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Errors in the control of quantum systems may be classified as unitary, decoherent and incoherent. Unitary errors are systematic, and result in a density matrix that differs from the desired one by a unitary operation. Decoherent errors correspond to general completely positive superoperators, and can only be corrected using methods such as quantum error correction. Incoherent errors can also be described, on average, by completely positive superoperators, but can nevertheless be corrected by the application of a locally unitary operation that ``refocuses'' them. They are due to reproducible spatial or temporal variations in the system's Hamiltonian, so that information on the variations is encoded in the system's spatiotemporal state and can be used to correct them. In this paper liquid-state nuclear magnetic resonance (NMR) is used to demonstrate that such refocusing effects can be built directly into the control fields, where the incoherence arises from spatial inhomogeneities in the quantizing static magnetic field as well as the radio-frequency control fields themselves. Using perturbation theory, it is further shown that the eigenvalue spectrum of the completely positive superoperator exhibits a characteristic spread that contains information on the Hamiltonians' underlying distribution., 14 pages, 6 figures

Control over spin dynamics has been obtained in NMR via coherent averaging, which is implemented through a sequence of RF pulses, and via quantum codes which can protect against incoherent evolution. Here, we discuss the design and implementation of quantum codes to protect against coherent evolution. A detailed example is given of a quantum code for protecting two data qubits from evolution under a weak coupling (Ising) term in the Hamiltonian, using an ``isolated'' ancilla which does not evolve on the experimental time scale. The code is realized in a three-spin system by liquid-state NMR spectroscopy on 13C-labelled alanine, and tested for two initial states. It is also shown that for coherent evolution and isolated ancillae, codes exist that do not require the ancillae to initially be in a (pseudo-)pure state. Finally, it is shown that even with non-isolated ancillae quantum codes exist which can protect against evolution under weak coupling. An example is presented for a six qubit code that protects two data spins to first order., Reformatted single spaced with figures incorporated into text (18 pages, 6 figures, PDF only, submitted to J. Chem. Phys.)

The results of quantum process tomography on a three-qubit nuclear magnetic resonance quantum information processor are presented, and shown to be consistent with a detailed model of the system-plus-apparatus used for the experiments. The quantum operation studied was the quantum Fourier transform, which is important in several quantum algorithms and poses a rigorous test for the precision of our recently-developed strongly modulating control fields. The results were analyzed in an attempt to decompose the implementation errors into coherent (overall systematic), incoherent (microscopically deterministic), and decoherent (microscopically random) components. This analysis yielded a superoperator consisting of a unitary part that was strongly correlated with the theoretically expected unitary superoperator of the quantum Fourier transform, an overall attenuation consistent with decoherence, and a residual portion that was not completely positive - although complete positivity is required for any quantum operation. By comparison with the results of computer simulations, the lack of complete positivity was shown to be largely a consequence of the incoherent errors during the quantum process tomography procedure. These simulations further showed that coherent, incoherent, and decoherent errors can often be identified by their distinctive effects on the spectrum of the overall superoperator. The gate fidelity of the experimentally determined superoperator was 0.64, while the correlation coefficient between experimentally determined superoperator and the simulated superoperator was 0.79; most of the discrepancies with the simulations could be explained by the cummulative effect of small errors in the single qubit gates., Comment: 26 pages, 17 figures, four tables; in press, Journal of Chemical Physics