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Start Over Author "Clarke, Matthew L." Search Limiters Peer Reviewed Topic catalysis Topic rhodium catalysts Publication Year Range Last 50 years Journal tetrahedron letters: international organ for the rapid publication of preliminary communications in organic chemistry
1 results on '"Clarke, Matthew L."'

1. Rhodium catalysed hydroformylation of unsaturated esters

Author

Clarke, Matthew L.

Subjects
*RHODIUM catalysts, *HYDROFORMYLATION, *ESTERS, *CATALYSIS
Abstract

Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions, and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed. [Copyright &y& Elsevier]

Published
2004
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