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1. Synthesis of the 2β,3α- and 2β,3β-isomers of 3-(p-substituted phenyl)tropane-2-carboxylic acid methyl esters

Author

Kathryn I. Keverline, Anita H. Lewin, Philip Abraham, and F. Ivy Carroll

Subjects
chemistry.chemical_classification, Samarium, chemistry.chemical_compound, chemistry, Carboxylic acid, Organic Chemistry, Drug Discovery, Iodide, Organic chemistry, chemistry.chemical_element, Tropane, Biochemistry
Abstract

The synthesis of 3-( p -substituted phenyl)trop-2-carboxylic acid methyl ester 8 and its reduction with samarium iodide provide a new synthesis of 3β-(4′-substituted phenyl)tropane-2β-carboxylic acid methyl ester ( 2 ) and, in addition, give the first synthesis of the 2β,3α-diastereoisomer 4 .

Published
1995
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