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Your search keyword '"Magnesium monoperoxyphthalate"' showing total 4 results
Start Over Descriptor "Magnesium monoperoxyphthalate" Journal synlett
4 results on '"Magnesium monoperoxyphthalate"'

1. Catalytic Oxidation of Silyl Enol Ethers to 1,2-Diketones Employing Nitroxyl Radicals

Author

Masaki Hayashi, Masatoshi Shibuya, and Yoshiharu Iwabuchi

Subjects
chemistry.chemical_compound, Nitroxyl radicals, chemistry, Silylation, Catalytic oxidation, Organic Chemistry, Polymer chemistry, Magnesium monoperoxyphthalate, Enol, Catalysis
Abstract

A novel and efficient method for the preparation of 1,2-diketones is reported. A series of α-diketones were readily prepared by the nitroxyl-radical-catalyzed oxidation of silyl enol ethers using magnesium monoperoxyphthalate hexahydrate (MMPP⋅6H2O) as the co-oxidant.

Published
2012

4. The Selective Generation of Regioisomeric TetrahydropyridineN-Oxides

Author

Andrew B. Holmes, Adrian L. Smith, and Andrew B. Hughes

Subjects
chemistry.chemical_classification, chemistry.chemical_compound, chemistry, Bicyclic molecule, Organic Chemistry, Pyridine, Magnesium monoperoxyphthalate, Oxidative cleavage, Medicinal chemistry, Nitrone, Octane
Abstract

Whereas the oxidative cleavage of bicyclic isoxazolidines 5 (2-phenylperhydroisoxazolo[2,3-a]pyridine) and 9 (6-(2-benzyloxyethyl)- 8 -(3-phenylsulfonylpropyl)-7 -oxa-1-azabicyclo-[3.2.1]octane) with magnesium monoperoxyphthalate (MMPP) significantly favours the formation of the more substituted tetrahydropyridine N-oxides, 3-chloroperoxybenzoic acid (mCPBA) is shown to favour the less substituted nitrone 10 in reaction with the more substituted isoxazolidine 9.

Published
1991

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