1. High performance dye-sensitized solar cells based on platinum nanoroses counter electrode
- Author
-
Yu-Hsuan Wei, Sung-Yen Wei, Ming-Chi Tsai, Fan-Gang Tseng, Chien-Kuo Hsieh, I-Ching Chen, and Hsuan-Chung Wu
- Subjects
Auxiliary electrode ,Materials science ,Working electrode ,Inorganic chemistry ,chemistry.chemical_element ,Exchange current density ,02 engineering and technology ,Surfaces and Interfaces ,General Chemistry ,Electrolyte ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,Surfaces, Coatings and Films ,law.invention ,Dye-sensitized solar cell ,chemistry ,law ,Solar cell ,Materials Chemistry ,Cyclic voltammetry ,0210 nano-technology ,Platinum - Abstract
In this study, we controlled the growth of crystalline plane to synthesize the vertical platinum nanopelts onto fluorine doped tin oxide (FTO) glass to construct the platinum nanoroses (PtNRs) by an easy electrochemical deposition (ECD) method at room temperature in the normal atmospheric environment, and applied the PtNRs as a counter electrode (CE) for dye-sensitized solar cell (DSSC). The morphologies and crystalline nanostructures of the ECD PtNRs were examined by field emission scanning electron microscopy and the high-resolution transmission electron microscopy. The electrocatalytic properties of the ECD PtNRs were analyzed by cyclic voltammetry and electrochemical impedance spectrum. The power conversion efficiency (PCE) of the DSSC assembled with the ECD PtNRs CE was examined under the illumination of AM 1.5 (100 mWcm − 2 ). The ECD PtNRs showed well contact behavior with FTO surface and offered a large surface area to promote the redox reaction rates therefore increased the exchange current density. Due to the PtNRs showed the macroporous structure, the electrolyte can easily diffuse through the open space between the nanopelts, resulting in improved kinetics for charge-transfer processes and reduced the charge-transfer resistance. Our findings suggest that the catalytic efficiency of PtNRs with a specific crystal plane was significantly greater than that of a traditional Pt film catalyst. In combination with a N719 dye-sensitized TiO 2 working electrode and an iodine-based electrolyte, the DSSC assembled with the PtNRs CE achieved a PCE of 6.58%, almost 10% higher than that of a cell prepared with a conventional sputtering Pt film CE (6.00%). These results provide a potential strategy for electrochemical catalytic applications.
- Published
- 2017
- Full Text
- View/download PDF