1. Smartphone-assisted visual ratio-fluorescence detection of hypochlorite based on copper nanoclusters.
- Author
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Li, Yanyue, He, Yu, Ge, Yili, Song, Gongwu, and Zhou, Jiangang
- Subjects
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DUAL fluorescence , *SMARTPHONES , *COPPER , *DRINKING water , *DETECTION limit , *COLORIMETRY , *COLORIMETRIC analysis - Abstract
[Display omitted] • A sensitive ratio-fluorescence sensor for hypochlorite determination was developed. • The detection mechanism was based on oxidation of curcumin to hypochlorite. • It has a low detection limit, and was applied to milk and tap water samples. • The smartphone was introduced to realize the visual quantitative detection. A sensitive naked eye and ratio-fluorescence sensor for Curcumin (CCM) and hypochlorite (ClO-) determination based on copper nanoclusters (Cu NCs) was developed. The fluorescence of the Cu NCs can be quenched due to inner filter effect (IFE) between CCM and Cu NCs, and the ratio fluorescence probe was formed. After adding ClO- to Cu NCs-CCM system, the phenolic and methoxy groups of CCM were oxidized to quinones, then the fluorescence of CCM was quenched and the fluorescence of Cu NC was restored. Moreover, the continuous detection of CCM and ClO- is accompanied by the change of solution color. Therefore, CCM and ClO- semiquantitative visual and fluorescence dual channel detection were realized. The detection results show that the detection based on Cu NCs-CCM probe has a wide detection range (0–412 µM) and low detection limit (24 µM), and a good recovery rate is obtained in adulterated milk and tap water detection. Furthermore, smartphone was introduced for image digital colorimetric analysis through the acquisition, recognition and RGB data processing of solution colors, providing an effective scheme for the field rapid detection of hypochlorite. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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