Design and characterization of a pH optical fiber sensor with a pH sensitive dye is described in this paper. TEOS (Tetra-ethyl-Orto-Silicate) was used to dope a plastic optical fiber, which will be used as the optical probe (OPTRODE). The sensor is prepared by fixing the doped plastic fiber on a fused ortosilica block surface with blue bromophenol. The fiber surface charged with silica modified the refractive index, which plays an important roll on the fiber, modifies the conditions of light propagation into the plastic optical fiber. The fiber transmittance is used to measure the pH of a solution or a fluid in a range between 4 and 7; such signal is captured by a photodetector and processed with a LabView program. The advantage of this system is that, 2cm of doped fiber are enough to measure the pH of a fluid in real time. The time response of the se nsor reported in the present study is approximately 10s. Keywords: Doped fiber, Optical fiber Sensor; pH sensor; Sol-Gel. 1. INTRODUCTION Many industrial sectors have as a need a distributed measurements system for chemical parameters. Early detection and location of water or fluids filtration, for example, could prevent premature damage to cables in both communications and power distribution ducts, in foods industry, biological systems, etc.[1-2]. The detection of some parameters, such pH decreasing to the value of 10, can be a good indicator of potential corrosion of reinforcing tensors in civil engineering structures which are on earth, underground or under water conditions. The definition of pH is the concentr ation of hydrogen ions in liquids. If the pH value is between 0 and 7, are called acids. If the pH values between 7 and 14 are called bases. For pH = 7 the substances are called neutrals, for example pure water, where is very important monitoring for our health. Some biological systems have ionic groups which electrical charge depends on pH concentration; this pH value depends on the balance between the O-H and H. Ther efore, pH is sensitive to the ions concentration in