced in the presence of Ca2+, while it was inhibited in the presence of Mg2+. The mesoporous structure of RHBCs strengthened the stability of La-modified RHBCs and weakened the inhibition of coexisting humic substances on phosphate adsorption through the “shielding effect”.

Phosphate plays an irreplaceable role in the production of fertilizers. However, its finite availability may not be enough to satisfy increasing demands for the fertilizer production worldwide. In this scenario, phosphate recovery can effectively alleviate this problem. Municipal wastewater has received high priority to recover phosphate because its quantity is considerable. Therefore, phosphate recovery from municipal wastewater can bring many benefits such as relieving the burden of increasing production of fertilizers and reduction in occurrence of eutrophication caused by the excessive concentration of phosphate in the released effluent. The chemical processes are the most widely applied in phosphate recovery in municipal wastewater treatment because they are highly stable and efficient, and simple to operate. This paper compares chemical technologies for phosphate recovery from municipal wastewater. As phosphate in the influent is transferred to the liquid and sludge phases, a technical overview of chemical phosphate recovery in both phases is presented with reference to mechanism, efficiency and the main governing parameters. Moreover, an analysis on their applications at plant-scale is also presented. The properties of recovered phosphate and its impact on crops and plants are also assessed with a discussion on the economic feasibility of the technologies.