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1. Asymmetric synthesis of the erythrinan alkaloid system using a chiral lithium amide base desymmetrisation as the key step

Author

Nigel S. Simpkins, Christopher D. Gill, and Daniel A. Greenhalgh

Subjects
chemistry.chemical_classification, chemistry.chemical_compound, Lithium amide, chemistry, Base (chemistry), Stereochemistry, Alkaloid, Organic Chemistry, Drug Discovery, Enantioselective synthesis, Ring (chemistry), Imide, Biochemistry
Abstract

A new asymmetric approach to the erythrinan alkaloid system is described, which involves chiral base desymmetrisation of a ring fused imide and a 6-exo-trig radical cyclisation as the key steps.

Published
2003
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