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In this study, titanium carbide (TiC) coatings were grown on the surface of a spheroidal graphite cast iron (SGI) via thermo-reactive diffusion (TRD) using powder-pack processing at 800 °C, 850 °C and 900 °C for 4 h. The TiC coatings obtained on the SGI were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), surface profilometry, microhardness, VDI adhesion testing, wear testing, and electrochemical corrosion testing. Depending on the TRD temperature, continuous, crack-free, and smooth TiC coatings of 5–11 μm thickness and 27.96–32.45 GPa hardness were obtained on the surface. The high chemical stability, high hardness, and good adhesion strength of TiC coatings resulted in a reduced friction, high wear resistance, and superior corrosion resistance compared to the untreated sample. Delamination and oxidation assisted abrasive wear transformed into oxidation-assisted adhesive wear in the coated samples. Galvanic corrosion was dominant in untreated SGI, while homogeneous corrosion occurred in the coated samples. TiC coatings grown using TRD have the potential to be used in engineering components exposed to tribo-corrosive conditions.

The coating Cr3C2 with 50wt.% Ni20Cr deposited by high velocity oxy-fuel (HVOF) spray process was characterized in detail to investigate the effect of annealing on the solid particle erosion behaviour and understand the influence of the binder properties. Systematic characterization of the coating was carried out using electron microscopy (scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electron probe microanalysis (EPMA)), X-ray diffraction (XRD), microindentation and nanoindentation techniques. The solid particle erosion tests were done on the as-sprayed coating and coatings annealed at 400�C, 600�C and 800�C using silica erodent particles. The coefficient of restitution of the coated samples was also measured by WC ball impact tests to simulate dynamic impacts. The as-sprayed coating consisted of primary carbides and binder that was a mixture of amorphous and nanocrystalline phases. Annealing leads to recrystallisation of binder phase and precipitation of secondary carbides. The coating hardness and binder ductility change with annealing temperature. The erosion resistance improves with annealing up to 600�C. In the as-sprayed coating, the amorphous phase, inter-splat boundaries and the elastic rebound characteristics affect the erosion response. While in the case of the coating annealed at 600�C, the presence of ductile crystalline binder, fine carbide precipitates and embedment of erodent particles together improve solid particle erosion resistance. � 2010 Elsevier B.V.