1. Superb Dye Adsorption and Dye-Sensitized Change in Cu2O–Ag Crystal Faces in the Dark
- Author
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Prashant Kartikeya, Soumen Dutta, Jaya Pal, Anup Kumar Sasmal, Ramkrishna Sahoo, and Tarasankar Pal
- Subjects
Langmuir ,Materials science ,Inorganic chemistry ,Oxide ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Crystal ,chemistry.chemical_compound ,Silver nitrate ,General Energy ,Adsorption ,chemistry ,Methyl orange ,Photocatalysis ,Galvanic cell ,Physical and Theoretical Chemistry ,0210 nano-technology - Abstract
Hybrid Cu2O–Ag is attractive because of its many applications in the fields of photocatalysis, surface-enhanced Raman scattering (SERS), and optical features. In this article, we have presented a newer application of Cu2O–Ag. Cu2O–Ag has been found to exhibit excellent anionic dye adsorption properties together with organic transformation for effective water remediation. Cu2O–Ag was prepared through a facile but controlled galvanic reaction between cuprous oxide (Cu2O) and silver nitrate (AgNO3), rendering stability and porosity. The experimental results of adsorption showed that Cu2O–Ag bears an exceptionally high adsorption capacity toward methyl orange (501.23 mg g–1), which is higher than most reported results. The adsorption of MO on Cu2O–Ag happens because of the definite chemical interaction between Cu(I) and the SO3– functionality of MO. A kinetic study revealed that the MO adsorption on Cu2O–Ag primarily followed the pseudo-second-order kinetic model. The kinetic model followed the Langmuir adsor...
- Published
- 2016
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