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Propylparaben (PrP) has attracted extensive concerns due to its wide occurrence in wastewater and potential health risk. Herein, nitrogen vacancy engineered reticulate g-C

Gas/particle (G/P) partitioning is an important influencing factor for the environmental fate of semi-volatile organic compounds (SVOCs). The G/P partitioning of polycyclic aromatic hydrocarbons (PAHs) is an integrated complex process due to its formation and growth concurrently with particles. Based on the large dataset of gaseous and particulate samples in a wide ambient temperature range of 50 °C, the simple empirical equations based on ambient temperature were established to predict the G/P partitioning quotient (KP) of PAHs at the temperature range from 252 K to 307 K (−21 °C to 34 °C). The performance of the empirical equations was validated by comparison with the monitoring KP of PAHs worldwide. The empirical equations exhibited good performance for the prediction of KP of PAHs based on ambient temperature. Two deviations with the prediction lines of the previous G/P partitioning models from the monitoring data of KP were observed. It was found that the deviations might be attributed to some non-considered influencing factors with the previous G/P partitioning prediction models. Therefore, further research should be conducted to study the mechanism of the G/P partitioning of PAHs, and more influencing factors should be introduced into the establishment of G/P partitioning models of PAHs. In summary, the result of the present study provided a convenient method for the prediction of KP of PAHs, which should be useful for the study of environmental fate of PAHs in atmosphere.

The study of indoor organic film on planar surfaces has been shown to be important to assess the transport and fate of organic pollutants in indoor environments. Limited research showed the relationship between equilibrium status of polycyclic aromatic hydrocarbons (PAHs) and the growth days for indoor window films. To accomplish this goal, indoor window film samples were collected in relation to film growth days in Northeast China. PAHs were frequently detected in window films collected during heating season (H-season), with concentrations significantly higher than that of non-heating season (NH-season). Accumulation characteristics of PAH suggested that PAH concentrations (ng/m2 film) were growing near-linearly with time. Partitioning status for PAHs between gas and window films under different accumulation stage from 1 to 11 weeks was investigated during the two seasons. The equilibrium status of PAHs in the films suggested that the octanol–air partition coefficient (logKOA) of the targeted PAHs should be approximately

Pharmaceuticals and personal care products (PPCPs) in wastewater have become an emerging issue due to their negative effects on human health and aquatic ecosystems. Two full-scale municipal and industrial wastewater treatment plants (WWTPs) along the Songhua River were chosen to evaluate the intra-day dynamics, seasonal variations and removal of 12 selected PPCPs. Our results suggested that the selected PPCPs were frequently detected in the influent and effluent. Caffeine was the predominant compound in the influent; while the selected PPCPs was dominated by TCS in the effluent, suggesting the different fates of selected PPCPs in the WWTPs. The intra-day dynamics of PPCPs in the influent were evaluated, suggesting that the 12 PPCPs can be grouped into three categories because of their different use patterns. The analysis of seasonal changes of PPCPs concentrations in the WWTPs suggested that the concentrations of some PPCPs were influenced by the chemical usage, degradation and temperature. The removal efficiency for the PPCPs were very high with the values ranged from 70.0% to 99.7% for WWTP#1, and from 62.5% to 99.4% for WWTP#2. Significant seasonal variations of PPCPs removal efficiency were observed. Base on the mass loading of PPCPs in the two WWTPs, our results suggested that WWTP#1 in the urban core received much more PPCPs in comparison to WWTP#2 in the suburban regions, suggesting that influences of the service population.

57 pairs of air samples (gas and particle phases) were collected using a high volume air sampler in a typical city of Northeast China. Brominated flame retardants (BFRs) including 13 polybrominated diphenyl ethers (PBDEs, including BDEs 17, 28, 47, 49, 66, 85, 99, 100, 138, 153, 154, 183, and 209) and 9 alternative BFRs (p-TBX, PBBZ, PBT, PBEB, DPTE, HBBZ, γ-HBCD, BTBPE, and DBDPE) were analyzed. The annual average total concentrations of the 13 PBDEs and the 9 alternative BFRs were 69 pg/m3 and 180 pg/m3, respectively. BDE 209 and γ-HBCD were the dominant congeners, according to the one-year study. The partial pressure of BFRs in the gas phase was significantly correlated with the ambient temperature, except for BDE 85, γ-HBCD and DBDPE, indicating the important influence of ambient temperature on the behavior of BFRs in the atmosphere. It was found that the gas–particle partitioning coefficients (logKp) for most low molecular weight BFRs were highly temperature dependent as well. Gas–particle partitioning coefficients (logKp) also correlated with the sub-cooled liquid vapor pressure (logPLo). Our results indicated that absorption into organic matter is the main control mechanism for the gas–particle partitioning of atmospheric PBDEs.