1. Synthesis, characterization and redox behavior of nickel(II) and cobalt(II) polymeric complexes
- Author
-
Hualiang Huang, Rongfang Guo, Chaofan Zhong, Aihong He, and Qian Wu
- Subjects
Biphenyl ,Mechanical Engineering ,Metals and Alloys ,chemistry.chemical_element ,Infrared spectroscopy ,Condensed Matter Physics ,Redox ,Electronic, Optical and Magnetic Materials ,Gel permeation chromatography ,chemistry.chemical_compound ,Nickel ,chemistry ,Mechanics of Materials ,Polymer chemistry ,Materials Chemistry ,Thermal stability ,Benzene ,Cobalt - Abstract
The polymeric complexes of 4,4′-bis[2-(2′-pyridyl)benzimidazolyl]biphenyl (Bmbp) with Co(II) (1), Ni(II) (2) and 1,3,5-tris[2-(2′-pyridyl)benzimidazolyl]benzene (Tmb) with Co(II) (3), Ni(II) (4) were successfully synthesized and characterized by using IR spectroscopy, elemental analysis, and gel permeation chromatography (GPC) analysis. Their cyclic voltametric behavior and thermal property were also studied. The results indicated these complexes display an irreversible redox process and have high thermal stability.
- Published
- 2008