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2. Scope of the Desulfinylative Palladium-Catalyzed Cross-Coupling of Aryl Sulfinates with Aryl Bromides.

Author

Ortgies, Dirk H., Barthelme, Alexandre, Aly, Sara, Desharnais, Brigitte, Rioux, Steven, and Forgione, Pat

Subjects
PALLADIUM compounds, SULFINATES, ARYL bromides, COUPLING reactions (Chemistry), PHOSPHINE, REACTION mechanisms (Chemistry)
Abstract

Herein is described the full scope of a desulfinylative cross-coupling of aryl sulfinates with aryl bromides. Optimized conditions were established and a bidentate phosphine ligand was found to be the key in obtaining good cross-coupling yields. Preliminary efforts to elucidate the reaction mechanism suggest that a Pd(0)-catalyzed mechanism is operative. [ABSTRACT FROM AUTHOR]

Published
2013
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