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1. Intramolecular Diels-Alder Strategy in a Synthetic Approach to the ­Eleutherobin Core

Author

Alain Tomas, Jacques Royer, Simona Samaritani, Hélène Bruyère, and Stéphanie Ballereau

Subjects
eleutherobin, intramolecular Diels–Alder reaction, antitumor agents, eleuthesides, sulfolene, sulfolene, Chemistry, Stereochemistry, Eleutherobin, fungi, Organic Chemistry, Total synthesis, intramolecular Diels–Alder reaction, antitumor agents, eleutherobin, Intramolecular force, Diels alder, eleuthesides
Abstract

An attractive intermediate in the total synthesis of eleutherobin has been synthesised. The key step of this synthesis is an intramolecular Diels-Alder reaction, which leads to intermediate possessing rings A and C of theeleutherobin skeleton.

Published
2005

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