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2. High-efficiency α-benzoyloxylation and hydroxylation of β-keto amides by phase transfer catalysis

Author

Chen Yifan, Nan Li, Qingwei Meng, Cui Jingwen, Feiyu Gao, Yakun Wang, and Qinghe Gao

Subjects
Hydroxylation, chemistry.chemical_compound, 010405 organic chemistry, Chemistry, Phase (matter), Organic Chemistry, Drug Discovery, 010402 general chemistry, 01 natural sciences, Biochemistry, Combinatorial chemistry, 0104 chemical sciences, Catalysis
Abstract

A facile and efficient protocol for α-benzoyloxylation and α-hydroxylation of β-keto amides by phase-transfer catalysis is presented. This methodology provides mild and practical access to a variety ofα-oxygenated β-keto amides. Furthermore, α-benzoyloxylation products can be easily converted into α-hydroxylation compounds, which are useful synthetic precursors of biological targets.

Published
2018

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