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Start Over Author "Bankar, Siddheshwar K." Journal synlett
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1. Facile Access to Cyclopentadienes via Catalytic Intramolecular Palladium-Ene Reaction of 2,4-Pentadienyl Acetates.

Author

Bharadwaj, Saitanya K., Bankar, Siddheshwar K., and Ramasastry, S. S. V.

Subjects
*PALLADIUM catalysts, *PENTADIENES, *ACETATES
Abstract

We have recently disclosed a palladium-catalyzed Trost- Oppolzer type Alder-ene reaction of 2,4-pentadienyl acetates for the synthesis of highly substituted cyclopentadienes and cyclopentenefused aromatics. The overall transformation also represents an acid-free iso-Nazarov type cyclization. Herein, we provide the hypothesis and rationale behind this work, while highlighting the seminal contributions of Trost, Oppolzer and others towards the development of the palladium- ene reaction. [ABSTRACT FROM AUTHOR]

Published
2018
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