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Your search keyword '"Terence G. Hamill"' showing total 2 results
Start Over Author "Terence G. Hamill" Journal the journal of organic chemistry
2 results on '"Terence G. Hamill"'

1. Three-different-component [1+2+n]-annulation reactions: ionic and radical cyclizations

Author

Edward Asirvatham, Gary H. Posner, Kevin S. Webb, and Terence G. Hamill

Subjects
chemistry.chemical_classification, Annulation, Ketone, Bicyclic molecule, Stereochemistry, Organic Chemistry, Free-radical reaction, Medicinal chemistry, chemistry.chemical_compound, Nucleophile, chemistry, Electrophile, Enone, Tetrahydrofuran
Abstract

One-carbon-atom Michael donors are used to initiate convergent and flexible [1+2+3]-hexannulations and [1+2+2]-pentannulations in which the initial nucleophilic carbon atom terminates the reaction sequence in an ionic fashion as an electrophilic center or in a carbon-centered radical fashion as a nucleophilic center. This protocol is used to prepare regiospecifically substituted bicyclic ketones and lactones and a cis-bicyclic tetrahydrofuran

Published
1990

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