1. A buetschliite-type rare-earth borate, KBaY(BO3)2
- Author
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Gao, Jianhua, Song, Limei, Hu, Xiaoyun, and Zhang, Dekai
- Subjects
- *
RARE earth metals , *BORATES , *LUMINESCENCE , *COMPLEX compounds , *CRYSTALLIZATION , *DOPED semiconductors - Abstract
Abstract: The title compound was firstly synthesized by solid state reaction and its single crystals were successfully obtained using a selected flux. It is isotypic with the mineral buetschliite, K2Ca(CO3)2, and crystallizes in the trigonal space group R-3m with a = 5.4526(12) Å, c = 17.781(8) Å, Z = 3. In the structure, Ba and K atoms are disordered on a same site in the proportion of 0.492(4):0.508(4). The fundamental building units are YO6 octahedra and BO3 triangles. The structure consists of [YB2O6]∞ double layers constructed by corner-sharing YO6 and BO3 groups. Ba/K atoms occupy the spaces between these two layers and play the role of bridges. In addition, the luminescence properties of Eu3+ doped KBaY(BO3)2 were also studied. [Copyright &y& Elsevier]
- Published
- 2011
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