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To improve the adaptability of GLC coatings in aqueous environment, a dense structure for GLC coatings was designed and constructed by nitrogen doping via PVD technique. The nitrogen content was tailored via tuning the nitrogen flow rate to optimize the tribological performances of the N-doped GLC coatings in water as well as to investigate the effects of different nitrogen contents. And the optimal nitrogen flow rate was 5 sccm. The results implied the nitrogen doping favored the increase of adhesion strength. The dense structure built by nitrogen doping entitled the N-GLC coatings to improved wear resistance in water and enhanced aqueous-adaptability, because the corrosion by water can be effectively inhibited compared with the column-structured nitrogen-free GLC coatings via PVD. [Display omitted] • The nitrogen modified GLC coatings with dense structure and better adhesion strength were constructed via PVD technique. • The nitrogen contents in the N-doped GLC coatings can be tailored by tuning the nitrogen flow rate in the PVD process. • The nitrogen-free GLC coating was failed in water environment, while the N-GLC coating with 5 sccm flow rate showed a lowest wear rate of 2.47 × 10-8 mm3/Nm. • The nitrogen doping contributed to the densification of the coatings and thus improved their aqueous-adaptability. [ABSTRACT FROM AUTHOR]

(CrNbTiAlV)N x high-entropy nitride films were prepared using magnetron sputtering method. The effect of substrate bias on the microstructure, mechanical, electrochemical, and tribo-corrosion properties of the films was systematically studied. The results show that the microstructure of the film changes from a loose columnar structure to a compact nanocrystal structure with the increase of substrate bias, accompanied by the preferred orientation from (200) to (111). The hardness, modulus and residual stress are positively correlated with increased substrate bias, reaching the maximum values of 35.3 GPa, 353.7 GPa and −6.41 GPa at −156 V, respectively. Under static corrosion, the film deposited under −126 V has the most positive E corr of −0.05 V and the lowest i corr of 0.013 μA/cm2. Under tribo-corrosion, the films deposited at −96 V and −126 V show the lowest coefficient of friction (~0.2) and wear rate (~4.4 × 10−7 mm3·N−1·m−1), respectively. The evolution of microstructure and mechanical property are the main factors affecting the tribo-corrosion behavior of (CrNbTiAlV)N x films. [Display omitted] • (CrNbTiAlV)N x high-entropy films were deposited at various substrate bias by magnetron sputtering. • The structure of the films changed from loose columnar to compact with the increase of substrate bias. • The hardness, modulus and residual stress of the films were positively correlated with increasing bias. • The influencing factors of (CrNbTiAlV)N x films under static corrosion and dynamic tribocorrosion were discussed. [ABSTRACT FROM AUTHOR]